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Selective O-Acylation of Enol Silyl Ethers with Acyl Fluorides Catalyzed by Fluoride Ions Derived from Potassium Fluoride and 18-Crown-6.
Sakai, Norio; Watanabe, Kota; Mori, Haruka; Maegawa, Yuki; Takeuchi, Ryuki; Ogiwara, Yohei; Ishida, Kento.
Afiliación
  • Sakai N; Department of Pure and Applied Chemistry, Faculty of Science and Technology, Tokyo University of Science (RIKADAI), Noda, Chiba, 278-8510, Japan.
  • Watanabe K; Department of Pure and Applied Chemistry, Faculty of Science and Technology, Tokyo University of Science (RIKADAI), Noda, Chiba, 278-8510, Japan.
  • Mori H; Department of Pure and Applied Chemistry, Faculty of Science and Technology, Tokyo University of Science (RIKADAI), Noda, Chiba, 278-8510, Japan.
  • Maegawa Y; Department of Pure and Applied Chemistry, Faculty of Science and Technology, Tokyo University of Science (RIKADAI), Noda, Chiba, 278-8510, Japan.
  • Takeuchi R; Department of Pure and Applied Chemistry, Faculty of Science and Technology, Tokyo University of Science (RIKADAI), Noda, Chiba, 278-8510, Japan.
  • Ogiwara Y; Department of Pure and Applied Chemistry, Faculty of Science and Technology, Tokyo University of Science (RIKADAI), Noda, Chiba, 278-8510, Japan.
  • Ishida K; Department of Pure and Applied Chemistry, Faculty of Science and Technology, Tokyo University of Science (RIKADAI), Noda, Chiba, 278-8510, Japan.
ChemistryOpen ; 13(7): e202300300, 2024 Jul.
Article en En | MEDLINE | ID: mdl-38286634
ABSTRACT
The fluoride ion-catalyzed selective O-acylation of enol silyl ethers with acyl fluorides using KF and 18-Crown-6 is described herein. This catalytic system facilitated the practical and facile reaction of a variety of enol silyl ethers derived from aromatic/aliphatic ketones and aldehydes with acyl fluorides to afford useful and valuable enol esters.
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Texto completo: 1 Banco de datos: MEDLINE Idioma: En Revista: ChemistryOpen Año: 2024 Tipo del documento: Article País de afiliación: Japón
Texto completo
Imprimir
XML
PubMed Links
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Texto completo: 1 Banco de datos: MEDLINE Idioma: En Revista: ChemistryOpen Año: 2024 Tipo del documento: Article País de afiliación: Japón