Trapping of a Terminal Intermediate in the Boron-Mediated Dinitrogen Reduction: Mono-, Tri-, and Tetrafunctionalized Hydrazines in Two Steps from N2.
J Am Chem Soc
; 2024 Apr 10.
Article
en En
| MEDLINE
| ID: mdl-38598273
ABSTRACT
The addition of chlorotrimethylsilane to a boron-mediated, transition-metal-free N2 activation reaction leads to the isolation of multiple potassium boryl(silyl)hydrazido species, likely trapping products of a terminal dinitrogen complex of boron. One of these silylated N2 species can be protonated or methylated, providing access to mono- to tetrafunctionalized hydrazines in two steps from N2 and in the absence of transition metals.
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Banco de datos:
MEDLINE
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En
Revista:
J Am Chem Soc
Año:
2024
Tipo del documento:
Article
País de afiliación:
Alemania