Stereoselective and controllable C3-Amination or C1,C3-di-amination of 2-nitroglycals.
Carbohydr Res
; 540: 109121, 2024 Jun.
Article
en En
| MEDLINE
| ID: mdl-38692248
ABSTRACT
Precise and selective modification of carbohydrates is a critical strategy in producing diverse carbohydrate derivatives for exploiting their functions. We disclosed a simple, efficient, and highly regioselective and stereoselective protocol to controllable amination of 2-nitroglycals under mild conditions in 5 min. A range of 3-amino-carbohydrates including 3-arylamino-2-nitro-glycals and 1,3-di-amino-carbohydrate derivatives were obtained in good to excellent yield with excellent stereoselectivity. The produced 3-amino-2-nitro-glycals can be used as a precursor for further transformation.
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Banco de datos:
MEDLINE
Asunto principal:
Nitrocompuestos
Idioma:
En
Revista:
Carbohydr Res
Año:
2024
Tipo del documento:
Article