Molecular Editing of Pyrroles to Benzenes/Naphthalenes by N2O Deletion.
Angew Chem Int Ed Engl
; 63(43): e202411166, 2024 Oct 21.
Article
en De
| MEDLINE
| ID: mdl-39008335
ABSTRACT
A molecular editing reaction for converting pyrrole rings into benzene rings through a sequential pathway of Diels-Alder and cheletropic reactions was developed. The nitrogen atom in a N-bridged intermediate is eliminated in the form of N2O by a strain-releasing pathway, ultimately leading to the formation of substituted benzene and naphthalene derivatives.
Texto completo:
1
Banco de datos:
MEDLINE
Idioma:
De
Revista:
Angew Chem Int Ed Engl
/
Angew. Chem. (Int. ed., Internet)
/
Angewandte Chemie (International ed. Internet)
Año:
2024
Tipo del documento:
Article
País de afiliación:
China