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Attosecond delays in X-ray molecular ionization.
Driver, Taran; Mountney, Miles; Wang, Jun; Ortmann, Lisa; Al-Haddad, Andre; Berrah, Nora; Bostedt, Christoph; Champenois, Elio G; DiMauro, Louis F; Duris, Joseph; Garratt, Douglas; Glownia, James M; Guo, Zhaoheng; Haxton, Daniel; Isele, Erik; Ivanov, Igor; Ji, Jiabao; Kamalov, Andrei; Li, Siqi; Lin, Ming-Fu; Marangos, Jon P; Obaid, Razib; O'Neal, Jordan T; Rosenberger, Philipp; Shivaram, Niranjan H; Wang, Anna L; Walter, Peter; Wolf, Thomas J A; Wörner, Hans Jakob; Zhang, Zhen; Bucksbaum, Philip H; Kling, Matthias F; Landsman, Alexandra S; Lucchese, Robert R; Emmanouilidou, Agapi; Marinelli, Agostino; Cryan, James P.
Afiliación
  • Driver T; Stanford PULSE Institute, SLAC National Accelerator Laboratory, Menlo Park, CA, USA. tdriver@stanford.edu.
  • Mountney M; Linac Coherent Light Source, SLAC National Accelerator Laboratory, Menlo Park, CA, USA. tdriver@stanford.edu.
  • Wang J; Department of Physics and Astronomy, University College London, London, UK.
  • Ortmann L; Stanford PULSE Institute, SLAC National Accelerator Laboratory, Menlo Park, CA, USA.
  • Al-Haddad A; Linac Coherent Light Source, SLAC National Accelerator Laboratory, Menlo Park, CA, USA.
  • Berrah N; Department of Applied Physics, Stanford University, Stanford, CA, USA.
  • Bostedt C; Department of Physics, The Ohio State University, Columbus, OH, USA.
  • Champenois EG; Paul Scherrer Institute, Villigen, Switzerland.
  • DiMauro LF; Department of Physics, University of Connecticut, Storrs, CT, USA.
  • Duris J; Paul Scherrer Institute, Villigen, Switzerland.
  • Garratt D; LUXS Laboratory for Ultrafast X-ray Sciences, Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne (EPFL), Lausanne, Switzerland.
  • Glownia JM; Stanford PULSE Institute, SLAC National Accelerator Laboratory, Menlo Park, CA, USA.
  • Guo Z; Department of Physics, The Ohio State University, Columbus, OH, USA.
  • Haxton D; Linac Coherent Light Source, SLAC National Accelerator Laboratory, Menlo Park, CA, USA.
  • Isele E; The Blackett Laboratory, Imperial College London, London, UK.
  • Ivanov I; Linac Coherent Light Source, SLAC National Accelerator Laboratory, Menlo Park, CA, USA.
  • Ji J; Linac Coherent Light Source, SLAC National Accelerator Laboratory, Menlo Park, CA, USA.
  • Kamalov A; Department of Applied Physics, Stanford University, Stanford, CA, USA.
  • Li S; KLA Corporation, Milpitas, CA, USA.
  • Lin MF; Stanford PULSE Institute, SLAC National Accelerator Laboratory, Menlo Park, CA, USA.
  • Marangos JP; Linac Coherent Light Source, SLAC National Accelerator Laboratory, Menlo Park, CA, USA.
  • Obaid R; Department of Applied Physics, Stanford University, Stanford, CA, USA.
  • O'Neal JT; Center for Relativistic Laser Science, Institute for Basic Science, Gwangju, Korea.
  • Rosenberger P; Laboratorium für Physikalische Chemie, ETH Zurich, Zurich, Switzerland.
  • Shivaram NH; Stanford PULSE Institute, SLAC National Accelerator Laboratory, Menlo Park, CA, USA.
  • Wang AL; Linac Coherent Light Source, SLAC National Accelerator Laboratory, Menlo Park, CA, USA.
  • Walter P; Linac Coherent Light Source, SLAC National Accelerator Laboratory, Menlo Park, CA, USA.
  • Wolf TJA; The Blackett Laboratory, Imperial College London, London, UK.
  • Wörner HJ; Department of Physics, University of Connecticut, Storrs, CT, USA.
  • Zhang Z; Stanford PULSE Institute, SLAC National Accelerator Laboratory, Menlo Park, CA, USA.
  • Bucksbaum PH; Physics Department, Ludwig-Maximilians-Universität, Munich, Germany.
  • Kling MF; Max Planck Institute of Quantum Optics, Garching, Germany.
  • Landsman AS; Linac Coherent Light Source, SLAC National Accelerator Laboratory, Menlo Park, CA, USA.
  • Lucchese RR; Department of Physics and Astronomy, Purdue University, West Lafayette, IN, USA.
  • Emmanouilidou A; Purdue Quantum Science and Engineering Institute, Purdue University, West Lafayette, IN, USA.
  • Marinelli A; Stanford PULSE Institute, SLAC National Accelerator Laboratory, Menlo Park, CA, USA.
  • Cryan JP; Linac Coherent Light Source, SLAC National Accelerator Laboratory, Menlo Park, CA, USA.
Nature ; 632(8026): 762-767, 2024 Aug.
Article en En | MEDLINE | ID: mdl-39169246
ABSTRACT
The photoelectric effect is not truly instantaneous but exhibits attosecond delays that can reveal complex molecular dynamics1-7. Sub-femtosecond-duration light pulses provide the requisite tools to resolve the dynamics of photoionization8-12. Accordingly, the past decade has produced a large volume of work on photoionization delays following single-photon absorption of an extreme ultraviolet photon. However, the measurement of time-resolved core-level photoionization remained out of reach. The required X-ray photon energies needed for core-level photoionization were not available with attosecond tabletop sources. Here we report measurements of the X-ray photoemission delay of core-level electrons, with unexpectedly large delays, ranging up to 700 as in NO near the oxygen K-shell threshold. These measurements exploit attosecond soft X-ray pulses from a free-electron laser to scan across the entire region near the K-shell threshold. Furthermore, we find that the delay spectrum is richly modulated, suggesting several contributions, including transient trapping of the photoelectron owing to shape resonances, collisions with the Auger-Meitner electron that is emitted in the rapid non-radiative relaxation of the molecule and multi-electron scattering effects. The results demonstrate how X-ray attosecond experiments, supported by comprehensive theoretical modelling, can unravel the complex correlated dynamics of core-level photoionization.
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Texto completo: 1 Banco de datos: MEDLINE Idioma: En Revista: Nature / Nature (Lond.) / Nature (London) Año: 2024 Tipo del documento: Article País de afiliación: Estados Unidos
Texto completo
Imprimir
XML
PubMed Links
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Texto completo: 1 Banco de datos: MEDLINE Idioma: En Revista: Nature / Nature (Lond.) / Nature (London) Año: 2024 Tipo del documento: Article País de afiliación: Estados Unidos