RESUMEN
Correction for 'A robust and porous titanium metal-organic framework for gas adsorption, CO2 capture and conversion' by Xuze Pan, et al., Dalton Trans., 2023, 52, 3896-3906, https://doi.org/10.1039/D2DT03158B.
RESUMEN
A robust and porous titanium metal-organic framework (Ti-MOF; LCU-402) has been hydrothermally synthesized through combining a tetranuclear Ti2Ca2(µ3-O)2(µ2-H2O)1.3(H2O)4(O2C-)8 cluster and a tritopic 1,3,5-benzene(tris)benzoic (BTB) ligand. LCU-402 shows remarkable stability and permanent porosity for CO2, CH4, C2H2, C2H4, and C2H6 gas adsorption. Moreover, LCU-402 as a heterogeneous catalyst can smoothly convert CO2 under a simulated flue atmosphere into organic carbonate molecules by cycloaddition reactions of CO2 and epoxides, indicating that LCU-402 might be a promising catalyst candidate in practical applications. We are confident that the identification of a persistent titanium-oxo building unit would accelerate the development of new porous Ti-MOF materials.
RESUMEN
In the title complex, [Cd(C(2)F(3)O(2))(NO(3))(C(10)H(8)N(2))(2)], the Cd(II) ion is hepta-coordinated by two chelating 2,2'-bipyridyl ligands [Cdâ¯N 2.370â (6)-2.416â (6)â Å], one carboxyl-ate O atom [Cdâ¯O 2.290â (6)â Å] from the trifluoro-acetate ligand and two O atoms [Cdâ¯O 2.386â (6), 2.633â (6)â Å] from a chelating nitrate anion. The trifluoro-methyl fragment is rotationally disordered between two orientations in a 0.640â (7):0.360â (7) ratio. In the crystal, weak inter-molecular C-Hâ¯O hydrogen bonds contribute to the crystal packing stability.