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Spectrochim Acta A Mol Biomol Spectrosc ; 322: 124842, 2024 Dec 05.
Artículo en Inglés | MEDLINE | ID: mdl-39032234

RESUMEN

In recent years, due to the abuse of antibiotics, nitro explosives and pesticides, which have caused great harm to the environment and human health, social concerns have prompted researchers to develop more sensitive detection platforms for these pollutants. In this paper, a novel two-dimensional Zn (II) coordination polymer, [Zn(L)0.5(1,2-bimb)]·DMF (1), [H4L=[1,1':4',1''-terphenyl]-2, 2'',4, 4'' -tetracarboxylic acid, 1,2-bimb = 1,2-bis(imidazol-1-ylmethyl)benzene] was synthesized using a hydro-solvothermal method. Among commonly used organic solvents, 1 exhibits significant stability. Fast and efficient fluorescence response can be achieved for tetracycline (TET), 4-nitrophenol (4-NP), fluazinam (FLU), and abamectin benzoate (AMB) with low detection limits. A binary intelligent logic gate device with FLU and AMB as chemical input signals is successfully constructed, which provides a new idea for biochemical detection. In addition, a portable visual test paper has been prepared, which has high sensitivity, good selectivity, and simple operation. It can be used for rapid detection of pollutants in daily life and has broad application prospects. Finally, a detailed discussion was conducted on the fluorescence sensing mechanism of 1 for detecting TET, 4-NP, AMB and FLU.


Asunto(s)
Nitrofenoles , Plaguicidas , Espectrometría de Fluorescencia , Tetraciclina , Nitrofenoles/análisis , Nitrofenoles/química , Tetraciclina/análisis , Plaguicidas/análisis , Espectrometría de Fluorescencia/métodos , Límite de Detección , Contaminantes Químicos del Agua/análisis , Zinc/análisis
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