Positively buoyant but sinking: Polymer identification and composition of marine litter at the seafloor of the North Sea and Baltic Sea.

Different litter types accumulate in all marine environments. Plastics are of special interest because of their high abundance and possible threats to marine organisms. Polymer type is crucial for their distribution and fate in marine environments. Seafloor litter abundance and composition in the Baltic and North Sea were analysed based on three sampling campaigns according to the protocol of ICES International Bottom Trawl Survey. Polymers were identified via attenuated total reflection-Fourier transform infrared spectroscopy. General litter abundances differed significantly between the Baltic and North Sea with 9.6 items/km2 and 70.7 items/km2, respectively. Plastic built the dominating litter group in both seas (62.2% and 91.3%, respectively). Polymer identification revealed clear dominance of polyethylene, polypropylene and polyamide. Most polymers were positively buoyant in seawater (89.5%), thereby excluding polymer density as the main driver of vertical plastic litter transportation. Plastics at the seafloor basically reflected the entirety of polymers entering marine environments.

Systematic identification of microplastics in abyssal and hadal sediments of the Kuril Kamchatka trench.

The occurrence of microplastics throughout marine environments worldwide, from pelagic to benthic habitats, has become serious cause for concern. Hadal zones were recently described as the "trash bins of the oceans" and ultimate sink for marine plastic debris. The Kuril region covers a substantial area of the North Pacific Ocean and is characterised by high biological productivity, intense marine traffic through the Kuril straits, and anthropogenic activity. Moreover, strong tidal currents and eddy activity, as well as the influence of Pacific currents, have the potential for long distance transport and retention of microplastics in this area. To verify the hypothesis that the underlying Kuril Kamchatka Trench might accumulate microplastics from the surrounding environments and act as the final sink for high quantities of microplastics, we analysed eight sediment samples collected in the Kuril Kamchatka Trench at a depth range of 5143-8250 m during the Kuril Kamchatka Biodiversity Studies II (KuramBio II) expedition in summer 2016. Microplastics were characterised via Micro Fourier Transform Infrared spectroscopy. All samples were analysed in their entirety to avoid inaccuracies due to extrapolations of microplastic concentrations and polymer diversities, which would otherwise be based on commonly applied representative aliquots. The number of microplastic particles detected ranged from 14 to 209 kg-1 sediment (dry weight) with a total of 15 different plastic polymers detected. Polypropylene accounted for the largest proportion (33.2%), followed by acrylates/polyurethane/varnish (19%) and oxidized polypropylene (17.4%). By comparing extrapolated sample aliquots with in toto results, it was shown that aliquot-based extrapolations lead to severe under- or overestimations of microplastic concentrations, and an underestimation of polymer diversity.