Probing natural gas components with Raman integrating sphere technology.

Raman spectroscopy is a powerful method of probing natural gas components, but higher sensitivity, greater miniaturization, and lower cost techniques are required. Therefore, we designed a Raman integrating sphere-enhanced spectroscopy technology in a volume of 40 × 40 × 20 cm3 based on the principle of integrating sphere reflection. This technology consists of two parts: the first is an integrating sphere model to collect scattered signals, and the second is a right-angle light-boosting system to increase the optical path of the pump light in the sample. Raman integrating sphere technology has a detection limit of 0.5 ppm in the air with an exposure time of 600 s under room temperature and ambient pressure conditions. Experiments of natural gas detection display that the detection limits of ethane, propane, n-butane, isobutane, n-pentane, and isopentane are 28, 28, 95, 28, 189, and 95 ppm, respectively. In addition, there is a linear relationship between the relative Raman intensity and the concentration of each component in natural gas, which can be used as a probe for detecting unknown natural gas components in gas wells.

Mechanical response of surface wettability of Janus porous membrane and its application in oil-water separation.

Smart surfaces with switchable wettability are widely studied for environmental application. Although a large number of stimulation routes provide broad prospects for the development of smart surfaces, achieving high sensitivity, fast response and recovery, simple operation, security and good stability is still challenging. Herein, a Janus membrane via electrospinning, chemical bath deposition and heat treatment is constructed. By using the hydrophilic ZIF-L nanosheet to functionalize the hydrophobic thermoplastic polyurethane (TPU) substrate, a smart surface utilizes the ZIF-L crack induced by strain in the hydrophilic layer to control surface wettability is obtained. In the range of 0%-100% strain, the wettability of the smart surface presents an obvious change with stretching, and water contact angle of the surface shows a monotonic increase with a maximum tuning range from 47° to 114°. Due to local fusion of the TPU microfibers and good binding between the ZIF-L layer and the TPU substrate after heat treatment, the prepared Janus membrane exhibits consistent and symmetrical hydrophilic-hydrophobic-hydrophilic transition curves in 50 stretching-releasing cycles. Thanks to the porous and asymmetric architecture, the membrane shows good oil-water separation performance, and the separation flux increases with the increase of strain, while the separation efficiency is always higher than 98%. Because of the excellent structural stability, the robust membrane with 100% strain maintains its oil-water separation property for 50 stretching-releasing cycles. This study provides a new perspective for the development of smart material with stimuli responsive surface for oily wastewater purification.

Study of hydrogen bonding interactions in ethylene glycol-water binary solutions by Raman spectroscopy.

EG (ethylene glycol) is a good model system for the study of the fundamental hydrogen bonds in aqueous solutions. Using Raman spectroscopy, we have investigated the EG volume fraction induced variation in the hydrogen bonding interactions and conformations of EG-H2O (water) binary solutions. New hydrogen bonding networks is evidenced by the appearance of remarkable changes in Raman spectra and the full width at half maximum (FWHM) when the mixing volume ratio is 0.5. The H-bond in water molecules firstly strengthened and then weakened with the increasing concentration of EG. Meanwhile, the dominant association structure also changed from H2O-H2O to EG-H2O in binary solutions in this process. We provide a simple but effective method for studying EG-H2O binary solutions. It also has exciting potential prospects and can be easily extended to other mixing situations.