[Gastric rupture as a complication of anorexia nervosa]. / Maagruptuur als complicatie van anorexia nervosa.

BACKGROUND: Anorexia nervosa may cause several gastro-intestinal complications. CASE DESCRIPTION: A 21-year-old woman presented herself with abdominal pain and vomiting a day after her first binge-eating episode. In her recent history she had lost 40 kg in weight and her BMI was 15 at presentation. Imaging showed gastric distension and ascites in all quadrants, suspicious of a gastric rupture. A blow-out of the stomach was seen during a diagnostic laparotomy, which was treated with a gastric sleeve procedure. Following surgery, the patient was diagnosed with anorexia nervosa of the restrictive type with a first episode of binge-eating. CONCLUSION: Gastric rupture is a rare and unknown complication of anorexia nervosa with a high mortality.

H and D attachment to naphthalene: spectra and thermochemistry of cold gas-phase 1-C10H9 and 1-C10H8D radicals and cations.

Excitation spectra of the 1H-naphthalene (1-C10H9) and 1D-naphthalene (1-C10H8D) radicals, and their cations, are obtained by laser spectroscopy and mass spectrometry of a skimmed free-jet expansion following an electrical discharge. The spectra are assigned on the basis of density functional theory calculations. Isotopic shifts in origin transitions, vibrational frequencies and ionization energies were found to be well reproduced by (time-dependent) density functional theory. Absolute bond dissociation energies, ionization energies and proton affinities were calculated using high-level quantum chemical methods.

Structure of the naphthalene dimer from rare gas tagging.

Excitation spectra of naphthalene dimer-argonn (n = 1-3) clusters are obtained by resonance enhanced multiphoton ionization time-of-flight mass spectroscopy. The spectra are generally independent of the number of attached argon atoms and reveal sharp structures which are fitted by superimposing independent monomer spectra. It is concluded that the rare-gas tagging technique reveals the presence of a T-shaped naphthalene dimer chromophore in the molecular beam.

Gas phase spectra of all-benzenoid polycyclic aromatic hydrocarbons: triphenylene.

The jet-cooled laser-induced fluorescence and dispersed fluorescence spectra of the S1(A1')<--S0(A1') transition of triphenylene are reported. The spectra exhibit false origins of e' symmetry which are modeled by performing calculations of Herzberg-Teller coupling using time-dependent density functional theory. It is found that this level of theory reproduces the main features of the observed spectra. The oscillator strength of the strongest band is calculated to be f=7x10(-4). From a combination of theory and the observed upper state lifetime of 41 ns, an estimate of the fluorescence yield is made of PhiF=0.084, in agreement with previous studies in the condensed phase.

Fully state-resolved photodissociation of formaldehyde, H2CO --> H + HCO:K conservation and a rigorous test of statistical theories.

The photodissociation dynamics of the reaction H2CO+hnu --> H + HCO have been investigated in the range 60-400 cm(-1) above the reaction threshold. Supersonically cooled formaldehyde was excited into 15 specific J, K(a), K, rotational states i n two vibrational lev el s 2(1) 4(1) 6(1) and 2(2) 4(1) in the A(1A2) state. The laser-induced fluorescence spectra of the nascent HCO fragment provided detailed product state distributions (PSDs), resolved by N, K(a), K(c), and J. When just the overall molecular rotation N is considered the PSDs are in remarkable agreement with calculations based on phase space theory (PST). However, when the projection of N onto the molecular frame (K(a),K(c)) is included the distributions show consistent deviations from PST. In particular, there is a tendency to preserve the initial parent rotational motion about the a and b axes. The effect is that states with higher initial K(a) in H2CO produce higher final K(a) in the HCO fragment. There is also a tendency for the upper/lower members of the asymmetry doublets in H2CO to map onto the same upper/lower set of product state asymmetry doublets. Finally, there are oscillations in some of the detailed PSDs that remain unexplained.