Guar gum/poly ethylene glycol/graphene oxide environmentally friendly hybrid hydrogels for controlled release of boron micronutrient.

The present study was aimed at synthesis of polymeric hydrogels for controlled boron (B) release, as B deficiency is a major factor that decreases crops yield. Thus, graphene oxide incorporated guar gum and poly (ethylene glycol) hydrogels were prepared using the Solution Casting method for boron release. 3-Glycidyloxypropyl trimethoxysilane (GLYMOL) was used as a cross-linker. Characterizations of hydrogels were carried out by Fourier Transform Infrared Spectroscopy (FTIR), Thermo-Gravimetric Analysis and Scanning Electron scope. The FTIR outcomes confirmed the existence of functional groups, bindings and development of hydrogel frameworks from incorporated components. The quantity of GLYMOL directly increased the thermal stability and water retention but decreased the swelling %. The maximum swelling for the hydrogel formulations was observed at pH 7. The addition of GLYMOL changed the diffusion from quasi-Fickcian to non-Fickcian diffusion. The maximum swelling quantities of 3822% and 3342% were exhibited by GPP (control) and GPP-8 in distilled water, respectively. Boron release was determined in distilled water and sandy soil by azomethine-H test using UV-Visible spectrophotometer while 85.11% and 73.65% boron was released from BGPP-16, respectively. In short, water retentive, water holding capacities, swelling performances, biodegradability and swelling/deswelling features would offer an ideal platform for boron release in sustained agricultural applications.

In-house fabrication of macro-porous biopolymeric hydrogel and its deployment for adsorptive remediation of lead and cadmium from water matrices.

A novel adsorbent was prepared by blending chitosan (CS) and acrylic acid (AA) while using formaldehyde as a cross linker in the form of hydrogel beads. The adsorption properties of these hydrogel beads for the removal of toxic metal ions (Pb2+ and Cd2+) from aqueous solutions were evaluated. The hydrogel beads have a 3D macro-porous structure whose -NH2 groups were considered to be the dominant binding specie for Cd and Pb ions. The equilibrium adsorption capacity (qe) of beads was significantly affected by the mass ratio of sorbent and sorbate. The percentage removal of Cd and Pb ions was observed to be enhanced with the increase in sorbate concentration. The hydrogel beads maintained good adsorption properties at adsorption-desorption equilibrium. The Langmuir and Freundlich models were used to elaborate the isotherms as well as isotherm constants. Adsorption isothermal data is well explained by the Freundlich model. The data of experimental kinetics is interrelated with the second-order kinetic model, which showed that the chemical sorption phenomenon is the rate limiting step. The results of intraparticle diffusion model described the adsorption process occurred on a porous substance that proved chitosan/Formaldehyde beads to be the favorable adsorbent.