Correction: Effect of support on hydrogen generation over iron oxides in the chemical looping process.

[This corrects the article DOI: 10.1039/D1RA07210B.].

Effect of support on hydrogen generation over iron oxides in the chemical looping process.

Fe2O3 is recognized as an excellent oxygen carrier for its low cost and high oxygen capacity. However, pure Fe2O3 must be deposited on supports to ensure high reactivity and durability. Here, we proposed several Fe2O3-based oxygen carriers using MgAl2O4, Ce0.8Gd0.2O1.9, and Zr0.8Y0.2O1.9 as supports and investigated their performance for chemical looping hydrogen generation. The support effect on chemical looping hydrogen generation performance was evaluated, and the fundamental insights were investigated in depth. Fe2O3/Ce0.8Gd0.2O1.9 exhibited a superior performance regarding high hydrogen yield and stable trend over 20 cycles at 750 °C. However, hydrogen yield of Fe2O3/Zr0.8Y0.2O1.9 exceeded that of Fe2O3/Ce0.8Gd0.2O1.9 at higher temperatures (850 °C). Characterizations show that Ce0.8Gd0.2O1.9 exhibits the highest oxygen vacancy concentration, which significantly improves the reduction and reoxidation reactions of Fe2O3, thus leading to an enhanced hydrogen yield. However, the interaction between Fe2O3 and Ce0.8Gd0.2O1.9 contributed to the increase in Fe2+ concentration, thus decreasing the oxygen capacity during the redox cycle and contributing to the declined hydrogen yield at higher temperatures. This work highlights the potential of Ce0.8Gd0.2O1.9 to be used as an effective support for Fe2O3 at mid-temperatures. We hope that the support effect in this work can be extended to design and select more active and durable oxygen carriers.

[Effects of Remedies on the Remediation of Typical Pb and Zn-contaminated soil in Huanjiang, Guangxi].

Due to the collapse of the Pb/Zn tailing dam of Huanjiang, Guangxi, the farmland along Huanjiang River are strongly acidic and heavy metal-contaminated, resulting in the loss of agricultural production. To explore some remedies and the migration of heavy metals in heavy metal contaminated-soil of Huanjiang, this study investigated the effects of different types of amendments (lime, calcium magnesium phosphate, organic fertilizer, polypropylene amide) on tested soils through soil leaching test. The results showed that T1 soil was severely acidified, reducing the pH of the soil layer to clean contact, while T2, T3, T4, T5 could significantly improve the contaminated soil pH, ranging from 2.7 to 3.2, 1.6 to 2.7 respectively. Compared with T1, in the contaminated soil at 0-20 cm, T2, T3, T4, T5 could effectively activate Pb and immobilize Zn. Compared with T1, in 20-60 cm clean soil, there was no significant differences in the effect of different treatments on DTPA-Pb and DTPA-Zn (P < 0.05). Compared with T1, T4 and T5 could provide good growing conditions for plants, which might provide technical support for future measurements such as bioremediation.