Efficient removal of Hg0 from cement kiln flue gas using CexFeyOz composite catalyst.

In this study, a kind of CexFeyOz composite with oxygen vacancy structure and strong oxygen storage capacity was prepared by coprecipitation method. Under the condition of no HCl of flue gas, the Hg0 in the flue gas of cement kiln was efficiently and economically removed by using 6-8% oxygen. The results showed that the optimum preparation conditions of the catalyst were Ce-Fe molar ratio of 1-11 and calcination temperature of 550 °C. In addition, the reaction temperature, space velocity, the concentration of O2, SO2, and NO had significant effects on the removal efficiency of Hg0 at different rates. More precisely, at the reaction temperature of 350 °C, low airspeed, high concentration of O2, and low concentration of SO2 and NO, the efficiency reached the highest value. According to XPS results, the elemental valence of the CexFeyOz composite changed after the reaction. The redox pairs of Ce3+-Ce4+ and Fe3+-Fe2+ had the ability to transfer electrons, which enabled more oxygen adsorbed on the catalyst surface to be converted into O2-, leading to the improvement of the oxidation efficiency of Hg0.

Enhancement of ethylbenzene removal from contaminated gas and corresponding mechanisms in biotrickling filters by a biosurfactant from piggery wastewater.

This study prepared a biosurfactant by using piggery wastewater to enhance ethylbenzene removal from contaminated gas in a biotrickling filter (BTF). Experiments were conducted to investigate the enhancement of ethylbenzene removal and the biofilm characteristics in present of the biosurfactant. Results demonstrated that the optimal biosurfactant concentration was 0.1 CMC and the corresponding ethylbenzene removal rate was 87.2%, much higher than that (68.9%) achieved in free of biosurfactant. The inlet ethylbenzene concentration and the empty bed residence time (EBRT) affected ethylbenzene removal as well. In present of 0.1 CMC of biosurfactant, ethylbenzene removal rate decreased from 87.2% to 72.2% with the increasing inlet ethylbenzene from 1000 to 2200 mg/m3, and decreased from 91.1% to 42.7% with the EBRT shorten from 30 to 7.5 s. For the enhancement mechanisms of ethylbenzene removal in BTF, the biosurfactant changed the contents of extracellular polymers (EPS) and decreased negative surface charge of the biofilm in the BTF, which improved the mass transfer of ethylbenzene to biofilm and facilitated the aggregation of microbes, and further improved the removal of ethylbenzene. All in all, the biosurfactant would be a feasible way to enhance the removal of ethylbenzene by the BTF.

The Patatin-Like Phospholipase Domain Containing Protein 7 Facilitates VLDL Secretion by Modulating ApoE Stability.

BACKGROUND AND AIMS: The regulation of hepatic very-low-density lipoprotein (VLDL) secretion is vital for lipid metabolism whose pathogenetic status is involved in fatty liver disease and dyslipidemia seen in hepatic steatosis. Accumulated evidence suggest that apolipoprotein E (ApoE) is closely related to hepatic VLDL secretion. Here, we report that the expression of patatin-like phospholipase domain containing protein 7 (PNPLA7) is strongly induced by hepatic steatosis and positively correlates with plasma triacylglycerol (TAG) levels in the human subjects, whereas the role of PNPLA7 in hepatic VLDL secretion is unknown. APPROACH AND RESULTS: Herein, with genetic manipulation in the mice, the deficiency of hepatic PNPLA7 expression resulted in reduced VLDL secretion accompanied by enhanced hepatic lipid accumulation and decreased hepatic ApoE expression. Furthermore, knockdown of PNPLA7 in the livers of the db/db mice also resulted in significant reduction in plasma TAG level but aggravated hepatic steatosis. Importantly, we observed that PNPLA7 interacted with ApoE and presumably at the site of endoplasmic reticulum. Mechanistically, we have shown that PNPLA7 could modulate polyubiquitination and proteasomal-mediated degradation of ApoE. Overexpressed ApoE restored the impaired VLDL-TAG metabolism in PNPLA7-knockdown primary hepatocytes. CONCLUSION: PNPLA7 plays a critical role in regulating hepatic VLDL secretion by modulating ApoE stability through its interaction with ApoE.

Rice straw biochar modified by aluminum chloride enhances the dewatering of the sludge from municipal sewage treatment plant.

Enhancement of the dewatering of the sludge by using rice straw biochar (RSB) modified by aluminum chloride (AlCl3) was investigated, and the possible enhancing mechanisms were discussed. Results showed that the settled volume after 30 min (SV30%), specific resistance to filtration (SRF), moisture content (MC) and capillary suction time (CST) of the sludge were decreased and the net sludge solids yield (YN) was increased by the increasing raw or modified RSB, which indicated a higher sludge dewaterability. When the dosage of the modified RSB was adjusted to 0.3 g(RSB)/g(dry sludge), SV30%, SRF, MC and CST were decreased to 79.8%, 1.2 × 1012 m/kg, 81.4% and 38 s, respectively, YN was increased to 19.4 kg/(m2·h). Furthermore, performance of the modified RSB in the dewatering of the sludge was significantly better than that of the raw RSB. For the enhancing mechanisms, charge neutralization occurred when the modified RSB (loaded with positively charged aluminum species on its surface) was dosed into the sludge system, thus destroying the stable sludge colloidal system, thus far easier to congregate the sludge particles, which enhanced the dewatering of the sludge. Another main enhancing mechanism was that after conditioned by the modified RSB, certain skeleton structures were formed in sludge cake to make water pass through easily by decreasing the extracellular polymeric substances (EPS) of the sludge. We found that the effectiveness of using the modified RSB to enhance the dewatering of the sludge is substantial and promising.