Hydroxyapatite Derived from Salmon Bone As Green Ecoefficient Support for Ceria-Doped Nickel Catalyst for CO2 Methanation.

Hydroxyapatite (HA) derived from salmon bone byproducts is used as a green support for the nanostructured nickel catalysts applied in the methanation of carbon dioxide (CO2). Undoped nickel catalysts and various ceria-doped nickel supported on hydroxyapatite (HA) were prepared by coimpregnation. Characteristics of the as-prepared catalysts were investigated by the various techniques, including X-ray diffraction (XRD), scanning electron microscopy (SEM), Brunauer-Emmett-Teller (BET), hydrogen temperature-programmed reduction (H2-TPR), carbon dioxide temperature-programmed desorption (CO2-TPD), and energy-dispersive X-ray spectroscopy (EDX). The catalyst activity was assessed throughout CO2 methanation in the low-temperature range of 225-350 °C with the molar ratio of H2/CO2 = 4/1. The function of HA and ceria provided a high dispersity of nickel particles over the catalyst surface with the size range of 24.5-25.8 nm, leading to improvement in the reduction and CO2 adsorption capacity of the catalysts as well as enhancing the catalytic efficiency in CO2 methanation. The 10Ni/HA catalyst reduced at suitable conditions of 400 °C for 2 h showed the highest catalytic performance among the tested catalysts. CO2 conversion and CH4 selectivity reached 76.6 and 100% at a reaction temperature of 350 °C, respectively. The results show that the Ni/HA sample doped with 6.0 wt % ceria was the best, with the CO2 conversion and the CH4 selectivity reaching 92.5% and 100%, respectively, at a reaction temperature of 325 °C.

Synthesis, Characteristics, Oil Adsorption, and Thermal Insulation Performance of Cellulosic Aerogel Derived from Water Hyacinth.

Cellulosic aerogel from water hyacinth (WH) was synthesized to address the dual environmental issues of water hyacinth pollution and the production of a green material. Raw WH was treated with sodium hydroxide (NaOH) with microwave assistance and in combination with hydrogen peroxide (H2O2). The results from X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, and scanning electron microscopy (SEM) showed that lignin and hemicellulose were markedly decreased after treatment, reducing from 24.02% hemicellulose and 5.67% lignin in raw WH to 8.32 and 1.92%, respectively. Cellulose aerogel from the pretreated WH had a high porosity of 98.8% with a density of 0.0162 g·cm-3 and a low thermal conductivity of 0.030 W·m-1·K-1. After modification with methyl trimethoxysilane (MTMS) to produce a highly hydrophobic material, WH aerogel exhibited high stability for oil absorption at a capacity of 43.3, 43.15, 40.40, and 41.88 (g·g-1) with diesel oil (DO), motor oil (MO), and their mixture with water (DO + W and MO + W), respectively. The adsorption remained stable after 10 cycles.