Electrospun microcrystalline cellulose/chitosan porous composite nanofibrous membranes modified by non-thermal plasma for gaseous formaldehyde adsorption.

To develop a green and facile adsorbent for removing indoor polluted formaldehyde (HCHO) gas, the biomass porous nanofibrous membranes (BPNMs) derived from microcrystalline cellulose/chitosan were fabricated by electrospinning. The enhanced chemical adsorption sites with diverse oxygen (O) and nitrogen (N)-containing functional groups were introduced on the surface of BPNMs by non-thermal plasma modification under carbon dioxide (CO2) and nitrogen (N2) atmospheres. The average nanofiber diameters of nanofibrous membranes and their nanomechanical elastic modulus and hardness values decreased from 341 nm to 175-317 nm and from 2.00 GPa and 0.25 GPa to 1.70 GPa and 0.21 GPa, respectively, after plasma activation. The plasma-activated nanofibers showed superior hydrophilicity (WCA = 0°) and higher crystallinity than that of the control. The optimal HCHO adsorption capacity (134.16 mg g-1) of BPNMs was achieved under a N2 atmosphere at a plasma power of 30 W and for 3 min, which was 62.42 % higher compared with the control. Pyrrolic N, pyridinic N, CO and O-C=O were the most significant O and N-containing functional groups for the improved chemical adsorption of the BPNMs. The adsorption mechanism involved a synergistic combination of physical and chemical adsorption. This study provides a novel strategy that combines clean plasma activation with electrospinning to efficiently remove gaseous HCHO.

The influence of torrefaction on pyrolysed biomass: The relationship of bio-oil composition with the torrefaction severity.

In this study, three types of biomass were torrefied at different times (0.5, 1, 1.5 h) and temperature (200, 240, 280, 320 °C), which were further pyrolyzed at 550 °C after torrefaction. CEI (carbon element index), which was established based on the carbon content of the torrefied biomass, was chosen as an indicator for reflecting torrefaction severity. The results showed that there was a curvilinear relationship between CEI and the physicochemical characteristics, energy recovery of torrefied biomass, which obtained an average goodness of fit was higher than 0.93. Moreover, the goodness of fit between CEI and pyrolysis carbon and bio-oil yield was higher than 0.95 and 0.91, respectively. Especially, the bio-oil composition and CEI were fitted by a quadratic function (y = a + bx + cx2). Based on the function, the yield of phenols could be predicted based on the CEI value, which would benefit for the preparation of higher quality bio-oil directionally.

High yield self-nitrogen-oxygen doped hydrochar derived from microalgae carbonization in bio-oil: Properties and potential applications.

In this work, the high yield self-N-O doped hydrochar had been prepared through the hydrothermal carbonization of microalgae in the aqueous bio-oil. The effects of temperature, residence time and the ratio of Chlorella and bio-oil on the solid yield were investigated. The results showed that the hydrochar had excellent thermal stability and abundant nitrogen and oxide functional groups, its solid yield reached 199.33%. After activated by KOH at high temperature, the hydrochar was transformed into a porous carbon material with high nitrogen content. The porous carbon showed high CO2 absorption of 5.57 mmol/g at 0 °C and 1 bar. It also exhibited a high specific capacitance of 216.6F/g at 0.2 A/g and a good electrochemical stability with 88% capacitance retention after consecutive 5000 cycles.