1.
Chem Commun (Camb)
; 55(100): 15085-15088, 2019 Dec 28.
Artigo
em Inglês
| MEDLINE
| ID: mdl-31781704
RESUMO
We demonstrate that PdAu single-atom alloy model catalysts offer a heterogeneous route to selective Würtz-type C-C coupling. Specifically, when methyl iodide is exposed to an otherwise unreactive Au(111) surface, single Pd atoms in the surface layer promote C-I dissociation and C-C coupling, leading to the selective formation of ethane.