Impact of Saharan dust exposure on airway inflammation in patients with ischemic heart disease.

Epidemiological studies found that increases in the concentrations of airborne particulate matter (PM) smaller than 10 microns diameter (PM10) in the ambient air due to desert dust outbreaks contribute to global burden of diseases, primarily as a result of increased risk of cardiovascular morbidity and mortality. No studies have investigated the possible association between desert dust inhalation and airway inflammation in patients with ischemic heart disease (IHD). Induced sputum was collected in 38 patients and analyzed to determine markers of airway inflammation (Transforming Growth Factor-ß1 [TGF-ß1] and hydroxyproline) concentrations. For the purpose of the investigation, PM10 and reactive gases concentrations measured in the European Air Quality Network implemented in the Canary Islands were also used. We identified Saharan desert dust using meteorology and dust models. Patients affected by smoking, chronic obstructive pulmonary disease (COPD), asthma, pulmonary abnormalities, acute bronchial or pulmonary disease were excluded. The median of age of patients was 64.71 years (56.35-71.54) and 14 (38.84%) of them were women. TGF-ß1 and hydroxyproline in sputum were highly associated to PM10 inhalation from the Saharan desert. According to a regression model, an increase of 1 µg/m3 of PM10 concentrations due to desert dust, results in an increase of 3.84 pg/gwt of TGF-ß1 (R2 adjusted = 89.69%) and of 0.80 µg/gwt of hydroxyproline (R2 adjusted = 85.28%) in the sputum of patients. The results of this study indicate that the exposure to high PM10 concentrations due to Saharan dust events are associated with intense inflammatory reaction in the airway mucosae of IHD-patients.

Monitoring of meso and microplastic debris in Playa Grande beach (Tenerife, Canary Islands, Spain) during a moon cycle.

The occurrence and composition of meso (5-25 mm) and microplastics (1-5 mm) in Playa Grande beach (Tenerife, Canary Islands, Spain) was monitored during a complete moon cycle on the different moon phases between 17th June and 16thJuly 2019. A total of 10 points were sampled each day finding an average content of mesoplastics of 18 g/m2 (0.36 g/L) and of microplastics of 13 g/m2 (1277 items/m2 or 1.6 g/L). Polypropylene and polyethylene accounted for 19% and 76% of the total, respectively. Tar was also found in the 1-5 mm fraction (2% of the total). Among the particles found, 83% were fragments, 11% pellets, 4% fibres and 2% films. The obtained results revealed that microplastic presence could not be related in this case with the tides but with the orientation and strength/speed of the wind.

Microplastic debris in beaches of Tenerife (Canary Islands, Spain).

The occurrence and composition of microplastics (1-5 mm) was evaluated in six beaches of the island of Tenerife (Canary Islands, Spain). Two of them were located at the North coast (El Socorro and San Marcos) and the rest in the South littoral (Leocadio Machado, El Porís, Los Abriguitos and Playa Grande). Sampling was developed during the months of October, November and December 2018 (depending on the beach) above the high tide line. Isolated microplastics were identified by attenuated total reflection infrared spectroscopy. All the beaches showed a relatively low content of microplastics, below 3.5 g/m2, which is also below 0.069 g/L of sand, except for Playa Grande, which showed an average content of 99 g/m2 or 2.0 g/L of sand. Tar pollution (around 18%) was also found in Playa Grande. The major polymers found were polyethylene, polypropylene and polystyrene, accounting for 69%, 18% and 4%, respectively.

Developing qualitative extraction profiles of coffee aromas utilizing polymeric ionic liquid sorbent coatings in headspace solid-phase microextraction gas chromatography-mass spectrometry.

Two solid-phase microextraction (SPME) sorbent coatings based on polymeric ionic liquids (PILs) have been utilized for the analysis of complex coffee aroma samples. The PIL-based SPME coatings examined, namely, poly(1-(4-vinylbenzyl)-3-hexadecylimidazolium bis[(trifluoromethyl)sulfonyl]imide) [poly(VBHDIm(+) NTf(2)(-))], with ~14-µm thickness, and poly(1-vinyl-3-hexylimidazolium chloride) [poly(ViHIm(+)Cl(-))], with ~8-µm thickness, were employed for the headspace determination of up to 49 analytes from four different coffee beans: two French roast coffees of different brands, Sumatra coffee, and decaffeinated Sumatra coffee. The analysis was conducted using gas chromatography coupled to mass spectrometry. For comparative purposes, the commercial polyacrylate (PA, 85-µm film thickness) SPME coating was utilized under the same extraction conditions. The three SPME coatings tested behaved quite differently as a function of the families of compounds extracted. Thus, the poly(VBHDIm(+) NTf(2)(-) ) coating was extremely selective for aldehydes while also exhibiting good extraction efficiencies for acids. The poly-(ViHIm(+) Cl(-)) coating exhibited superior performance for aromatic alcohols, and the PA coating worked better for heterocyclic aromatics. Both PIL-based SPME sorbent coatings demonstrated exceptional selectivity and extraction efficiency when dealing with complex coffee aromas in spite of their small film thicknesses.

Utilization of a benzyl functionalized polymeric ionic liquid for the sensitive determination of polycyclic aromatic hydrocarbons; parabens and alkylphenols in waters using solid-phase microextraction coupled to gas chromatography-flame ionization detection.

The functionalized polymeric ionic liquid poly(1-(4-vinylbenzyl)-3-hexadecylimidazolium bis[(trifluoromethyl)sulfonyl]imide (poly(VBHDIm(+)NTf(2)(-))) has been used as successful coating in solid-phase microextraction (SPME) to determine a group of fourteen endocrine disrupting chemicals (ECDs), including polycyclic aromatic hydrocarbons (PAHs), alkylphenols, and parabens, in several water samples. The performance of the PIL fiber in direct immersion mode SPME followed by gas chromatography (GC) with flame-ionization detection (FID) is characterized with average relative recoveries higher than 96.1% from deionized waters and higher than 76.7% from drinking bottled waters, with precision values (RSD) lower than 13% for deionized waters and lower than 14% for drinking bottled waters (spiked level of 1 ng mL(-1)), when using an extraction time of 60 min with 20 mL of aqueous sample. Detection limits varied between 9 ng L(-1) and 7 ng mL(-1). A group of real water samples, including drinking waters, well waters, and swimming pool waters, have been analyzed under the optimized conditions. A comparison has also been carried out with the commercial SPME coatings: polydimethylsyloxane (PDMS) 30 µm, and polyacrylate (PA) 85 µm. The functionalized PIL fiber (∼12 µm) demonstrated to be superior to both commercial fibers for the overall group of analytes studied, in spite of its lower coating thickness. A normalized sensitivity parameter is proposed as a qualitative tool to compare among fiber materials, being higher for the poly(VBHDIm(+)NTf(2)(-)) coating. Furthermore, the partition coefficients of the studied analytes to the coating materials have been determined. A quantitative comparison among the partition coefficients also demonstrates the superior extraction capability of the functionalized PIL sorbent coating.