1.
Org Biomol Chem
; 21(15): 3096-3100, 2023 Apr 12.
Artigo
em Inglês
| MEDLINE
| ID: mdl-36974750
RESUMO
Activated vinylcyclopropanes can form zwitterionic π-allylmetal species in the presence of transition metals and are widely used in organic synthesis. A nickel-catalyzed asymmetric allylation of secondary phosphine oxides with vinylcyclopropanes was described. Tertiary phosphine oxide products could be obtained with up to 91% yield and 92% ee.