A review on water treatment technologies for the management of oxoanions: prospects and challenges.

Oxoanions are a class of contaminants that are easily released into the aquatic systems either through natural or anthropogenic activities. Depending on their oxidation states, they are highly mobile, resulting in the contamination of underground water. Above the permissible level in groundwater, they pose as threats to mammals when the contaminated water is consumed. Some of the health challenges caused are cancer, neurological, cardiac, gastrointestinal, and skin disorders. Several treatment technologies have been adopted over the years for the management of these oxoanions present in the aquatic systems. However interesting these treatment technologies might be, they also have their limitations such as cost-effectiveness, the complexity of the process, and generation of secondary pollutants. This work focused on some of the water treatment technologies applied for the removal of oxoanions. Some of the advantages and disadvantages of these treatment technologies are also highlighted. Amongst all the treatment technologies, adsorption is the most applied method for the removal of oxoanions. However, photocatalysis has a higher prospect since it is non-selective and secondary pollutants are not generated after the treatment process. Also, photocatalysis can simultaneously reduce and oxidise oxoanions as well as organic pollutants respectively.

Unraveling bacterial diversity in oil refinery effluents.

Oil refinery effluents are among stressful environments, and they are characterized by alkaline pH, high concentrations of dissolved solids, electrical conductivity, and metals (mainly Fe, Al, B, Sr, Mn, Cu, Ni). In this study, bacterial diversity in these habitats was inferred from full-length 16S rRNA gene sequences obtained from the PacBio® sequencing platform. The results have shown low bacterial diversity in both raw and treated effluents, with sequences representing only two phyla: Firmicutes and Proteobacteria. Sequences from the raw effluents represent four major genera: Bacillus, Wenzhouxiangella, Rhodabaculum, and Halomonas. Whilst bacterial communities from the treated effluents are relatively more diverse as sequences represent five dominant genera: Pseudoxanthomonas, Brevundimonas, Pseudomonas, Rhodobaculum and Rhizobium. Most of the genera represented in the dataset are halophilic or halotolerant microbes known to have the competency to catabolize a broad spectrum of organic and inorganic pollutants. Hypothetically, these bacteria may be relevant for biotechnological and industrial applications, particularly for the remediation of saline industrial wastes.

The impact of microbial ecology and chemical profile on the enhanced biological phosphorus removal (EBPR) process: a case study of Northern Wastewater Treatment Works, Johannesburg.

The impact of polyphosphate-accumulating organism (PAO) and glycogen-accumulating organism (GAO) populations as well as of the chemical profile on the performance of Unit-3 (open elutriation tanks) and Unit-5 (covered elutriation tank) of the City of Johannesburg Northern Wastewater Treatment Works was determined. Physicochemical parameters of wastewater samples were measured using standard methods. Bacterial diversity was determined using 16S rRNA gene amplicon pyrosequencing of the variable region V1-3. Results showed soluble COD concentrations from settled sewage for Unit-3 at 192.8 mg COD/L and for Unit-5 at 214.6 mg COD/L, which increased to 301.8 mg COD/L and 411.6 mg COD/L in the overflow from elutriation tanks and decreased to 170.9 mg COD/L and 256.3 mg COD/L at the division boxes, respectively. Both long-chain volatile fatty acids (heptanoic acid, isobutyric acid, 3-methylbutanoic acid, pentanoic acid, 4-methylpentanoic acid, methylheptanoic acid) and short-chain volatile fatty acids (acetic acid, propionic acid, isobutyric acid) were present within concentration ranges of 17.19 mg/L to 54.98 mg/L and 13.64 mg/L to 87.6 mg/L for Unit 3 and 38.61 mg/L to58.85 mg/L and 21.63 mg/L to 92.39 mg/L for Unit 5, respectively. In the secondary settling tanks, the phosphate-removal efficiency in Unit-5 appeared to be slightly higher (0.08 mg P/L) compared to that of Unit-3 (0.11 mg P/L). The average DO concentrations (2.1 mg/L and 2.2 mg/L) as well as the pH values (pH 7 to pH 7.5) were found to be slightly higher in Unit-5 in the aerobic zones. The high presence of PAOs in the bioreactors (Unit-5: Dechloromonas (14.96%), Acinetobacter (6.3%), Zoogloea (4.72%) in the anaerobic zone and Dechloromonas (22.37 %) in the aerobic zone; Unit-3: Dechloromonas (37.25%) in the anaerobic zone and Dechloromonas (23.97%) in the aerobic zone) confirmed the phosphate-removal efficiencies of both units. Negligible GAOs were found in the aerobic zones (Defluviicoccus spp.: 0.33% for Unit-5 and 0.68% for Unit-3) and in the anaerobic zones (Defluviicoccus: 9.8% for Unit-3). The high microbial diversity and a negligible percentage of GAOs in Unit-5 could contribute to its high phosphate-removal efficiency, although results did not indicate statistically significant differences between the unit with a covered elutriation tank (Unit-5) and that with open elutriation tanks (Unit-3).