Mechanistic vision on polypropylene microplastics degradation by solar radiation using TiO2 nanoparticle as photocatalyst.

Microplastics are emerging contaminants owing to their occurrence and distribution in everywhere the ecosystem and leading to major environmental problems. Management methods are more suitable for larger-sized plastics. Here, the current study elucidates that, TiO2 photocatalyst under sunlight irradiation actively mitigates polypropylene microplastics (pH 3, 50 h) in an aqueous medium. End of post-photocatalytic experiments, the weight loss percentage of microplastics was 50.5 ± 0.5%. Fourier transforms infrared (FTIR) and nuclear magnetic resonance spectroscopy (1H NMR) spectroscopy results revealed the formation of peroxide and hydroperoxide ions, carbonyl, keto and ester groups at the end of the post-degradation process. Ultraviolet-Visible Diffuse Reflectance spectroscopic (UV - DRS) results showed variation in the optical absorbance of polypropylene microplastics peak values at 219 and 253 nm. Increased the weight percentage of oxygen level due to the oxidation of functional groups and decreased the weight percentage of carbon content in electron dispersive spectroscopy (EDS), probably owing to breakdown of long-chain polypropylene microplastics. In addition, scanning electron microscopy (SEM) microscopic analysis showed the surface having holes, cavities, and cracks on irritated polypropylene microplastics. The overall study and their mechanistic pathway strongly confirmed the formation of reactive oxygen species (ROS) with help of the movement of electrons by photocatalyst under solar irradiation which aids the degradation of polypropylene microplastics.

Biochemical, Genotoxic and Histological Implications of Polypropylene Microplastics on Freshwater Fish Oreochromis mossambicus: An Aquatic Eco-Toxicological Assessment.

In recent years, polypropylene microplastic has persisted in freshwater ecosystems and biota, forming ever-growing threats. This research aimed to prepare polypropylene microplastics and evaluate their toxicity to the filter feeder Oreochromis mossambicus. In this research, fish were given a dietary supplement of polypropylene microplastics at 100, 500, and 1000 mg/kg for acute (96 h) and sub-acute (14 days) durations to assess toxic effects on liver tissues. FTIR results revealed the presence of polypropylene microplastic in their digestion matter. The ingestion of microplastics in O. mossambicus led to fluctuations in homeostasis, an upsurge in reactive oxygen species (ROS) levels, an alteration in antioxidant parameters, including superoxide dismutase (SOD), catalase (CAT), glutathione-S-transferase (GST), and glutathione peroxidase (GPx); a promotion in the oxidation of lipid molecules; and a denaturation in the neurotransmitter enzyme acetylcholinesterase (AChE). Our data indicated that sustained exposure to microplastics (14 days) produced a more severe threat than acute exposure (96 h). In addition, higher apoptosis, DNA damage (genotoxicity), and histological changes were found in the liver tissues of the sub-acute (14 days) microplastics-treated groups. This research indicated that the constant ingestion of polypropylene microplastics is detrimental to freshwater environments and leads to ecological threats.

N-phenyl-1-naphthylamine/ß-cyclodextrin inclusion complex as a new fluorescent probe for rapid and visual detection of Pd(2+).

Inclusion complex between N-phenyl-1-naphthylamine (NPN) and ß-cyclodextrin (ß-CD) was studied by FT-IR, (1)H and 2D NMR, XRD, FT-Raman, SEM and DSC techniques. The formation of 1:1 stoichiometric inclusion complex of NPN with ß-CD was proposed based on the Nuclear magnetic resonance spectroscopy and Molecular docking study. The molecular encapsulation of host-guest inclusion complex based on simple chemosensor has high selectivity and sensitivity for the determination of Pd(2+) ion. Host-guest inclusion complex as a spectroscopic probe is used for the detection of transition metal cation Pd(2+). Coordination of this Pd(2+) with (NPN/ß-CD) inclusion complex exhibited a noticeable color change in the solution state it used for naked-eye detection.