RESUMO
Solar steam generation is an efficient way of harvesting solar energy for water purification. Developing a versatile solar absorber with salt resistance and the capability to purify an oil-in-water emulsion is a grand challenge. Herein, a polypropylene (PP) nonwoven fabric-based photothermal absorber is fabricated by the combination of carbon nanotubes (CNTs), polypyrrole (PPy), and a fluorinated hydrophobic coating in a layer-by-layer approach. The specially designed architecture displays a hierarchical microstructure and Janus wetting properties, facilitating solar absorption and heat generation on the evaporation surface, and can effectively prevent salt crystallization. The water layer formed on the superhydrophilic/underwater superoleophobic bottom surface could repel oil droplets and form a channel to advect concentrated salt back into bulk water, which enabled high purity separation of an oil-in-water emulsion and continuous desalinization of seawater without the reduction of the evaporation rate. As a result, the solar absorber can achieve a remarkable evaporation rate of 1.61 kg m-2 h-1 and an energy efficiency of 91.2% under 1 sun irradiation and shows extraordinary performance in the purification of contaminated wastewater (over 99.8% purity). The strategy proposed provides a pathway for developing versatile high-performance solar absorbers for the sustainable treatment of saline water, wastewater, and oil-containing water.
RESUMO
High-performance low-cost superhydrophobic sponges are desired for selective recycling of leaking oils from open water. Herein, an ingenious method is proposed to fabricate an ultrathin superhydrophobic coating layer on a commercial sponge. The coating layer is composed of a shish-kebab-structured porous ultrahigh molecular weight polyethylene (UHMWPE) film that is fabricated from a UHMWPE/xylene solution by shear flow-induced crystallization. A strong relationship between the shish-kebab crystallite morphology and the superwetting performance is confirmed. The UHMWPE coating layer fabricated at a 900 rpm rotation rate possesses a lamellae size of 95.1 nm and a lamellae distance of 27.4 nm, which lead to a high water contact angle of 157° and a low contact angle hysteresis of 4.5°. The UHMWPE layer prepared in 4 min of treatment is thick enough to prevent the intrusion of water even under vacuum and remain superoleophilic. The developed UHMWPE-coated sponge (UCS) exhibited a high absorption capability of 70-191 g/g toward various oils and solvents, which is comparable with the neat melamine sponge. Its excellent compressibility and durability enabled fast recovery of absorbed oil with a high recovery rate (over 85%) by mechanical squeezing. The UCS could be assembled into small devices to selectively collect oil from open water and a water/oil mixture using a pump, which manifests its promising practical applicability. Apart from these extraordinary properties, the approach developed has the lowest material cost and the shortest processing time hitherto.