RESUMO
Highly conductive carbon-based fibrous composites have become one of the most sought-after components in the field of electromagnetic interference (EMI) shielding due to their excellent comprehensive performance. In this work, a flexible nonwoven fabric consisting of carbon fibers (CFs) and polypropylene/polyethylene (PP/PE) core/sheath bicomponent fibers (ESFs), known as CEF-NF, is introduced into the graphene (GE)/poly(vinylidene fluoride) (PVDF) nanocomposite obtained by a solution casting method to fabricate a CEF-NF/GE/PVDF film. Disparate microstructures can be clearly observed in CEF-NF/GE/PVDF films with different graphene contents. Thanks to an internal porous network structure formed when the graphene content is high, this film exhibits better electrical conductivity. In the frequency range of 30-1500 MHz, this film can achieve a significantly high EMI shielding effectiveness (EMI-SE) value of about 48.5 dB at tiny thickness and density (1731.40 dB cm2 g-1), which are far better than many competitive materials. Moreover, this film exhibits adequate tensile strength and excellent flexibility, as the film's structural form can be retained even after multiple folding processes. In addition, by combining two-dimensional (2D) graphene and one-dimensional (1D) CF, the CEF-NF/GE/PVDF film achieves a remarkable in-plane thermal conductivity of 25.702 W m-1 K-1, making it an exceptional heat conductor. In summary, our results demonstrate that CEF-NF/GE/PVDF film is an excellent EMI shielding material that is light weight, highly flexible, and mechanically robust with outstanding thermal conductivity, which positions it superbly for applications in next-generation commercial portable electronics.
RESUMO
We report a NO2 gas sensor based on germanium quantum dots (GeQDs)/graphene hybrids. Graphene was directly grown on germanium through chemical vapor deposition and the GeQDs were synthesized via molecular beam epitaxy. The samples were characterized by atomic force microscope, Raman spectra, scanning electron microscope, x-ray photoelectron spectroscope and transmission electron microscope with energy dispersive x-ray. By introducing GeQDs on graphene, the gas sensor sensitivity to NO2 was improved substantially. With the optimization of the growth time of GeQDs (600 s), the response sensitivity to 10 ppm NO2 can be as high as 3.88, which is 20 times higher than that of the graphene sensor without GeQDs decoration. In addition, the 600 s GeQDs/graphene hybrid sensor exhibits fast response and recovery rates as well as excellent stability. Our work may provide a new route to produce low-power consumption, portable, and room temperature gas sensor which is amenable to mass production.