Comparison of adsorption properties for cadmium removal from aqueous solution by Enteromorpha prolifera biochar modified with different chemical reagents.

Using biochar to remove heavy metals from water is environmentally beneficial. In this study, three kinds of chemical reagents, including ZnCl2, H3PO4 and KMnO4, were introduced to modify the biochar derived from Enteromorpha prolifera. The performance of these modified biochar in removing Cadmium ions (Cd(II)) from water was investigated. The physicochemical properties of activated biochars were characterized by N2-sorption, thermal gravity and differential thermal gravity (TG/DTG), scanning electron microscopy (SEM), elemental analysis and Fourier transform infrared spectroscopy (FTIR). The results showed that the removal rate of Cd(II) from water by EP biochar modified with H3PO4 was significantly increased, and the maximum adsorption capacity of Cd(II) reached to 423 mg/g for PBC. Moreover, the adsorption of Cd(II) from water by phosphoric acid modified biochar was very fast, and the saturation adsorption of Cd(II) was reached within 1 h. Compared with pseudo first-order model, pseudo secondary-order model was much more suitable for analyzing the adsorption kinetics data of Cd(II) onto KBC or ZBC. The adsorption of Cd(II) onto PBC was analyzed by the intra-particle diffusion kinetic model, where the value of R2 was high as 0.98. The Langmuir model was fit for phosphoric acid modified biochar.

Inhibition of oil digestion in Pickering emulsions stabilized by oxidized cellulose nanofibrils for low-calorie food design.

Celluloses are renewable and biodegradable natural resources. The application of celluloses as oil-in-water Pickering emulsifiers is still quite limited. In this paper, cellulose nanofibrils (CNFs) with oxidation degrees (DOs) of 52.8% and 92.7% (DO50 and DO90) were obtained from TEMPO-mediate oxidation for microcrystalline cellulose (MC). The production of carboxyl groups of CNFs were confirmed by FT-IR and 13C solid-NMR. CNF-stabilized O/W Pickering emulsion showed excellent colloidal stability compared with un-oxidized cellulose by Turbiscan stability analysis. Additionally, CNF-stabilized Pickering emulsions showed stable colloidal properties in simulated intestinal fluid (SIF). Most importantly, in vitro fatty acid release kinetics under SIF showed that CNFs have strong inhibitory lipid digestion behavior. Our results suggest that the oxidation modification not only improves their emulsification activity but also promotes their application in oil digestion inhibition, providing inspiration for designing and developing low-calorie food products.