Characteristics, sources, and health risk assessment of atmospheric particulate mercury in Guanzhong Basin.

Mercury (Hg) has received increasing public attention owing to its high toxicity and global distribution capability via long-range atmospheric transportation. Guanzhong Basin (GB) is vital for the industrial and economic development of Shaanxi Province. To determine the concentration, spatial distribution, seasonal variation, sources, and health risks of particulate-bound mercury (PBM), PM2.5 samples were collected at three sampling sites representing urban, rural, and remote areas during winter and summer in GB. The three sampling sites were in Xi'an (XN), Taibai (TB), and the Qinling Mountains (QL). The mean PBM concentrations in XN, TB, and QL in winter were 130 ± 115 pg m-3, 57.5 ± 47.3 pg m-3, and 53.6 ± 38.5 pg m-3, respectively, higher than in summer (13.7 ± 7.11 pg m-3, 8.01 ± 2.86 pg m-3, and 7.75 ± 2.85 pg m-3, respectively). PBM concentrations are affected by precipitation, meteorological conditions (temperature and mixed boundary layer), emission sources, and atmospheric transport. During the sampling period, the PBM dry deposition in XN, TB, and QL was 1.90 µg m-2 (2 months), 0.835 µg m-2 (2 months), and 0.787 µg m-2 (2 months), respectively, lower than the range reported in national megacities. According to backward trajectory and potential source contribution factor (PSCF) analysis, mercury pollution in XN is mainly affected by local pollution source emissions, whereas the polluted air mass in TB and QL originates from local anthropogenic emissions and long-distance atmospheric transmission. The non-carcinogenic health risk values of PBM in XN, TB, and QL in winter and summer were less than 1, indicating that the risk of atmospheric PBM to the health of the residents was negligible.

Concentrations and light absorption properties of PM2.5 organic and black carbon based on online measurements in Lanzhou, China.

To elucidate the variations in mass concentrations of organic carbon (OC) and black carbon (BC) in PM2.5 and their light absorption characteristics in Lanzhou, we conducted one-year online measurements by using a newly developed total carbon analyzer (TCA08) coupled with an aethalometer (AE33) from July 2018 to July 2019. The mean OC and BC concentrations were 6.4 ± 4.4 and 2.0 ± 1.3 µg/m3, respectively. Clear seasonal variations were observed for both components, with winter having the highest concentrations, followed by autumn, spring, and summer. The diurnal variations of OC and BC concentrations were similar throughout the year, with daily two peaks occurring in the morning and evening, respectively. A relatively low OC/BC ratio (3.3 ± 1.2, n = 345) were observed, indicating that fossil fuel combustion was the primary source of the carbonaceous components. This is further substantiated by relatively low biomass burning contribution (fbiomass: 27.1% ± 11.3%) to BC using aethalometer based measurement though fbiomass value which increased significantly in winter (41.6% ± 5.7%). We estimated a considerable brown carbon (BrC) contribution to the total absorption coefficient (babs) at 370 nm (yearly average of 30.8% ± 11.1%), with a winter maximum of 44.2% ± 4.1% and a summer minimum of 19.2% ± 4.2%. Calculation of the wavelength dependence of total babs revealed an annual mean AAE370-520 value of 4.2 ± 0.5, with slightly higher values in spring and winter. The mass absorption cross-section of BrC also exhibited higher values in winter, with an annual mean of 5.4 ± 1.9 m2/g, reflecting the impact of emissions from increased biomass burning on BrC concentrations.

Concentrations, sources, fluxes, and absorption properties of carbonaceous matter in a central Tibetan Plateau river basin.

Carbonaceous matter (CM) (such as water-insoluble organic carbon (WIOC), black carbon (BC), and water-soluble organic carbon (WSOC)) has a significant impact on the carbon cycle and radiative forcing (RF) of glacier. Precipitation samples and glacier's snow/ice samples (snowpit, surface snow, and granular ice) (Xiao dongkemadi Glacier) were collected at the Dongkemadi River Basin (DRB) in the central Tibetan Plateau (TP) between May and October 2016 to investigate the characteristics and roles of CM in the TP River Basin. WIOC, BC, and WSOC concentrations in precipitation were relatively higher than that in snowpit, but lower than that in surface snow/ice, with the wet deposition fluxes of 0.10 ± 0.002, 0.04 ± 0.001, and 0.12 ± 0.002 g C m-2 yr-1 at DRB, respectively. The positive matrix factorization model identified four major sources (biomass burning source, secondary precursors, secondary aerosol, and dust source) of CM in precipitation at DRB. Two source areas (South Asia and the interior of TP) contributing to the pollution at DRB were identified using a potential source contribution function model, a concentration-weighted trajectory method, and the back-trajectory model. Moreover, the light-absorption by WSOC in the ultraviolet region was 23.0%, 12.1%, and 3.4% relative to the estimated total light-absorption in precipitation, snowpit, and surface snow/ice, respectively. Optical indices analysis revealed that WSOC in snowpit samples presented higher molecular weight, while presented higher aromatic and higher molecule sizes in surface snow/ice and precipitation samples, respectively. RF by WSOC relative to that of BC was estimated to be 17.6 ± 17.6% for precipitation, 10.9 ± 5.8% for snowpit, and 10.7 ± 11.6% for surface snow/ice, respectively, during the melt season in the central TP River Basin. These results help us understand how CM affects glaciers, and they can be utilized to create policies and recommendations that efficiently reduce emissions.

Atmospheric particle-bound polycyclic aromatic compounds over two distinct sites in Pakistan: Characteristics, sources and health risk assessment.

Much attention is drawn to polycyclic aromatic hydrocarbons (PAHs) as an air pollutant due to their toxic, mutagenic and carcinogenic properties. Therefore, to understand the levels, seasonality, sources and potential health risk of PAHs in two distinct geographical locations at Karachi and Mardan in Pakistan, total suspended particle (TSP) samples were collected for over one year period. The average total PAH concentrations were 31.5 ± 24.4 and 199 ± 229 ng/m3 in Karachi and Mardan, respectively. The significantly lower concentration in Karachi was attributed to diffusion and dilution of the PAHs by the influence of clean air mass from the Arabian sea and high temperature, enhancing the volatilization of the particle phase PAHs to the gas phase. Conversely, the higher concentration (~6 times) in Mardan was due to large influence from local and regional emission sources. A clear seasonality was observed at both the sites, with the higher values in winter and post-monsoon due to higher emissions and less scavenging, and lower values during monsoon season due to the dilution effect. Diagnostic ratios and principal component analysis indicated that PAHs in both sites originated from traffic and mixed combustion sources (fossil fuels and biomass). The average total BaP equivalent concentrations (BaPeq) in Karachi and Mardan were 3.26 and 34 ng/m3, respectively, which were much higher than the WHO guideline of 1 ng/m3. The average estimates of incremental lifetime cancer risk from exposure to airborne BaPeq via inhalation indicated a risk to human health from atmospheric PAHs at both sites.

Research progresses of microplastic pollution in freshwater systems.

Microplastics (MPs) have received widespread attention as an emerging environmental pollutant. They are ubiquitous in the freshwater system, causing a global environmental issue. The current features and perspectives of MPs in the freshwater systems can provide the concerns of their ecological effects, which has not been addressed widely. Therefore, in this study, we reviewed the characteristics of MPs in freshwater environments and discussed their sources and potential impacts. The abundance of MPs in freshwater system ranged from approximately 3-6 orders of magnitude in different regions. There colors were mainly white and transparent, with polypropylene (PP) and polyethylene (PE) as the major polymers. The main shape of these MPs was fibers with dominant size of less than 1 mm. Analysis indicated MPs in freshwater system mostly originated from human activities such as sewage discharge in highly contaminated areas, while atmospheric long-distance transport and precipitation deposition played an important role in remote areas. Freshwater MPs pollutants also affected drinking water and aquatic organisms. Because the abundance of MPs in organisms was relatively balanced, the pollution level of biological MP pollution cannot accurately characterize the pollution status in the watershed currently. Future research should focus and strengthen on periodic monitoring to characterize the temporal and spatial changes of MPs, and enhance toxicological research to explore MPs pollution impact on biota and humans.

Historical Black Carbon Reconstruction from the Lake Sediments of the Himalayan-Tibetan Plateau.

Black carbon (BC) is one of the major drivers of climate change, and its measurement in different environment is crucial for the better understanding of long-term trends in the Himalayan-Tibetan Plateau (HTP) as climate warming has intensified in the region. We present the measurement of BC concentration from six lake sediments in the HTP to reconstruct historical BC deposition since the pre-industrial era. Our results show an increasing trend of BC concurrent with increased anthropogenic emission patterns after the commencement of the industrialization era during the 1950s. Also, sedimentation rates and glacier melt strengthening influenced the total input of BC into the lake. Source identification, based on the char and soot composition of BC, suggests biomass-burning emissions as a major contributor to BC, which is further corroborated by open-fire occurrence events in the region. The increasing BC trend continues to recent years, indicating increasing BC emissions, mainly from South Asia.