Phosphorus immobilisation in sediment by using iron rich by-product as affected by water pH and sulphate concentrations.

Iron (Fe) rich by-product from drinking water treatment plants can be added to rivers and lakes to immobilise phosphorus (P) in sediment and lower eutrophication risks. This study was set up to investigate the P immobilisation efficiency of an Fe rich by-product as affected by the pH and sulphate (SO4) concentration in the overlying water. Both factors are known to inhibit long-term P immobilisation under anoxic conditions. A static sediment-water incubation was conducted at varying buffered water pH values (6, 7 and 8) and different initial SO4 concentrations (0-170 mg SO4 L-1) with or without Fe rich by-product amendment to the sediment. In the unamended sediment, the P release to the overlying water was highest, and up to 6 mg P L-1, at lowest water pH due to higher reductive dissolution of Fe(III) oxyhydroxides. The Fe rich by-product amendment to the sediment largely reduced P release from sediment by factors 50-160 depending on pH, with slightly lowest immobilisation at highest pH 8, likely because of pH dependent P sorption. The total sulphur (S) concentrations in the overlying water reduced during incubation. The P release in unamended sediments increased from 2.7 mg L-1 to 4.2 mg L-1 with higher initial SO4 concentrations, suggesting sulphide formation during incubation and FeS precipitation that facilitates release of P. However, no such SO4 effects were found where Fe rich by-product was applied that lowered P release to <0.1 mg L-1 illustrating high stability of immobilised P in amended sediments. This study suggests that Fe rich by-product is efficient for P immobilisation but that loss of Fe in low pH water may lower its long-term effect.

Internal loading of phosphate in rivers reduces at higher flow velocity and is reduced by iron rich sand application: an experimental study in flumes.

Many lowland regions are afflicted with high phosphorus (P) peaks in rivers during the summer months. Static incubations of sediments have shown that reductive dissolution of ferric iron (Fe(III)) minerals in the sediment explain these P peaks. This study was set up to identify if that mechanism also dominates in a dynamic system, thereby testing the roles of water flow velocity and sediment Fe/P ratio. Decreasing flow velocity was suspected to lower the flux of dissolved oxygen (DO) towards the sediment. The role of the Fe(III)/P ratio was tested by amending iron-rich glauconite sand (GS) to the sediment, in this manner testing possible remediation techniques. Eight flumes (1.80 m long) were constructed with duplicates of four treatments of two laminar flow velocities over the sediment (0.05 m s-1 or 0.15 m s-1) that was either or not amended with GS (10% w/w). In all flumes a daily dose of sodium glutamate was added as a carbon source to mimic wastewater with high BOD, the flumes were operated for 28 days. A decreased velocity lowered the steady-state DO concentration and enhanced the sediment-water release of P by a factor 3. Sediment amendment with GS reduced solution P by factors 3 (low flow velocity) and 2 (high flow velocity). This effect is related to a combination of increasing binding sites for P and of lowering the DO consumption. These experimental data suggest that previously unexplained summer peaks of P in lowland rivers are related to low flow events that limit the DO flux. The internal loading of P requires management of DO in water and can be mitigated by enhancing sediment Fe.