Spectroscopic fingerprinting, pollution characterization, and health risk assessment of potentially toxic metals from urban particulate matter.

The unprecedented stride of urbanization and industrialization has given rise to anthropogenic input of tiny particulates into the air. Urban particulate matter (PM) armored with potentially toxic metals (PTMs) could be lethal to the environment and human health. Therefore, the present study was planned to investigate the spectroscopic fingerprinting, pollution status and health risk of PM-associated PTMs collected from ten functional areas of Lahore, Pakistan. The diverged results of studied qualitative and quantitative analyses showed distinct compositional and pollution characteristics of PTMs in urban PM with respect to selected functional areas. The XRD results evident the fractional presence of metal-containing minerals, i.e., pyrite (FeS2), calcite (CaCO3), zinc sulfate (ZnSO4), and chalcostibite (CuSbS2). Several chemical species of Zn, Pb, and As were found in PM of various functional areas. However, morphologies of PM showed anthropogenic influence with slight quantitative support of PTMs presence. The cumulative representation of PTMs pollution of all selected areas depicted that Cd was heavily polluted (Igeo=3.21) while Cr (Igeo=1.82) and Ni (Igeo=2.11) were moderately polluted PTMs. The industrial area having high pollution status of Cd (Igeo=5.54 and EF=18.07), Cu (Igeo=6.4 and EF=32.61), Cr (Igeo=4.03 and EF=6.53), Ni (Igeo=5.7 and EF=20.17), and Zn (Igeo=4.87 and EF=11.27) was prominent among other studied areas. The PTMs were likely to pose a high non-cancerous risk in IndAr (HI = 7.48E+00) and HTV (HI = 1.22E +00) areas predominantly due to Zn with HQ > 1. However, Cr was prominent to cause cancerous risks with values beyond the tolerable range (1.00E-04 to 1.00E-06).

Biogeochemical behaviour and toxicology of chromium in the soil-water-human nexus: A review.

Chromium (Cr) affects human health if it accumulates in organs to elevated concentrations. The toxicity risk of Cr in the ecosphere depends upon the dominant Cr species and their bioavailability in the lithosphere, hydrosphere, and biosphere. However, the soil-water-human nexus that controls the biogeochemical behaviour of Cr and its potential toxicity is not fully understood. This paper synthesizes information on different dimensions of Cr ecotoxicological hazards in the soil and water and their subsequent effects on human health. The various routes of environmental exposure of Cr to humans and other organisms are also discussed. Human exposure to Cr(VI) causes both carcinogenic and non-carcinogenic health effects via complicated reactions that include oxidative stress, chromosomal and DNA damage, and mutagenesis. Chromium(VI) inhalation can cause lung cancer; however, incidences of other types of cancer following Cr(VI) exposure are low but probable. The non-carcinogenic health consequences of Cr(VI) exposure are primarily respiratory and cutaneous. Research on the biogeochemical behaviour of Cr and its toxicological hazards on human and other biological routes is therefore urgently needed to develop a holistic approach to understanding the soil-water-human nexus that controls the toxicological hazards of Cr and its detoxification.

A critical review on biochar-assisted free radicals mediated redox reactions influencing transformation of potentially toxic metals: Occurrence, formation, and environmental applications.

Potentially toxic metals have become a viable threat to the ecosystem due to their carcinogenic nature. Biochar has gained substantial interest due to its redox-mediated processes and redox-active metals. Biochar has the capacity to directly adsorb the pollutants from contaminated environments through several mechanisms such as coprecipitation, complexation, ion exchange, and electrostatic interaction. Biochar's electron-mediating potential may be influenced by the cyclic transition of surface moieties and conjugated carbon structures. Thus, pyrolysis configuration, biomass material, retention time, oxygen flow, and heating time also affect biochar's redox properties. Generally, reactive oxygen species (ROS) exist as free radicals (FRs) in radical and non-radical forms, i.e., hydroxyl radical, superoxide, nitric oxide, hydrogen peroxide, and singlet oxygen. Heavy metals are involved in the production of FRs during redox-mediated reactions, which may contribute to ROS formation. This review aims to critically evaluate the redox-mediated characteristics of biochar produced from various biomass feedstocks under different pyrolysis conditions. In addition, we assessed the impact of biochar-assisted FRs redox-mediated processes on heavy metal immobilization and mobility. We also revealed new insights into the function of FRs in biochar and its potential uses for environment-friendly remediation and reducing the dependency on fossil-based materials, utilizing local residual biomass as a raw material in terms of sustainability.

Health impacts of indoor air pollution from household solid fuel on children and women.

The inefficient and incomplete combustion of solid fuel (SF) is associated with high levels of indoor air pollutants leading to 3.55 million deaths annually. The risk is higher in women and children, due to their higher exposure duration and unique physical properties. The current article aims to provide a critical overview regarding the use of solid fuel, its associated pollutants, their toxicity mechanisms and, most importantly the associated health impacts, especially in women and children. Pollutants associated with SF mostly include polycyclic aromatic hydrocarbons, particulate matter, nitrous oxide, carbon monoxide and sulfur dioxide, and their concentrations are two- to threefold higher in indoor environments. These pollutants can lead to a variety of health risks by inducing different toxicity mechanisms, such as oxidative stress, DNA methylation, and gene activation. Exposed children have an increased prevalence of low birth weight, acute lower respiratory tract infections, anemia and premature mortality. On the other hand, lung cancer, chronic obstructive pulmonary disease and cardiovascular diseases are the major causes of disability and premature death in women. Indoor air pollution resulting from SF combustion is a major public health threat globally. To reduce the risks, it is important to identify future research gaps and implement effective interventions and policies.

Nickel in soil and water: Sources, biogeochemistry, and remediation using biochar.

Nickel (Ni) is a potentially toxic element that contaminates soil and water, threatens food and water security, and hinders sustainable development globally. Biochar has emerged as a promising novel material for remediating Ni-contaminated environments. However, the potential for pristine and functionalized biochars to immobilize/adsorb Ni in soil and water, and the mechanisms involved have not been systematically reviewed. Here, we critically review the different dimensions of Ni contamination and remediation in soil and water, including its occurrence and biogeochemical behavior under different environmental conditions and ecotoxicological hazards, and its remediation using biochar. Biochar is effective in immobilizing Ni in soil and water via ion exchange, electrostatic attraction, surface complexation, (co)precipitation, physical adsorption, and reduction due to the biogeochemistry of Ni and the interaction of Ni with surface functional groups and organic/inorganic compounds contained in biochar. The efficiency for Ni removal is consistently greater with functionalized than pristine biochars. Physical (e.g., ball milling) and chemical (e.g., alkali/acidic treatment) activation achieve higher surface area, porosity, and active surface groups on biochar that enhance Ni immobilization. This review highlights possible risks and challenges of biochar application in Ni remediation, suggests future research directions, and discusses implications for environmental agencies and decision-makers.

Carbon fractionation and stable carbon isotopic fingerprint of road dusts near coal power plant with emphases on coal-related source apportionment.

Road dust from coal utilization is a significant source contributing to the generation of pollutants that can affect the health of people residing within close proximity to roadways. In this study, road dust samples were collected from different directions centered around a coal-fired power plant in Huainan. Black carbon (BC), soot, char, organic carbon (OC) and total carbon (TC), as well as the δ13C of samples, were determined. Compared to the reference locations which were distant from the power plant, the research areas surrounding the power plant were featured by significantly higher OC/BC ratio and TC concentration. The OC/BC showed significant difference in urban vs. rural areas, and at different distances from the central power plant, which implied that the source and spread of carbonaceous species was dominantly affected by wind direction and urban/rural area differences. Surface morphology analysis showed that the road dust was mixed with spherical particles similar to fly ash. High-resolution XPS C1s spectrum revealed the existence of metal carbide, metal carbonate, and CF3 in the road dust samples. The speciation of carbon in road dusts was found correlated with sampling directions and urban functional areas. Based on the δ13C and OC/BC, it could be inferred that coal-related substances might be important sources of road dusts.

Efficiency of various silicon rich amendments on growth and cadmium accumulation in field grown cereals and health risk assessment.

Cadmium (Cd) contamination of arable soils and its subsequent accumulation in food is one of the global issues which needs urgent attention. Field experiments were conducted to explore the impacts of ten silicon (Si) rich amendments on Cd bioavailability and accumulation by maize and wheat irrigated with sewage effluents. Results depicted that applied amendments decreased the total Cd accumulation in shoots and grains of both crops with and the maximum decrease was observed in rice husk biochar (RHB) treatment. The RHB was able to significantly decrease the translocation factor, Cd harvest and health risk indexes. All amendments differentially affected the soil pH, EC, CaCl2-extractable Si, and decreased the AB-DTPA-extractable soil Cd. Overall, suitable Si rich amendments (like RHB and CSB etc.) can be employed to mitigate the health risks associated with dietary Cd in untreated sewage irrigated fields. However, the cost-benefit analysis such Si rich amendments should be considered before final recommendations.

Characterizing pollution indices and children health risk assessment of potentially toxic metal(oid)s in school dust of Lahore, Pakistan.

Toxic metal pollution is a renowned environmental concern, especially to sensitive environments like school classrooms and their association with children's health. The study was planned to determine the pollution characteristics of 13 potentially toxic metal (oid)s (PTMs) and their associated children's health risk assessment from school dust samples of considerably three land-use types (residential, roadside, and industrial areas) of Lahore, Pakistan. Geo-accumulation (Igeo), pollution (PI), integrated pollution (IPI) and pollution load (PLI) indexes were used to determine the PTMs contamination and USEPA health risk assessment models were employed to assess the health risks in children. The mean concentrations of Cd, Cr, Cu, Ni, Pb, and Zn for three land-use types were found much higher than the permissible limits. Results of pollution indices revealed that school dust was strongly contaminated with Cd, Pb, and Zn whilst moderately contaminated with Cr and Cu. Moreover, the health risk assessment models revealed no significant non-cancerous risks in children with predominantly highest hazardous index (HI) of Cr in industrial (4.61E-01) and Pb in both roadside (4.30E-01) and residential (2.26E-01) area schools. According to cumulative HI of all PTMs and exposure routes, the land-use areas were in descending order as industrial > roadside > residential. The calculations of hazardous quotient (HQ) showed ingestion was the leading pathway of PTMs exposure through school dust. For carcinogenic health risk (CR), the most prominent PTM was Cr with values of 1.53E-06 in industrial area schools, found close to the tolerable range (1.0E-06). Hence, school dust of Lahore prominently contaminated with eminent PTMs triggering slight health risks predominantly by ingestion exposure to children.

Estimating the pollution characteristics and health risks of potentially toxic metal(loid)s in urban-industrial soils in the Indus basin, Pakistan.

The Indus Basin Irrigation Network (IBIN) plays a vital role in the agricultural system of Pakistan, irrigating seventeen million hectares of cultivated areas. Rapid urbanization, industrialization, and agricultural activities along the Indus basin have influenced the soil quality and human health; it is, therefore, critical to know its pollution characteristics. Soil samples from Indus basin, i.e., Abbottabad (ABT), Haripur (HRP), Attock (ATC), and Islamabad (ISB) have been analyzed for the total contents of potentially toxic metal(loid)s (PTMs) in the top layer. The topsoil samples from 0 to 10 cm depth have been further investigated using different pollution indices and human health risk assessment models. The contamination degree of soil pollution was highest in ISB (33.75), followed by ABT (25.30) and ATC (23.57). The assessment of the daily intake of PTMs by children and adults through different pathways revealed ingestion as the significant exposure pathway. Cr was found to be the major element posing non-carcinogenic health risks to children at ATC whereas the non-carcinogenic risks posed by all other PTMs were within the safe limit. Furthermore, life-time carcinogenic risks for Ni followed by Cr and Cd were greatly exceeded at all locations and As at ATC and ISB for both age groups, but comparatively children were found to be at a higher risk of carcinogenicity. Hence, efficient remediation strategies are needed to reduce the increasing content and health risks of PTMs in the Indus basin.

Silicon nanoparticles enhanced the growth and reduced the cadmium accumulation in grains of wheat (Triticum aestivum L.).

The application of silicon (Si) under heavy metal stress is well known, but the use of Si nanoparticles (NPs) under metal stress in not well documented. Thus, the experiments were performed to investigate the impacts of soil and foliar applied Si NPs on wheat (Triticum aestivum L.) growth and cadmium (Cd) accumulation in grains under Cd toxicity. The plants were grown under natural environmental conditions and were harvested after physiological maturity (124 days after sowing). The results demonstrated that Si NPs significantly improved, relative to the control, the dry biomass of shoots, roots, spikes and grains by 24-69%, 14-59%, 34-87%, and 31-96% in foliar spray and by 10-51%, 11-49%, 25-69%, and 27-74% in soil applied Si NPs, respectively. The Si NPs enhanced the leaf gas exchange attributes and chlorophyll a and b concentrations, whereas diminished the oxidative stress in leaves which was indicated by the reduced electrolyte leakage and enhancement in superoxide dismutase and peroxidase activities in leaf under Si NPs treatments over the control. When compared with the control, the foliar spray of Si NPs reduced the Cd contents in shoots, roots, and grains by 16-58%, 19-64%, and 20-82%, respectively, whereas soil applied Si NPs reduced the Cd concentrations in shoots, roots, and grains by 11-53%, 10-59%, and 22-83%, respectively. In comparison with the control, Si concentrations significantly (p ≤ 0.05) increased in the shoots and roots in both foliar and soil supplementation of Si NPs. Our results suggested that Si NPs could improve the yield of wheat and more importantly, reduce the Cd concentrations in the grains. Thus, the use of Si NPs might be a feasible approach in controlling Cd entry into the human body via crops.

Investigating the drinking and surface water quality and associated health risks in a semi-arid multi-industrial metropolis (Faisalabad), Pakistan.

Urban areas under the influence of multi-industrial activities with arid and semi-arid environments witness the significant increase in environmental pollution especially in the water sector. The present study evaluated the water quality and associated health risk assessment through heavy metal pollution. Drinking (n = 48) and surface (n = 37) water samples were collected from semi-arid multi-industrial metropolis, Faisalabad, Pakistan. Physio-chemical and biological parameters and different metals (Al, As, Ba, Cd, Cr, Cu, Fe, Pb, Ni and Zn) were investigated using standard procedures and multivariate water quality assessments. Many physio-chemical and biological parameters and metals especially arsenic were exceeding the permissible limit of Punjab environmental quality standards and the World Health Organization. The results from water quality index showed that < 56% samples have poor, < 8% have very poor and < 6% have unsuitable water quality for drinking purposes. Water quality for the Gugera Branch Canal was found suitable with medium sodium (alkalinity) and salinity hazards, while it was found poor with magnesium absorption ratio. Hazard quotient (HQ) values for arsenic were found at the threshold level (HQ > 1) and carcinogenicity was found in case of arsenic and chromium (1 × 10-4) in adults and children. Semi-arid weather combined with different anthropogenic activities and unusual water features provoked metal contamination. Results of the present study can deliver basic information for effective management of water in the most populous and industrial areas.

A systematic review on global pollution status of particulate matter-associated potential toxic elements and health perspectives in urban environment.

Airborne particulate matter (PM) that is a heterogeneous mixture of particles with a variety of chemical components and physical features acts as a potential risk to human health. The ability to pose health risk depends upon the size, concentration and chemical composition of the suspended particles. Potential toxic elements (PTEs) associated with PM have multiple sources of origin, and each source has the ability to generate multiple particulate PTEs. In urban areas, automobile, industrial emissions, construction and demolition activities are the major anthropogenic sources of pollution. Fine particles associated with PTEs have the ability to penetrate deep into respiratory system resulting in an increasing range of adverse health effects, at ever-lower concentrations. In-depth investigation of PTEs content and mode of occurrence in PM is important from both environmental and pathological point of view. Considering this air pollution risk, several studies had addressed the issues related to these pollutants in road and street dust, indicating high pollution level than the air quality guidelines. Observed from the literature, particulate PTEs pollution can lead to respiratory symptoms, cardiovascular problems, lungs cancer, reduced lungs function, asthma and severe case mortality. Due to the important role of PM and associated PTEs, detailed knowledge of their impacts on human health is of key importance.

Emission characteristics for gaseous- and size-segregated particulate PAHs in coal combustion flue gas from circulating fluidized bed (CFB) boiler.

The partitioning behavior of polycyclic aromatic hydrocarbons (PAHs) between gaseous and particulate phases from coal-fired power plants (CFPPs) is critically important to predict PAH removal by dust control devices. In this study, 16 US-EPA priority PAHs in gaseous and size-segregated particulate phases at the inlet and outlet of the fabric filter unit (FFs) of a circulating fluidized bed (CFB) boiler were analyzed. The partitioning mechanisms of PAHs between gaseous and particulate phases and in particles of different size classes were investigated. We found that the removal efficiencies of PAHs are 45.59% and 70.67-89.06% for gaseous and particulate phases, respectively. The gaseous phase mainly contains low molecular weight (LMW) PAHs (2- and 3-ring PAHs), which is quite different from the particulate phase that mainly contains medium and high molecular weight (MMW and HMW) PAHs (4- to 6-ring PAHs). The fractions of LMW PAHs show a declining trend with the decrease of particle size. The gas-particle partitioning of PAHs is primarily controlled by organic carbon absorption, in addition, it has a clear dependence on the particle sizes. Plot of log (TPAH/PM) against logDp shows that all slope values were below -1, suggesting that PAHs were mainly adsorbed to particulates. The adsorption effect of PAHs in size-segregated PMs for HMW PAHs is more evident than LMW PAHs. The particle size distributions (PSDs) of individual PAHs show that most of PAHs exhibit bi-model structures, with one mode peaking in the accumulation size range (2.1-1.1 µm) and another mode peaking in coarse size range (5.8-4.7 µm). The intensities of these two peaks vary in function of ring number of PAHs, which is likely attributed to Kelvin effect that the less volatile HMW PAH species preferentially condense onto the finer particulates. The emission factor of PAHs was calculated as 3.53 mg/kg of coal burned, with overall mean EFPAH of 0.55 and 2.98 mg/kg for gaseous and particulate phase, respectively. Moreover, the average emission amount of PAHs for the investigated CFPP was 1016.6 g/day and 371073.6 g/y, respectively.

Farmyard manure alone and combined with immobilizing amendments reduced cadmium accumulation in wheat and rice grains grown in field irrigated with raw effluents.

Cadmium (Cd) stress is a serious concern in agricultural soils worldwide whereas little is known about the impact of farmyard manure (FYM) alone or combined with limestone, lignite and biochar on Cd concentrations in plants. Wheat was grown in Cd-contaminated field amended with control (T1), FYM @ 0.1% (T2), FYM + limestone @ 0.05% each (T3), FYM + lignite @ 0.05% each (T4), FYM + biochar @ 0.05% each (T5) and subsequent rice was grown without additional use of amendments. Soil application of amendments increased straw and grain yield and thousand grain weight being maximum in FYM + limestone treatment. Wheat and rice straw yield increased by 19% and 10% in T3 than control respectively. Photosynthetic pigments increased with the supply of amendments than control. Amendments decreased Cd concentration, total Cd uptake in straw and grains and Cd harvest index of both crops and the maximum reduction in these parameters was recorded with where FYM + limestone (T3). Cd concentration in wheat and rice straw decreased by 78.5% and 65% in T3 than control, respectively. The highest benefit to cost ratio was obtained in FYM + limestone (T3). Ammonium bicarbonate - diethylenetriamine penta acetic acid (AB-DTPA) extractable Cd of the post-harvest soil reduced whereas Cd immobilization index and soil pH increased with the supply of all treatments than control being maximum in T3. The present study revealed that field management with FYM + limestone increased plant yield and reduced Cd concentrations in grains.

Developmental selenium exposure and health risk in daily foodstuffs: A systematic review and meta-analysis.

Selenium (Se) is a trace mineral and an essential nutrient of vital importance to human health in trace amounts. It acts as an antioxidant in both humans and animals, immunomodulator and also involved in the control of specific endocrine pathways. The aim of this work is to provide a brief knowledge on selenium content in daily used various foodstuffs, nutritional requirement and its various health consequences. In general, fruits and vegetables contain low content of selenium, with some exceptions. Selenium level in meat, eggs, poultry and seafood is usually high. For most countries, cereals, legumes, and derivatives are the major donors to the dietary selenium intake. Low level of selenium has been related with higher mortality risk, dysfunction of an immune system, and mental failure. Selenium supplementation or higher selenium content has antiviral outcomes and is necessary for effective reproduction of male and female, also decreases the threat of chronic disease (autoimmune thyroid). Generally, some advantages of higher content of selenium have been shown in various potential studies regarding lung, colorectal, prostate and bladder cancers risk, nevertheless results depicted from different trials have been diverse, which perhaps indicates the evidence that supplementation will merely grant advantage if the intakes of a nutrient is deficient. In conclusion, the over-all people should be advised against the usage of Se supplements for prevention of cardiovascular, hepatopathies, or cancer diseases, as advantages of Se supplements are still ambiguous, and their haphazard usage could result in an increased Se toxicity risk. The associations among Se intake/status and health, or disease risk, are complicated and need exposition to notify medical practice, to improve dietary recommendations, and to develop adequate communal health guidelines.

Comparative effects of biochar-nanosheets and conventional organic-amendments on health risks abatement of potentially toxic elements via consumption of wheat grown on industrially contaminated-soil.

Potentially toxic elements (PTEs) discharge to the soil environment through increased anthropogenic activities is a global threat. These PTEs can have harmful and chronic-persistent health effects on exposed populations through food consumption grown on contaminated soils. Efforts to investigate the transformation mechanism and accumulation behavior of PTEs in soil-plant system and their adverse health-effects have focused extensively in previous studies. However, limited studies address biochar nanosheets (BCNs) as a potential soil amendment to reduced humans health risks through dietary intake of food-crop grown on PTE-contaminated soil. Here, we showed how BCNs cutback health hazards of PTEs through impacts on bioavailability and phytoaccumulation of PTEs, and their daily intake via consumption of wheat. When BCNs amendment was compared with both conventional organic amendments (COAs) and control, it significantly (P ≤ 0.05) reduced bioavailability and uptake of PTEs by wheat plants. Based on risk assessment results, the hazard indices (HIs) for PTEs in all treatments were <1, however, BCNs addition significantly (P ≤ 0.05) reduced risk level, when compared to control. Furthermore, the cancer risks for Cd, Cr and Ni over a lifetime of exposure were higher in all treatments than the tolerable limit (1.00E-4 to 1.00E-6), however BCNs addition significantly suppressed cancer risk compared to control. Conclusively, our results suggest that BCNs can be used as soil amendment to reduce potential risks of PTEs through consumption of food grown in PTE-contaminated soils.

Evaluating the health risks of potentially toxic elements through wheat consumption in multi-industrial metropolis of Faisalabad, Pakistan.

Potentially toxic elements (PTEs) pollution is the fastest growing concern around the entire globe especially in developing countries. Rapid industrialization and urbanization are the dominant sources of anthropogenic soil-food chain contamination with PTEs. The intent of current study was to investigate the interactive levels of Cu, Fe, Mn, Ni, Pb, and Zn in soil and their accumulation in wheat (Triticum aestivum L.) samples collected from 96 sites including industrial, urban, and peri-urban areas of a leading multi-industrialized center (Faisalabad) of Pakistan. According to results obtained from present study, non-carcinogenic (HQ) and life-time carcinogenic risks (CR) of the PTEs to the local inhabitants were estimated following the risk assessment modals proposed by the US-EPA. With respect to estimated HQ for chronic non-carcinogenic risk of Mn, Ni, and Pb, higher potential hazards were observed as compared to Cu, Fe, and Zn. Meanwhile, the carcinogenic risk of Ni marginally exceeded the limit described by US-EPA for adults. Overall, the health risks of PTEs with the consumption of wheat were lower than the limits described by US-EPA except for Ni. However, continuous consumption of this PTEs contaminated food may result the potential buildup of poisonousness and various disorders in humans. Therefore, long-term monitoring and gastrointestinal bio-accessibility studies are requisite for the safety of humans under such conditions.

Pollution characteristics and human health risks of potentially (eco)toxic elements (PTEs) in road dust from metropolitan area of Hefei, China.

This study aims to investigate the pollution characteristics of road dust and their associated health risks of potentially toxic elements (PTEs) to humans using array-based risk assessment models described by United States Environmental Protection Agency (USEPA) in a metropolitan area of Hefei, China. Geoaccumulation index (Igeo) was used to describe pollution characteristics of roadside dust in urban, periurban and industrial areas. Results indicate that industrial roadside dust was contaminated with Fe, Ni, Cu, Ti, V, Pb, Ba, Sb, Cr, Sn, Pb, As and Ga showing Igeo value (log2 (x)) between Igeo class 3 to 4. In other hand, urban roadside dust contamination with Cu, Zn, Sb and Ga ranged between Igeo classes 2 to 3 and with As and Pb ranged between Igeo classes 4 to 5. Furthermore, health risk assessment revealed negligible non-cancerous health hazard in all sites including urban, periurban and industrial areas. The hazard quotient (HQ) and hazard Index (HI) values for all exposure routes (ingestion, inhalation, and dermal contact) were <1 except for chromium with HI value of 1.06E+00 in industrial areas. Moreover, the most prominent exposure route was ingestion (HQing) and the non-carcinogenic health risks were found to be high in case of children compared to the adults. The cancer risk from As, Co, Cr, Ni, and Pb was found to be in safe levels as the RI (carcinogenic risks) values were below the limits for carcinogens (1.00E-6 to 1.00E-4).

Bioavailability evaluation, uptake of heavy metals and potential health risks via dietary exposure in urban-industrial areas.

A verity of human activities i.e. urbanization and industrialization have been resulted serious environmental contaminations by heavy metals in all over the world. The settlement of populations in urban and nearby industrial areas for economic development has significant share in their exposure to these metallic contaminants. Depending on the nature and type of the pollutants, targeted urban-industrial environments can have harmful and chronic health risk impacts on exposed local inhabitants and may require detoxification, healing and remedial therapy. Consequently, environmental monitoring as well as human health risk assessments of urban environments under industrial influence are key dominant features. We believe this work will provide new insights into the studies of metals exposure and associated health risks in emerging industrials cities of developing countries. Present study aimed to study the bioavailability of metals, quantify the changeability in soil and vegetable metal concentrations and estimation of human health risks via dietary exposure, focusing on urban-industrial environment. Soil and vegetable samples were collected in six random sites within the urban, periurban and industrial areas and analyzed for metal concentrations. In addition, risk assessment model proposed by US-EPA was employed to estimate the potential health risk of heavy metals via dietary intake. Results indicated that the heavy metal concentrations were noteworthy in periurban and urban-industrial areas. However, contamination levels varied with the type of vegetable, and the point source pollution such as traffic, urban wastes and industrial effluent. According to the estimated THQ and HI values for non-carcinogenic risk, little or no negative impact of heavy metals was observed on local inhabitants. However, the concentrations of Cr, Cd, Pb and Ni were nearly closed to the permissible limits described by US-EPA in urban-industrial areas. Conclusively, some efficient remedial strategies should be focus to overcome the increasing levels of Cr, Cd, Pb and Ni in this study area to protect the health of local inhabitants.

Contrasting effects of biochar, compost and farm manure on alleviation of nickel toxicity in maize (Zea mays L.) in relation to plant growth, photosynthesis and metal uptake.

Nickel (Ni) toxicity in agricultural crops is a widespread problem while little is known about the role of biochar (BC) and other organic amendments like farm manure (FM) from cattle farm and compost (Cmp) on its alleviation. A greenhouse experiment was conducted to evaluate the effects of BC, Cmp and FM on physiological and biochemical characteristics of maize (Zea mays L.) under Ni stress. Maize was grown in Ni spiked soil without and with two rates of the amendments (equivalent to 1% and 2% organic carbon, OC) applied separately to the soil. After harvest, plant height, root length, dry weight, chlorophyll contents, gas exchange characteristics and trace elements in plants were determined. In addition, post-harvest soil characteristics like pHs, ECe and bioavailable Ni were also determined. Compared to the control, all of the amendments increased plant height, root length, shoot and root dry weight with the maximum increase in all parameters by FM (2% OC) treatment. Similarly, total chlorophyll contents and gas exchange characteristics significantly increased with the application of amendments being maximum with FM (2% OC) application. Amendments significantly increased copper, zinc, manganese and iron concentrations and decreased Ni concentrations in the plants. The highest reduction in shoot Ni concentration was recorded with FM (2% OC) followed by BC (2% OC) being 73.2% and 61.1% lower compared to the control, respectively. The maximum increase in soil pH and decrease in AB-DTPA extractable Ni was recorded with BC (2% OC) followed by FM (2% OC). It is concluded that FM (2% OC) was the most effective in reducing Ni toxicity to plants by reducing Ni uptake while BC (2% OC) was the most effective in decreasing bioavailable Ni in the soil through increasing soil pH. However, long-term field studies are needed to evaluate the effects of these amendments in reducing Ni toxicity in plants.