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1.
Anal Chim Acta ; 1141: 221-229, 2021 Jan 02.
Artigo em Inglês | MEDLINE | ID: mdl-33248656

RESUMO

Accurate measurement of naturally occurring radionuclides in blast furnace slag, a by-product of the steel industry, is required for compliance with building regulations where it is often used as an ingredient in cement. A matrix reference blast furnace slag material has been developed to support traceability in these measurements. Raw material provided by a commercial producer underwent stability and homogeneity testing, as well as characterisation of matrix constituents, to provide a final candidate reference material. The radionuclide content was then determined during a comparison exercise that included 23 laboratories from 14 countries. Participants determined the activity per unit mass for 226Ra, 232Th and 40K using a range of techniques. The consensus values obtained from the power-moderated mean of the reported participant results were used as indicative activity per unit mass values for the three radionuclides: A0(226Ra) = 106.3 (34) Bq·kg-1, A0(232Th) = 130.0 (48) Bq·kg-1 and A0(40K) = 161 (11) Bq·kg-1 (where the number in parentheses is the numerical value of the combined standard uncertainty referred to the corresponding last digits of the quoted result). This exercise helps to address the current shortage of NORM industry reference materials, putting in place infrastructure for production of further reference materials.

2.
Health Phys ; 111(5): 420-6, 2016 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-27682900

RESUMO

Thoron (Rn) exhalation from building materials has become increasingly recognized as a potential source for radiation exposure in dwellings. However, few studies have focused on mitigation strategies to reduce exposure from thoron and its progeny. Therefore, the purpose of this study is to (1) determine the reduction in thoron exhalation from building materials applied with regularly available surface barriers and (2) investigate the effects from surface roughness of the base material, barrier thickness, and surface cover on the thoron-retaining action of the surface barrier. The findings from this study demonstrate that regular surface barriers provide a potentially significant reduction in thoron exhalation, which can reach more than 90%. Despite this reduction, there are also materials that provide no reduction at all. Based on this work, no commonly available product property could be identified that provides good guidance on the barriers' performance to reduce thoron exhalation.


Assuntos
Poluentes Radioativos do Ar/química , Poluição do Ar em Ambientes Fechados/análise , Materiais de Construção/análise , Pintura/análise , Papel , Radônio/química , Poluentes Radioativos do Ar/análise , Poluição do Ar em Ambientes Fechados/prevenção & controle , Difusão , Teste de Materiais , Doses de Radiação , Proteção Radiológica/métodos , Radônio/análise , Propriedades de Superfície
3.
Langmuir ; 23(26): 13158-63, 2007 Dec 18.
Artigo em Inglês | MEDLINE | ID: mdl-17985939

RESUMO

We report a biomimetic procedure to prepare superhydrophobic cotton textiles. By in situ introducing silica particles to cotton fibers to generate a dual-size surface roughness, followed by hydrophobization with polydimethylsiloxane (PDMS), normally hydrophilic cotton has been easily turned superhydrophobic, which exhibits a static water contact angle of 155 degrees for a 10 microL droplet. The roll-off angle of water droplets depends on the droplet volume, ranging from 7 degrees for a droplet of 50 microL to 20 degrees for a 7 microL droplet. When a perfluoroalkyl chain is introduced to the silica particle surface, the superhydrophobic textile also becomes highly oleophobic, as demonstrated by a static contact angle of 140 degrees and a roll-off angle of 24 degrees for a 15 microL sunflower oil droplet.


Assuntos
Fibra de Algodão , Mimetismo Molecular , Têxteis , Dimetilpolisiloxanos/química , Microscopia Eletrônica de Varredura , Silicones/química , Propriedades de Superfície
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