Electrochemically Induced Structural and Morphological Evolutions in Nickel Vanadium Oxide Hydrate Nanobelts Enabling Fast Transport Kinetics for High-Performance Zinc Storage.
ACS Appl Mater Interfaces
; 12(22): 24726-24736, 2020 Jun 03.
Article
en En
| MEDLINE
| ID: mdl-32374149
ABSTRACT
Suitable intercalation cathodes and fundamental insights into the Zn-ion storage mechanism are the crucial factors for the booming development of aqueous zinc-ion batteries. Herein, a novel nickel vanadium oxide hydrate (Ni0.25V2O5·0.88H2O) is synthesized and investigated as a high-performance electrode material, which delivers a reversible capacity of 418 mA h g-1 with 155 mA h g-1 retained at 20 A g-1 and a high capacity of 293 mA h g-1 in long-term cycling at 10 A g-1 with 77% retention after 10,000 cycles. More importantly, multistep phase transition and chemical-state change during intercalation/deintercalation of hydrated Zn2+ are illustrated in detail via in situ/ex situ analytical techniques to unveil the Zn2+ storage mechanism of the hydrated and layered vanadium oxide bronze. Furthermore, morphological development from nanobelts to hierarchical structures during rapid ion insertion and extraction is demonstrated and a self-hierarchical process is correspondingly proposed. The unique evolutions of structure and morphology, together with consequent fast Zn2+ transport kinetics, are of significance to the outstanding zinc storage capacity, which would enlighten the mechanism exploration of the aqueous rechargeable batteries and push development of vanadium-based cathode materials.
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1
Colección:
01-internacional
Idioma:
En
Revista:
ACS Appl Mater Interfaces
Asunto de la revista:
BIOTECNOLOGIA
/
ENGENHARIA BIOMEDICA
Año:
2020
Tipo del documento:
Article