Occurrence, multiphase partition and risk assessment of organic amine pesticides in drinking water source of Xiang River, China.

The extensive use of organic amine pesticides (OAPs) in agricultural practices has resulted in the contamination of water environments, posing threats to ecosystems and human health. This study focused on the Xiang River (XR), a representative drinking water source, as the research area to investigate the occurrence characteristics of 34 OAPs. Diphenylamine emerged as the most prevalent OAP in surface water due to industrial and agricultural activities, while cycloate dominated in sediments due to cumulative effects. Generally, the concentration of OAPs in a mixed tap water sample was lower than those in surface water samples, indicating OAPs can be removed by water plants to a certain extent. The water-sediment distribution coefficients (kd) of ΣOAPs were much less than 1 L/g, the majority of OAPs maintained relatively high concentrations in water samples instead of accumulating in sediments. Furthermore, risk assessment revealed that carbofuran showed a moderate risk to the aquatic environment, with a risk quotient of 0.23, while other OAPs presented minor risks. This study provided crucial insights for regional pesticide management and control in the XR basin, emphasizing the importance of implementing strategies to minimize the release of OAPs into the environment and protect human health.

Spatial distribution and risk assessment of pyrethroid insecticides in surface waters of East China Sea estuaries.

Pyrethroid insecticides are the most commonly used household insecticides and pose substantial risks to marine aquatic organisms. many studies have detected pyrethroid insecticides in the waters and estuaries of the western United States, but their distributions within western Pacific estuaries have not been reported. Accordingly, we used high-throughput organic analyses combined with high volume solid-phase extraction to comprehensively assess 13 pyrethroid insecticides in East China Sea estuaries and the Huangpu River. The results demonstrated the presence of various ∑13pyrethroid insecticides in East China Sea estuaries (mean and median values of 8.45 ± 5.57 and 7.78 ng L-1, respectively), among which cypermethrin was the primary contaminant. The concentrations of ∑12pyrethroid insecticide detected in the surface waters at the Huangpu River (mean 6.7 ng L-1, outlet 16.4 ng L-1) were higher than those in the Shanghai estuary (4.7 ng L-1), suggesting that runoff from inland areas is a notable source of insecticides. Wetlands reduced the amount of runoff containing pyrethroid insecticides that reached the ocean. Several factors influenced pesticide distributions in East China Sea estuaries, and higher proportions were derived from agricultural sources than from urban sources, with a higher proportion of agricultural sources than urban sources, influenced by anthropogenic use in the region. Permethrin and cypermethrin were the main compounds contributing to the high ecological risk in the estuaries. Consequently, to prevent risks to marine aquatic life, policymakers should aim to reduce insecticide contaminants derived from urban and agricultural sources.

Occurrence and ecological risk assessment of 16 phthalates in surface water of the mainstream of the Yangtze River, China.

Phthalic acid esters (PAEs), a class of typical endocrine disruptors, have received considerable attention due to their widespread applications and adverse effects on biological health. In this study, 30 water samples, along the mainstream of the Yangtze River (YR), were collected from Chongqing (upper stream) to Shanghai (estuary) from May to June in 2019. The total concentrations of 16 targeted PAEs ranged from 0.437 to 20.5 µg/L, with an average of 1.93 µg/L, where dibutyl phthalate (DBP, 0.222-20.2 µg/L), bis (2-ethylhexyl) phthalate (DEHP, 0.254-7.03 µg/L), and diisobutyl phthalate (DIBP, 0.0645-0.621 µg/L) were the most abundant PAEs. According to the pollution level in the YR to assess the ecological risk posed by PAEs, the results showed medium risk level of PAEs in the YR, among which DBP and DEHP posed a high ecological risk to aquatic organisms. The optimal solution for DBP and DEHP is found in ten fitting curves. The PNECSSD of them is 2.50 µg/L and 0.34 µg/L, respectively.

Spatial distribution and risk assessment of conazole fungicides in surface seawater of the East China Sea.

Conazole fungicides (CFs), the common-used pesticide in agriculture distributed widely in the environment. This research analyzed the occurrence, potential sources, and risks of eight CFs in the East China Sea surface seawater in the early summer of 2020. The total CF concentration ranged from 0.30 to 6.20 ng/L, with an average value of 1.64 ± 1.24 ng/L. Fenbuconazole, hexaconazole, and triadimenol were the major CFs that comprised >96 % of the total concentration. The Yangtze River was identified as the significant source of CFs from the coastal regions to the off-shore inputs. Ocean current was the first-order factor controlling the content and distribution of CFs in the East China Sea. Although risk assessment revealed CFs posed a low or no substantial risk to ecology and human health, long-term monitoring was also encouraged. This study provided a theoretical foundation for assessing CFs' pollution levels and potential risks in the East China Sea.

Spatial assessment of triazole organic compounds in surface water from the coastal estuaries to the East China sea.

Triazole is widely used in the synthesis of pharmaceuticals, pesticides, and fungicides. However, triazole organic compounds are often a source of toxicity in the water environment due to the presence of chlorobenzene. This study reported on the occurrence and distribution of 15 TrOCs in the surface waters of estuaries and the East China sea, and identified the influences of TrOCs originating from the estuarine environment on the ocean. The results showed that the total concentrations of ∑TrOCs in the surface water of estuaries along the coasts of Jiangsu (JS), Zhejiang (ZJ), and Shanghai (SH), China ranged from 0.020 to 104 ng L-1 (7.49 ± 18.2 ng L-1), whereas they ranged from 0.235 to 1.25 ng L-1 (mean 0.711 ± 0.235 ng L-1) in the East China sea. Difenoconazole and tebuconazole were the dominant TrOCs in the estuaries, whereas fenbuconazole and hexaconazole dominated in the ocean. TrOCs in surface water of estuaries showed a continuous spatial distribution and presented regional characteristics mainly related to agricultural activities. In contrast, TrOCs in the East China Sea showed a low spatial variation and dispersion, which may be related to complex disturbance by currents and dilution. The low levels of estuarine TrOCs measured in SH estuaries (<0.5 ng L-1) indicates that the Yangtze River may only pose a low-level TrOC contamination risk to the East China Sea. Moreover, estuary transport in the estuaries of ZJ may have influenced the occurrence of TrOCs in the offshore East China Sea area, although they may have also undergone a filter process in the estuary turbid zone; whereas it had little influence on the open sea. This study can act as a critical reference for the presence of TrOCs in surface water both estuaries and the ocean.

Occurrence, sources, and risk assessment of pyrethroid insecticides in surface water and tap water from Taihu Lake, China.

Pyrethroid insecticides are one of the most widely used insecticides globally, posing a severe threat to human health and the environment. In this study, we applied high-throughput organic analysis testing combined with high-volume solid-phase extraction (Hi-throat/Hi-volume SPE) to elucidate the occurrence of 11 pyrethroid insecticides in lake water (n = 37), tributary river water (n = 15), and tap water (n = 6) in the Taihu Lake Basin. Permethrin was found to be the major contributing pyrethroid insecticide (detection rate = 100%). The concentrations of pyrethroid insecticides from different lake regions were revealed in the following descending order: southern > eastern > western > northern. The principal component analysis and multiple linear regression demonstrated that landscape maintenance, agricultural cultivation, and livestock breeding were the main sources of pyrethroid insecticides in the Taihu Lake surface water. Moreover, runoff input plays an important role in their accumulation, while the surrounding rivers contribute 2292 kg of pyrethroid insecticides to Taihu Lake annually. The risk assessment analysis demonstrated that pyrethroid insecticides pose a high risk to both the ecological environment and the surrounding human populations, thereby necessitating effective countermeasures. Furthermore, the pyrethroid insecticides in the Yangtze River Delta region have to be controlled. Overall, this is the first study focused on China that revealed the residue levels in water sources and tap water.

Assessment of currently used organochlorine pesticides in surface water and sediments in Xiangjiang river, a drinking water source in China: Occurrence and distribution characteristics under flood events.

Xiangjiang (XJ) is a typical urban inland river that serves as a drinking water source, which may be affected by the currently used organochlorine pesticides (CUOCPs) originating from agricultural activities in the vicinity. On this basis, this study comprehensively explored the occurrence and distribution characteristics of CUOCPs in surface water and sediments under long-term precipitation and subsequent floods. Considering the low concentration of CUOCPs in water, a technique combining high-throughput organic analysis with high-volume solid phase extraction (High-throat/Hi-volume SPE) was introduced for effective analysis of CUCOPs. The results showed that the concentration of CUOCPs in the water and sediments of XJ ranged from 2.33 to 6.40 ng L-1 (average of 3.93 ± 1.15 ng L-1) and from 1.52 to 21.2 ng g-1 (average of 6.60 ± 4.31 ng g-1 dw), respectively. The distribution of CUOCPs in water was consistent throughout XJ, but that in sediments was not uniform, indicating a stronger impact of floods on water than on sediments. Water-sediment partition coefficients were generally >2 L g-1, showing a tendency of CUOCP dominance in sediments. The results of principal component analysis and cluster analysis showed that the occurrence of CUOCPs is significantly affected by exogenous disturbance, which could be flood events; meanwhile, clusters of CUOCPs were found in both water and sediments in the source-limited middle reaches in urban areas. Redundancy analysis (RDA) showed that CUOCP occurrences were not positively correlated with nutrient elements (nitrogen and phosphorus), but related to pH and dissolved oxygen (DO), indicating complex sources.

Occurrence, distribution and risk assessment of organophosphate ester flame retardants and plasticizers in surface seawater of the West Pacific.

Twenty-eight samples of surface seawater were collected from the West Pacific Ocean during 2019 using a high-volume solid-phase extraction with high-throughput organic analysis (Hi-throat/Hi-volume SPE) method, and concentrations of 10 organophosphate ester flame retardants and plasticizers (OPEs) were determined. The total OPE concentration in the samples was 3.02-48.4 ng L-1 (mean 25.0 ± 10.5 ng L-1), with tris(2-chloroethyl) phosphate (TCEP) being the largest contributor. Cluster analysis results showed off-shore input from the coast of East and Southeast Asia was an important source of these chemicals. Tri-p-tolyl phosphate (TpTP) should also be considered for long-term monitoring, because of its high detection frequency. Results of a risk assessment indicated low ecological risk to species in the West Pacific Ocean for TPhP and ΣOPEs. Hazard quotients (HQs) were all <1, indicating that the health risk to humans from these chemicals was at acceptable levels.

Correction to: Risk exposure assessment of per- and polyfluoroalkyl substances (PFASs) in drinking water and atmosphere in central eastern China.

The original publication of this paper contains a mistake.

Risk exposure assessment of per- and polyfluoroalkyl substances (PFASs) in drinking water and atmosphere in central eastern China.

We examined per- and polyfluoroalkyl substances (PFASs) in air from eight cities, and in water from six drinking-water treatment plants (DWTPs), in central eastern China. We analyzed raw and treated water samples from the DWTPs for 17 ionic PFASs with high-performance liquid chromatography/negative-electrospray-ionization tandem mass spectrometry (HPLC/(-)ESI-MS/MS), and analyzed the gas and particle phases of atmospheric samples for 12 neutral PFASs by gas chromatography-mass spectrometry (GC-MS). Perfluorooctanoic acid (PFOA) and perfluorohexanoic acid (PFHxA) were the dominant compounds in drinking water, and fluorotelomer alcohols (FTOHs) dominated in atmospheric samples. Of all the compounds in the treated water samples, the concentration of PFOA, at 51.0 ng L-1, was the highest. Conventional treatments such as coagulation (COA), flocculation (FOC), sedimentation (SED), and sand filtration (SAF) did not remove PFASs. Advanced treatments, however, including ultrafiltration (UF) and activated carbon (AC), removed the majority of PFASs except for shorter-chain PFASs such as perfluorobutanoic acid (PFBA) and perfluoropentanoic acid (PFPA). We also investigated human exposure to PFASs via drinking water and the atmosphere and found that the mean daily intake of PFASs was 0.43 ng kg-1 day-1.