Ecological risk assessment of metals in the Arctic environment with emphasis on Kongsfjorden Fjord and freshwater lakes of Ny-Ålesund, Svalbard.

The concentrations of five heavy metals (Cd, Cr, Cu, Pb, and Zn) in the sediments, water, phytoplankton, zooplankton, and macroalgae from Kongsfjorden Fjord and the freshwater lakes of Ny-Ålesund in the Svalbard archipelago were determined in order to describe the anthropogenic impacts related to the Ny-Ålesund town. Water samples from nine stations, sediment samples from 23 stations, plankton samples from five stations, and six species of macroalgae were collected and subjected to heavy metal analysis using atomic absorption spectrophotometry (AAS). Only Cu and Zn were detected in the water samples. The plankton samples had only Zn, Cu, and Cr. The average metal concentrations in macroalgae fell in the decreasing order of Cu > Zn > Cr > Cd > Pb. In sediment samples, the metal order was as follows: Zn > Cu > Cr > Pb > Cd. Multivariate statistical analyses including principal component analysis (PCA) and hierarchical cluster analysis (HCA) were used to identify the source of the metal contamination. The metals were found to originate from a blend of both anthropogenic and geogenic sources. Pollution monitoring indices including geoaccumulation index (Igeo), contamination factor, contamination degree (Cdeg), pollution load index (PLI), and potential ecological risk (PER) were calculated using the metal data. In the study area, Igeo values of the metals showed pollution grades from 0 (uncontaminated) to 6 (extremely contaminated). Cdeg fell in classes from 1 (low contamination) to 4 (very high contamination). PLI values ranged between 0 and 5.68. PER values expressed that except for a few stations located at higher elevations in the glacial outwash plains, all other sites were highly polluted. The high level of pollution indices in the sites can be attributed to the anthropogenic activities persistent in the study area.

Metal-associated human health risk assessment due to consumption of pelagic and benthic ichthyofaunal resources from the highly contaminated Cuddalore coast in Southern India.

We present seasonal variation of four metals (Cd, Cu, Pb, and Zn) in nine pelagic and three benthic fish species from the highly polluted Cuddalore coast in Tamil Nadu, India. Metals were assessed using atomic absorption spectrometry and detected in all fish species, in at least one season, except Iniistius cyanifrons where cadmium was not detected throughout. In both benthic and pelagic fish, order of metal concentration was Zn > Cu > Pb > Cd. Multivariate statistical analysis revealed that metals may have originated from both natural and anthropogenic sources. Health risk assessment revealed that consumption of fish from Cuddalore coast does not pose health risk for now; however, hazard index values (pelagic = 0.97; benthic = 0.90) are in borderline. Even a slight increase in metal concentration in fish can prove hazardous for human consumption. Sooner or later, eating fish from Cuddalore coast may pose a considerable health risk to humans if metal pollution is not held at Bay.

Assessment of renal and hepatic dysfunction by co-exposure to toxic metals (Cd, Pb) and fluoride in people living nearby an industrial zone.

Togo's phosphate processing plant at Kpeme discharges waste, containing Cd, Pb, and fluoride, into the sea and on the soil. Heavy metals toxicity on kidneys and the liver has been studied. However, fluoride toxicity on these organs remains to be investigated. The present study deals with the variation in renal and hepatic functioning parameters due to fluoride, Cd and Pb. Totally, 350 volunteers were recruited from five different localities around this phosphate processing plant for sample collection. Cd and Pb contents in blood samples were determined by spectrophotometry and fluoride by the titanium chloride method. Biochemical parameters were measured using Biolab kits. The pollutant contents were elevated in polluted areas where ASAT, ALAT, creatinine, and urea increased, and total protein decreased. Correlation and multivariate tests showed that fluoride is related to the various pathologies mentioned. PCA revealed that phosphate processing in Togo is a source of renal and hepatic toxicity.