RESUMO
We agree with Bruineberg and colleagues' main claims. However, we urge for a more forceful critique by focusing on the extended mind debate. We argue that even once the Pearl and Friston versions of the Markov blanket have been untangled, that neither is sufficient for tackling and resolving the question of demarcating the boundaries of the mind.
Assuntos
Leucemia Linfocítica Crônica de Células B/epidemiologia , Adulto , Idoso , Idoso de 80 Anos ou mais , Antígenos CD/análise , Estudos Transversais , Feminino , Humanos , Incidência , Irlanda/epidemiologia , Leucemia Linfocítica Crônica de Células B/diagnóstico , Leucemia Linfocítica Crônica de Células B/economia , Masculino , Pessoa de Meia-IdadeRESUMO
Employing the thiophene based quinone, benzo[1,2-b:4,5-b']dithiophene-4,8-dione, as the electron-accepting moiety alongside N-phenylcarbazole donors to produce a donor-π-acceptor-π-donor (D-π-A-π-D) molecule has yielded a new red emitter displaying delayed fluorescence. This new molecule shows strongly (over 100 nm) red-shifted emission when compared to an anthraquinone based analogue. Cyclic voltammetry complemented by computational insights prove that this red-shift is due to the significantly stronger electron-accepting ability of the thiophene quinone compared to anthraquinone. Photophysical and computational studies of this molecule have revealed that while the presence of the thiophene containing acceptor facilitates rapid intersystem crossing which is comparable to anthraquinone analogues, the reverse intersystem crossing rate is slow and non-radiative decay is rapid which we can attribute to low-lying locally excited states. This limits the total photoluminescence quantum efficiency to less than 10% in both solution and the solid state. These results provide a useful example of how very minor structural variations can have a defining impact on the photophysical properties of new molecular materials.