Recycling waste dolomite powder in cement paste: Early hydration process, microscale characteristics, and life-cycle assessment.

Waste dolomite powder (WDP) is a byproduct obtained from dolomite quarries during the preparation of dolomite products. To study the re-utilisation of WDP, an eco-friendly cement-based material was prepared using WDP as a micro-aggregate. The effects of WDP on the early hydration process, microscale characteristics, and life-cycle assessment of cement paste are discussed in this study. The isothermal calorimetry results showed that the incorporating WDP in cement paste accelerated the early hydration process of cement according to the degree of reaction. In this case, the setting time of the cement pastes with WDP was shortened, and the early compressive strength was significantly improved. The results of X-ray diffraction and scanning electron microscopy analysis at early curing ages (1 and 3 d) showed changes in the peak intensity of ettringite and portlandite and a denser microstructure. Mercury intrusion porosimetry tests showed that the middle and large capillary pores were refined by the nucleation and filling effects of WDP. Based on environmental and economic evaluations, the utilisation of WDP reduced energy consumption, CO2 emissions, and economic costs. Compared to the sample without WDP, the energy consumption, CO2 emissions, and economic cost indices were 42 %, 42.69 %, and 39.4 % lower, respectively. Our results may provide valuable references for the re-utilisation of WDP in low-carbonation cement-based materials.

Three new flavonoid glycosides from the aerial parts of Allium sativum L. and their anti-platelet aggregation assessment.

Three new flavonoid glycosides, Dasuanxinoside F-H (1-3), were isolated from the aerial parts of Allium sativum, together with eight known compounds which were firstly reported in this plant, including three flavonoid glycosides (4-6) and five phenylethanoid glycosides (7-11). Their structures were identified by UV-vis, IR, 1D and 2D NMR spectra, as well as HR-ESI-MS analyses. The inhibitory effect of the isolated compounds on platelet aggregation induced by adenosine diphosphate (ADP) was evaluated in vitro. The results showed that most compounds displayed different degrees of inhibition. Among them, 2, 5, 8 and 9 exhibited the strongest activity on platelet aggregation.

Combining Data from Multiple Sources to Evaluate Spatial Variations in the Economic Costs of PM2.5-Related Health Conditions in the Beijing-Tianjin-Hebei Region.

Fine particulate matter, known as PM2.5, is closely related to a range of adverse health outcomes and ultimately imposes a high economic cost on the society. While we know that the costs associated with PM2.5-related health outcomes are not uniform geographically, a few researchers have considered the geographical variations in these costs because of a lack of high-resolution data for PM2.5 and population density. Satellite remote sensing provides highly precise, high-resolution data about how PM2.5 and population density vary spatially, which can be used to support detailed health-related assessments. In this study, we used high-resolution PM2.5 concentration and population density based on remote sensing data to assess the effects of PM2.5 on human health and the related economic costs in the Beijing-Tianjin-Hebei (BTH) region in 2016 using exposure-response functions and the relationship between health and economic costs. The results showed that the PM2.5-related economic costs were unevenly distributed and as with the population density, the costs were mainly concentrated in urban areas. In 2016, the economic costs of PM2.5-related health endpoints amounted to 4.47% of the total gross domestic product in the BTH region. Of the health endpoints, the cost incurred by premature deaths accounted for more than 80% of the total economic costs associated with PM2.5. The results of this study provide new and detailed information that could be used to support the implementation of national and regional policies to reduce air pollution.

Low-cost, acid/alkaline-resistant, and fluorine-free superhydrophobic fabric coating from onionlike carbon microspheres converted from waste polyethylene terephthalate.

Onionlike carbon microspheres composed of many nanoflakes have been prepared by pyrolyzing waste polyethylene terephthalate in supercritical carbon dioxide at 650 °C for 3 h followed by subsequent vacuum annealing at 1500 °C for 0.5 h. The obtained onionlike carbon microspheres have very high surface roughness and exhibit unique hydrophobic properties. Considering their structural similarities with a lotus leaf, we further developed a low-cost, acid/alkaline-resistant, and fluorine-free superhydrophobic coating strategy on fabrics by employing the onionlike carbon microspheres and polydimethylsiloxane as raw materials. This provides a novel technique to convert waste polyethylene terephthalate to valuable carbon materials. At the same time, we demonstrate a novel application direction of carbon materials by taking advantage of their unique structural properties. The combination of recycling waste solid materials as carbon feedstock for valuable carbon material production, with the generation of highly value-added products such as superhydrophobic fabrics, may provide a feasible solution for sustainable solid waste treatment.