Source apportionment and ecological health risks assessment from major ions, metalloids and trace elements in multi-aquifer groundwater near the Sunan mine area, Eastern China.

Evaluating the ecological health risks created by major ions, metalloids and trace elements concentrations in groundwater and pollution sources were essential to effectively protect groundwater resources. For this study, A total of 93 samples were collected from multiple aquifers in the Sunan mining area, eastern China. The Positive matrix factorization (PMF) model results revealed the following sources, in percentages. The Quaternary loose aquifer (QLA) water includes CaMg mineral dissolution (30.3 %), salinity (28.2 %), metal industrial wastewater (26.3 %), iron and manganese minerals (8.0 %) and coal gangue (7.2 %). The Permian fractured sandstone aquifer (PFA) water includes CaMg mineral dissolution sources (29.8 %), mine wastewater (28.6 %), aluminosilicate (21.6 %) and pyrite source (20.0 %). The Carbonifer fractured limestone aquifer (CFA) water includes and mine wastewater (34.2 %), CaMg mineral dissolution (25.4 %), pyrite (22.6 %) and aluminosilicate (17.7 %). The Ordovician fractured limestone aquifer (OFA) water includes manganese and aluminum metal minerals (27.9 %), halite dissolution materials (24.9 %), industrial and agricultural waste water (24.0 %) and calcium­magnesium minerals (23.2 %). A PMF-based assessment of ecological health risk indicates that the concentrations of elements As and Co are the dominant elements impacting non-carcinogenic and carcinogenic risks; and As, Cr, and Cu are the dominant elements impacting potential ecological risks. These mainly originate from geological sources, coal gangue sources, mine drainage sources and agricultural sewage discharge sources. The study showed the sources of groundwater pollution in multiple aquifers and their priority treatment areas, providing a basis for groundwater management and protection.

Ecological Risk Assessment and Influencing Factors of Heavy-Metal Leaching From Coal-Based Solid Waste Fly Ash.

In order to promote and broaden the utilization of fly ash as a resource, the fly ash from a 2,660-MW coal-fired power plant in Huainan (China) was investigated. The physical and chemical properties of fly ash were characterized by scanning electron microscopy, energy spectrum analysis, and XRD. The content and different forms of the heavy metals Cd, Cr, Cu, Co, and Ni were determined by acid digestion, oscillation leaching, and Tessier five-step extraction. The effect of pH, temperature, and particle size on the leached amount of heavy metals was studied. Finally, the ecological risk index was calculated for each heavy metal via the risk assessment coding (RAC) method and Hakanson ecological risk assessment method, allowing the ecological risk of fly ash to be determined under different environmental conditions. Results showed that the average concentrations of Cd, Cr, Co, and Ni were all below the risk screening values reported for environmental pollutants (pH > 7.5). Under varying pH, temperature, and particle size conditions, the leached amounts (oscillation leaching) were below the soil risk screening values for agricultural land in China. An RAC-Cd value of >50% indicates a high ecological risk, while the RAC values of Co and Ni were between 10 and 30%, indicating a medium ecological risk, and the RAC values of Cr and Cu were <10%, indicating a low ecological risk. With increasing pH, the potential ecological risk index (RI) decreased, with a maximum RI of 59.62 observed at pH 2.8. With increasing temperature, the potential ecological RI increased initially to a maximum of 27.69 at 25°C and then decreased thereafter. With increasing particle size, the ecological RI decreased, with the highest RI of 4.06 occurring at <0.075 mm. The Hakanson ecological RI value was below 150, indicating a slight ecological risk. Therefore, fly ash can be considered as a soil additive and conditioner that is suitable for use in the improvement of reclamation soil in coal mining subsidence areas.

Distribution, sources, and ecological risk assessment of HCHs and DDTs in water from a typical coal mining subsidence area in Huainan, China.

Coal mining subsidence areas are a special and widespread ecosystem in China and many developing countries in the world. However, limited research has focused on HCHs and DDTs in coal mining subsidence areas. Investigating the concentration, distribution, and sources of HCHs and DDTs at the Yangzhuang coal mining subsidence area in Huainan, China, is the object of this study. Water samples from different depths were collected from this region to detect and analyze HCHs and DDTs using gas chromatography-mass spectrometry. The result showed that the concentrations of HCHs and DDTs increased with increasing water depth, and the average concentrations of HCHs and DDTs in the top (T-layer), middle (M-layer), and bottom (B-layer) layers were 152, 169, and 182 ng∙L-1, respectively. Spatial distribution of HCH and DDT concentrations in the study area revealed that the concentrations gradually decreased in the direction of water flow, and the highest concentration was observed at the entrance of the Nihe River. The T-layer was easily influenced by environmental and human activities, while the M-layer and B-layer were mainly influenced by sediment. Using principal component analysis and diagnostic ratios, we found that HCHs and DDTs in the study area mainly originated due to natural and human activities (such as pesticide use). Hexachlorocyclohexanes (HCHs) were mainly derived from lindane, and dichlorodiphenyltrichloroethanes (DDTs) mainly originated due to the recent agricultural use of dicofol; both of these are directly related to agricultural activities. Based on a comparison of reported concentrations of HCHs and DDTs in the rivers and lakes throughout China, we found that the overall ecological risk of HCHs and DDTs in the study area was elevated. The results are important for further understanding the transfer characteristics of HCHs and DDTs as well as the ecological health of the water in coal mining subsidence areas.