Determination of heavy metals and risk assessment in nail cosmetics sold in Seoul, Korea.

OBJECTIVE: The objective of this study was to evaluate some toxic levels of nail cosmetics marketed in Seoul, Korea and health risk assessment on humans. METHODS: We collected 45 random nail cosmetics and analysed for lead, cadmium, arsenic and antimony by inductively coupled plasma-optical emission spectrometry (ICP-OES). RESULTS: Four metals concentrations were Pb 0.037 ± 0.083 (

Pesticide residues in vegetables and risk assessment for consumers in Korea during 2010-2014.

This study was carried out to assess the exposure to pesticide residues from vegetable consumption of residents in Seoul using data on pesticide residue concentrations and the quantity of vegetables consumed. A total of 34,520 samples of 96 types of vegetables collected from 2010 to 2014 by the Seoul Metropolitan Government Institute of Health and Environment (SIHE) were analysed for 283 different pesticide residues. Among the vegetable samples, 86.1% did not contain any measurable levels of pesticide and 1.4% had residues exceeding Maximum Residue Limits (MRL). A total of 105 different pesticide residues were found and 45 residues exceeded MRLs. The most commonly found residues were azoxystrobin, diethofencarb, procymidone, cypermethrin, and tebufenpyrad. A total of 547 vegetable samples from 37 different types of vegetables had residues exceeding MRLs. From these results, 20 agrochemicals were chosen based on their high level of detection and violation rate of the MRL. The potential health risk associated with exposure to the pesticides through vegetable intake was estimated as a Risk Index (RI, %ADI). For a citizen of Seoul, the RIs of the mean value and 97.5th percentile were shown to be 0.0 ~ 7.4% and 0.4 ~ 73.9% respectively. For citizens of Seoul by age (consumers only), the highest RIs for children (under 6 years old) and the elderly (over 65 years old) were with chlorothalonil, and the estimated daily intakes (EDI) were 56.0%, 112.5%, respectively, of its ADI. For adults (19 ~ 64 years old) the highest RI was for chlorfenapyr and the EDI reached 118.6%. These results show that, despite the high levels of some pesticide residues, they may not be considered as a serious public health problem.

Monitoring and risk assessment of pesticide residues in commercially dried vegetables.

We tested for residual pesticide levels in dried vegetables in Seoul, Korea. A total of 100 samples of 13 different types of agricultural products were analyzed by a gas chromatography-nitrogen phosphate detector (GC-NPD), an electron capture detector (GC-µECD), a mass spectrometry detector (GC-MSD), and a high performance liquid chromatography-ultraviolet detector (HPLC-UV). We used multi-analysis methods to analyze for 253 different pesticide types. Among the selected agricultural products, residual pesticides were detected in 11 samples, of which 2 samples (2.0%) exceeded the Korea Maximum Residue limits (MRLs). We detected pesticide residue in 6 of 9 analyzed dried pepper leaves and 1 sample exceeded the Korea MRLs. Data obtained were then used for estimating the potential health risks associated with the exposures to these pesticides. The estimated daily intakes (EDIs) range from 0.1% of the acceptable daily intake (ADI) for bifenthrin to 8.4% of the ADI for cadusafos. The most critical commodity is cadusafos in chwinamul, contributing 8.4% to the hazard index (HI). This results show that the detected pesticides could not be considered a serious public health problem. Nevertheless, an investigation into continuous monitoring is recommended.