Evidence of economic development revealed in centennial scale sedimentary records of organic pollutants in Huguangyan Marr Lake.

Sedimentary records of polycyclic aromatic hydrocarbons (PAHs) and phthalates could reflect energy consumption and industrial production adjustment. However, there is limited knowledge about their effects on variations of PAH and phthalate compositions in the sediment core. The PAH and phthalate sedimentary records in Huguangyan Maar Lake in Guangdong, China were constructed, and random forest models were adopted to quantify the associated impact factors. Sums of sixteen PAH (∑16 PAH) and seven phthalate (∑7 PAE) concentrations in the sediment ranged from 28.8 to 1110 and 246-4290 µg/kg dry weight in 1900-2020. Proportions of 5-6 ring PAHs to the ∑16 PAHs increased from 32.0 %-40.7 % in 1900-2020 with increased coal and petroleum consumption, especially after 1980. However, those of 2-3 ring PAHs decreased from 30.7 % to 23.6 % due to the biomass substitution with natural gas. The proportions of bis (2-ethylhexyl) phthalate to the ∑7 PAEs decreased from 52.3 %-29.1 % in 1900-2020, while those of di-isobutyl phthalate increased (13.7 % to 42.3 %). The shift from traditional plasticizers to non-phthalates drove this transformation, though the primary plastic production is increasing. Our findings underscore the effectiveness of optimizing energy structures and updating chemical products in reducing organic pollution in aquatic environments.

Groundwater hydrochemistry, source identification and pollution assessment in intensive industrial areas, eastern Chinese loess plateau.

Groundwater is essential for regional ecological-economic system and is an important resource of drinking water, especially in the Chinese Loess Plateau (CLP), where is a typical water-limited ecosystem. Groundwater quality deterioration will affect water security and exacerbate the water shortages. Groundwater hydrochemistry, pollution source apportionment, quality and health risks were evaluated based on analysis of major ions and selected trace elements in seasonal samples of the Fen River Basin (FRB) in the eastern CLP. Groundwaters in the FRB were mainly HCO3--Ca2+-Na+ water type with low dissolved solutes in upstream samples, high values in midstream samples and medium values in downstream samples. Solutes in upstream samples were mainly derived from carbonate weathering, while those in midstream and downstream samples came from silicate weathering, evaporites dissolution and anthropogenic sources. Self-organizing map (SOM) showed the hydrochemistry remained unchanged from dry to wet season for most sampling points. The seasonal variations of Ag, Cd, Ni, Pb, and Tl were significant due to anthropogenic input. High NO3- in upstream and downstream samples resulted primarily from sewage discharge, and high SO42- in midstream and downstream samples was from gypsum- and coal-related industries. In addition, anthropogenic input related to coal industries significantly aggravates pollution of As, Ni, Ag, Fe, and Mn. Influenced by evaporites and anthropogenic input, midstream samples had high salinity, total hardness and water quality indices (WQIs) and were unsuitable for irrigation or drinking purposes. Seasonal variation of WQI in the FRB was unsignificant except Jiaokou River sub-basin, where groundwater quality was worse in the wet season than the dry season due to coal mining. Great attention should be paid to the high non-carcinogenic risks of exposure to F, V, Mn, and Cr via dermal absorption, particularly for children. Overall, groundwater quality in the FRB was best in upstream, medium in midstream and worst in midstream based on different index. Groundwater quality is deteriorated by anthropogenic input and the sewage discharge in the FRB should be strictly controlled. Our report provides a reference for groundwater pollution evaluation and source identification in similar areas.

Spatiotemporal variations, sources, water quality and health risk assessment of trace elements in the Fen River.

As the largest river in Shanxi Province, the Fen River is the main water source for regional economic and ecological development. Water deficiency and industrialization have led to serious water pollution in the Fen River. The major and trace elements of seasonal river waters were measured to determine the spatiotemporal variations and assess the water quality as well as its controlling factors in the Fen River. Trace elements are divided into high abundance elements (B, Ba, Li, and Mn) and low abundance elements (As, Cu, Fe, Ni, Rb, Se, U, and V). The spatial variation of trace elements is obvious, with low values upstream, intermediate values downstream, and very high values midstream. The average values of the trace elements showed different seasonal variations, with high values of As, B, Ba, Mn, and Rb in the wet season, high Cu, V, and Li values in the dry season, and minor seasonal variations of Fe, Ni, Se, and U concentrations. Principal component analysis (PCA) and correlation analysis (CA) showed natural origins of Ba, Mn, Ni, and U, anthropogenic input of As, B, Cu, Li, Rb, Se, and V. According to the results of absolute principal component sore-multivariate linear regression (APCS-MLR), the major pollution sources in the Fen River basin were related to human activities. The land use type significantly influenced the concentrations of trace elements, with high values in the cropland and low values in the forest. The water quality index (WQI) values were higher in the midstream and wet season. In comparison with other rivers in the world, the pollution of the Fen River is at a moderate level. Health risk assessment showed that As, Ba, Mn, Ni, V, and Se were the potential pollutants damaging in the Fen River, especially for children. This study highlights the importance of seasonal sample analysis and can provide vital data for water quality conservation in the Fen River basin.

Spatiotemporal trends of atmospheric Pb over the last century across inland China.

Sedimentary records from remote regions contain pollutants derived dominantly from atmospheric input, and thus have the potential to trace past atmospheric pollution history. Based on seventeen sediment records from relatively remote areas of China, atmospheric Pb pollution history during the last century was studied. These records suggest only occasionally slight pollution before ~1950 and display synchronous Pb enrichment processes since the 1950s, implying the start of widespread atmospheric Pb pollution in China. This corresponded well with the beginning of socio-economic development after the establishment of the People's Republic of China. However, owing to the Chinese Cultural Revolution, a roughly unchanged atmospheric Pb status was found in the 1960-70s except on the Qinghai-Tibetan Plateau, where atmospheric Pb still increased gradually caused by long-range atmospheric transport of pollutants from southwest Asia. In ~1980-2000, atmospheric Pb experienced the greatest increase, resulting from rapid development of extensive economy after the Reform and Opening-up in 1978. After ~2000, atmospheric Pb generally stopped increase due to the phasing out of leaded gasoline, but it remained high, with the highest in Southwest China, medium in Northeast China, central North China and the Qinghai-Tibetan Plateau, and the lowest in the southeast Mongolia Plateau and West China. This study reveals spatio-temporal variations of atmospheric Pb in inland China under the influence of recent human activities, providing an important supplement for understanding global Pb pollution in the Anthropocene.

One-century sediment records of heavy metal pollution on the southeast Mongolian Plateau: Implications for air pollution trend in China.

Historical records of heavy metals from remote areas are important for assessing temporal pollution trends of the regional atmosphere. Based on comparison analyses of heavy metals, Pb isotopes, and total carbon in sediment cores from two relatively remote lakes on the southeast Mongolian Plateau, atmospheric heavy metal pollution trends during ∼1900-2016 were reconstructed. The current anthropogenic fluxes of Zn, Cd and Pb in the region are 11.7, 0.104 and 2.44 mg m-2 yr-1, respectively, close to those in Lake Sayram in West China, but lower than most other records in China. Anthropogenic metal fluxes and 206Pb/207Pb ratios suggest that (1) before ∼1950 atmospheric metal pollution was negligible in the region; (2) since ∼1950, the pollution became detectable but was relatively slight until ∼1980, corresponded with the beginning of socio-economic development after the foundation of China in 1949 and the rapid development after the Reform and Opening-up in 1978; and (3) since ∼2000, atmospheric Pb stopped increasing because of the phasing out of leaded gasoline. Based on comparison and fitting analyses with other sediment records, a similar four-stage evolution picture of atmospheric heavy metals in China over the last century was uncovered. This study indicates rapid increase trends of atmospheric heavy metals in China since ∼1980 associated with economic development.

Sedimentary biogeochemical record in Lake Gonghai: Implications for recent lake changes in relatively remote areas of China.

Owing to rapid socio-economic development and climate warming, lakes even in remote areas have experienced marked changes in the last century. However, there are few studies revealing the multi-faceted biogeochemical changes and disentangling impacts of human and climate in relatively remote lakes in China. In this study we reconstructed historical changes of geochemistry, nutrition, primary production, ecology, and pollution in an alpine lake (Gonghai) in central North China, and revealed coherent changes and drivers in relatively remote Chinese lakes by compiling other records. Results show that Lake Gonghai has experienced considerably biogeochemical changes since the 1980s induced mainly by increased regional human activities, with detected human-related changes occurring in the 1950s-70s. The most important change is a shift of diatom primary producers in the 1980s, caused mainly by an increase of regional atmospheric N and P deposition associated with rapid socio-economic development. Another remarkable change is the increase of pollution levels since the 1980s, represented by heavy metals, also caused by atmospheric deposition. Compiled sediment records demonstrate similar biogeochemical changes in most lakes from relatively remote areas of China since the 1970s-80s, associated closely with increased inputs of human-induced atmospheric N, P and pollutants, whereas the influence of climate warming is likely limited. This study highlights markedly human-related biogeochemical changes in relatively remote Chinese lakes during the Anthropocene epoch.

Characteristics, sources, water quality and health risk assessment of trace elements in river water and well water in the Chinese Loess Plateau.

Water resources and water quality are restrictive factors in the Chinese Loess Plateau (CLP), a unique area with most severe soil erosion, fragile ecology and water shortage. River and well water samples were firstly analyzed, and multiple methods and indexes, including principal component analysis (PCA), correlation analysis (CA), sodium adsorption ratio (SAR), water quality index (WQI), hazard quotient (HQ), and hazard index (HI), were used to investigate characteristics, water quality and health risk assessment of trace elements in CLP. The average trace elements concentrations were higher than the world average with a slightly alkaline characteristic. PCA and CA showed that Al, Fe, Li, B, As, and F had natural origins from loess weathering and leaching; Cr, Pb, Cd, Cu, Ag, and Tl were mainly from anthropogenic input; Co, Ni, and Mn were dominated by both anthropogenic and natural sources. The poor river water quality was mainly related with high sodium (alkalinity) and salinity hazard. The poor well water quality samples with high WQI values, especially for As, Cr, and B, were distributed in the northwest and the Fenhe River sub-basin. The pollution level of trace elements in rivers in CLP was in medium level compared with other rivers worldwide. Arsenic pollution was the worst in well water and was the potential pollutant in river water especially for children. Arid climate together with anthropogenic input and special water characteristics (high Na, pH, and low Ca) aggravated As pollution. More work should be done to monitor the secular variation and remove As in the high As areas. The results of this study can provide the basic data for efficient water management and human health protection in CLP.

Assessment of the hydrogeochemistry and groundwater quality of the Tarim River Basin in an extreme arid region, NW China.

The concentrations of the major and trace elements in the groundwater of the Tarim River Basin (TRB), the largest inland river basin of China, were analyzed before and during rainy seasons to determine the hydrogeochemistry and to assess the groundwater quality for irrigation and drinking purposes. The groundwater within the TRB was slightly alkaline and characterized by high ionic concentrations. The groundwater in the northern sub-basin was fresh water with a Ca(2+)-HCO3(-) water type, whereas the groundwater in the southern and central sub-basins was brackish with a Na(+)-Cl(-) water type. Evaporite dissolution and carbonate weathering were the primary and secondary sources of solutes in the groundwater within the basin, whereas silicate weathering played a minor role. The sodium adsorption ratio (SAR), water quality index (WQI), and sodium percentage (%Na) indicated that the groundwater in the northern sub-basin was suitable for irrigation and drinking, but that in the southern and central sub-basins was not suitable. The groundwater quality was slightly better in the wet season than in the dry season. The groundwater could be used for drinking after treatment for B(3+), F(-), and SO4(2-) and for irrigation after control of the sodium and salinity hazards. Considering the high corrosivity ratio of the groundwater in this area, noncorrosive pipes should be used for the groundwater supply. For sustainable development, integrated management of the surface water and the groundwater is needed in the future.

Sedimentary record of hydrophobic organic compounds in relation to regional economic development: a study of Taihu Lake, East China.

Sediment cores taken from Taihu Lake, East China were analyzed for polycyclic aromatic hydrocarbons (PAHs), organochlorine pesticides (OCPs) and polybrominated biphenyl ethers (PBDEs). The results showed a general sharp increase of HCH, DDT, PAH and PBDE concentrations in the surface layers, corresponding to a sedimentation time of 1980 and 1990 onward in the Meiliang Bay and Xukou Bay, respectively. The source of PAHs has largely transferred from petrogenic to pyrogenic origin, and good relationships were observed between sediment PAH concentrations and the regional gross domestic product. The sharp increase of DDTs in recent years may be related to the mobilization and migration of these chemicals from surface soil to lake sediment, as a result of enhanced soil run-off due to large scale land transform, as well as the contribution of current usage of dicofol and DDT-containing anti-fouling paints.