Microplastics in drinking water: A review on methods, occurrence, sources, and potential risks assessment.

Microplastics in drinking water captured widespread attention following reports of widespread detection around the world. Concerns have been raised about the potential adverse effects of microplastics in drinking water on human health. Given the widespread interest in this research topic, there is an urgent need to compile existing data and assess current knowledge. This paper provides a systematic review of studies on microplastics in drinking water, their evidence, key findings, knowledge gaps, and research needs. The data collected show that microplastics are widespread in drinking water, with large variations in reported concentrations. Standardized methodologies of sampling and analysis are urgently needed. There were more fibrous and fragmented microplastics, with the majority being <10 µm in size and composed of polyester, polyethylene, polypropylene, and polystyrene. Little attention has been paid to the color of microplastics. More research is needed to understand the occurrence and transfer of microplastics throughout the water supply chain and the treatment efficiency of drinking water treatment plants (DWTPs). Methods capable of analyzing microplastics <10 µm and nanoplastics are urgently needed. Potential ecological assessment models for microplastics currently in use need to be improved to take into account the complexity and specificity of microplastics.

Characteristics, sources, and health risk assessment of atmospheric particulate mercury in Guanzhong Basin.

Mercury (Hg) has received increasing public attention owing to its high toxicity and global distribution capability via long-range atmospheric transportation. Guanzhong Basin (GB) is vital for the industrial and economic development of Shaanxi Province. To determine the concentration, spatial distribution, seasonal variation, sources, and health risks of particulate-bound mercury (PBM), PM2.5 samples were collected at three sampling sites representing urban, rural, and remote areas during winter and summer in GB. The three sampling sites were in Xi'an (XN), Taibai (TB), and the Qinling Mountains (QL). The mean PBM concentrations in XN, TB, and QL in winter were 130 ± 115 pg m-3, 57.5 ± 47.3 pg m-3, and 53.6 ± 38.5 pg m-3, respectively, higher than in summer (13.7 ± 7.11 pg m-3, 8.01 ± 2.86 pg m-3, and 7.75 ± 2.85 pg m-3, respectively). PBM concentrations are affected by precipitation, meteorological conditions (temperature and mixed boundary layer), emission sources, and atmospheric transport. During the sampling period, the PBM dry deposition in XN, TB, and QL was 1.90 µg m-2 (2 months), 0.835 µg m-2 (2 months), and 0.787 µg m-2 (2 months), respectively, lower than the range reported in national megacities. According to backward trajectory and potential source contribution factor (PSCF) analysis, mercury pollution in XN is mainly affected by local pollution source emissions, whereas the polluted air mass in TB and QL originates from local anthropogenic emissions and long-distance atmospheric transmission. The non-carcinogenic health risk values of PBM in XN, TB, and QL in winter and summer were less than 1, indicating that the risk of atmospheric PBM to the health of the residents was negligible.

Variability of ambient black carbon concentration in the Central Himalaya and its assessment over the Hindu Kush Himalayan region.

During 2015-2018, eight black carbon (BC) monitoring sites were established in Nepal and Bhutan to fill a significant data gap regarding BC measurement in Central Himalaya. This manuscript analyzes and presents data from these eight stations and one additional station on the Tibetan plateau (TP). Complex topography, varied emission sources, and atmospheric transport pathways significantly impacted the BC concentrations across these stations, with annual mean concentrations varying from 36 ng m-3 to 45,737 ng m-3. Higher annual mean concentrations (5609 ± 4515 ng m-3) were recorded at low-altitude sites than in other locations, with seasonal concentrations highest in the winter (7316 ± 2541 ng m-3). In contrast, the annual mean concentrations were lowest at high-altitude sites (376 ± 448 ng m-3); the BC concentrations at these sites peaked during the pre-monsoon season (930 ± 685 ng m-3). Potential source contributions to the total observed BC were analyzed using the absorption angstrom exponent (AAE). AAE analysis showed the dominance of biomass burning sources (>50 %), except in Kathmandu. By combining our data with previously published literature, we put our measurements in perspective by presenting a comprehensive assessment of BC concentrations and their variability over the Hindu Kush Himalayan (HKH) region. The BC levels in all three geographic regions, high, mid, and low altitude significantly influenced by the persistent seasonal meteorology. However, the mid-altitude stations were substantially affected by valley dynamics and urbanization. The low-altitude stations experienced high BC concentrations during the winter and post-monsoon seasons. Concentration weighted trajectory (CWT) and frequency analyses revealed the dominance of long-range transported pollution during winter over HKH, from west to east. South Asian sources remained significant during the monsoon season. During pre- and post-monsoon, the local, regional, and long-distance pollution varied depending on the location of the receptor site.

Polar amplification comparison among Earth's three poles under different socioeconomic scenarios from CMIP6 surface air temperature.

The polar amplification (PA) has become the focus of climate change. However, there are seldom comparisons of amplification among Earth's three poles of Arctic (latitude higher than 60 °N), Antarctica (Antarctic Ice Sheet) and the Third Pole (the High Mountain Asia with the elevation higher than 4000 m) under different socioeconomic scenarios. Based on CMIP6 multi-model ensemble, two types of PA index (PAI) have been defined to quantify the PA intensity and variations, and PAI1/PAI2 is defined as the ratio of the absolute value of surface air temperature linear trend over Earth's three poles and that for global mean/over other regions except Earth's three poles. Arctic warms fastest in winter and weakest in summer, followed by the Third Pole, and Antarctica warms least. The similar phenomenon proceeds when global warming of 1.5-2.0 °C, and 2.0-3.0 °C above pre-industrial levels. After removing the Earth's three poles self-influence, all the PAI2s increase much more obviously relative to the PAI1s, especially the Antarctic PAI. Earth's three poles warm faster than the other regions. With the forcing increasing, PA accelerates much more over Antarctica and the Third Pole, but becomes weaker over Arctic. This demonstrates that future warming rate might make a large difference among Earth's three poles under different scenarios.

Contrasting changes in long-term wet mercury deposition and socioeconomic development in the largest city of Tibet.

Information about the long-term trends of wet mercury (Hg) deposition is important for assessing the impact of atmospheric pollution on environmental health. As the most populated and capital city of Tibet, Lhasa is isolated far away from the heavily-polluted urban clusters in China. In this study, a 10-year observation was conducted in Lhasa to establish the long-term trend of wet Hg deposition and investigate the possible causes of this variation trend. Our study showed no significant increase in wet Hg deposition while Lhasa has achieved rapid population and economic growth during the study period. The contrasting changes in long-term wet Hg deposition and socioeconomic development (e.g., GDP growth) could be greatly attributed to the efforts in preventing and controlling air pollution at regional and local levels. This trend in Lhasa differs greatly from those observed by a rapid increase of Hg trend in the remote areas of the Tibetan Plateau. Our findings indicate that the remote cryospheric areas over the Tibetan Plateau are prone to be affected by transboundary Hg pollution, and more attention should be paid to its environmental and health effects for future study.

Atmospheric particle-bound polycyclic aromatic compounds over two distinct sites in Pakistan: Characteristics, sources and health risk assessment.

Much attention is drawn to polycyclic aromatic hydrocarbons (PAHs) as an air pollutant due to their toxic, mutagenic and carcinogenic properties. Therefore, to understand the levels, seasonality, sources and potential health risk of PAHs in two distinct geographical locations at Karachi and Mardan in Pakistan, total suspended particle (TSP) samples were collected for over one year period. The average total PAH concentrations were 31.5 ± 24.4 and 199 ± 229 ng/m3 in Karachi and Mardan, respectively. The significantly lower concentration in Karachi was attributed to diffusion and dilution of the PAHs by the influence of clean air mass from the Arabian sea and high temperature, enhancing the volatilization of the particle phase PAHs to the gas phase. Conversely, the higher concentration (~6 times) in Mardan was due to large influence from local and regional emission sources. A clear seasonality was observed at both the sites, with the higher values in winter and post-monsoon due to higher emissions and less scavenging, and lower values during monsoon season due to the dilution effect. Diagnostic ratios and principal component analysis indicated that PAHs in both sites originated from traffic and mixed combustion sources (fossil fuels and biomass). The average total BaP equivalent concentrations (BaPeq) in Karachi and Mardan were 3.26 and 34 ng/m3, respectively, which were much higher than the WHO guideline of 1 ng/m3. The average estimates of incremental lifetime cancer risk from exposure to airborne BaPeq via inhalation indicated a risk to human health from atmospheric PAHs at both sites.

Gaseous and particulate pollutants in Lhasa, Tibet during 2013-2017: Spatial variability, temporal variations and implications.

In recent decades, most big cities in China have experienced severe air pollution accompanied by rapid economic and social development. Analysis of measurements of air pollutants form a fundamental basis for understanding the characteristics of air pollution and are important references for policy-making. In this study, five-year measurements of air pollutants at 6 sites in Lhasa, a typical high altitude big city in southwestern China, were analyzed from January 2013 to December 2017. Air pollutants at all the 6 sites in Lhasa generally displayed similar patterns of both diurnal and monthly variations, indicating the mixed atmospheric environment and the overall effect of the meteorological conditions in the city. Spatially, the air pollutant concentrations at the 6 sites were generally characterized by high concentrations of SO2, NO2, CO, PM10 and PM2.5 at urban sites and high O3 concentrations at suburban sites. In comparison with other provincial capital cities in China, Lhasa has low concentrations of air pollutants, except for O3, and thus, better air quality. Although Lhasa has experienced rapid urbanization and economic development, air pollution conditions have remained rather stable and even decreased slightly in term of particular air pollutants. We suggested that the relatively isolated location, low air pollutant emissions associated with its industrial structure and renewable energy consumption, and effective air pollution control measures, collectively contributed to the synchronous improvement of the economy and air quality in Lhasa. Such "Lhasa pattern" may serve as a positive example for other regional hub cities in China and beyond that experience socioeconomic development and simultaneously seek to improve air quality.

Hydrochemical assessment (major ions and Hg) of meltwater in high altitude glacierized Himalayan catchment.

Snowpack and glacial melt samples were collected to understand the hydrochemical, isotopic characteristics and the source of Hg contamination in high altitude glacierized Himalayan catchment. Both the snow and glacial melt were acidic in nature with calcium and magnesium as the dominant cations and bicarbonate and chloride as the dominant anions. The major ion concentrations for cations were found to be Ca2+ > Mg2+ > Na+ > K+ and HCO3- > Cl- > SO42- > NO3- for anions. The atmospheric processes like the precipitation source and aerosol scavenging control the snow chemistry and the weathering of the rocks modify the hydrochemistry of glacial melt. The samples of both the snow and glacial melt were classified as Ca-Mg-HCO3- type. The concentration of Hg in snow (154.95 ng L-1) and glacial melt (112.04 ng L-1) was highest (still lower compared to the maximum permissible limit (1000 ng L-1) by WHO in drinking water) during summer season (August-September) and lowest (snow 2.2 and 40.01 ng L-1 for glacial melt) during winter (November). The results reveal that mercury concentration in snowpacks is attributed to the combined mixing of long-range transport of pollutants via westerlies throughout the year and the industrial effluents coming from highly industrial belts of Panjab, Haryana, Rajasthan, Indo-Gangetic plains, and neighboring areas via southwest monsoons during August-September. However, in glacial melt, the Hg concentration was typically controlled by rate of melting, leaching, and percolation. Higher degree and rate of glacial melting decreases the Hg concentration in glacial melt. Stable isotopic analysis and backward air mass trajectory modeling also corroborate the source of precipitation from southwest monsoons during August-September, with its air mass trajectories passing through the highly industrialized belts of Indo-Gangetic plain and adjoining areas.

Preliminary Health Risk Assessment of Potentially Toxic Metals in Surface Water of the Himalayan Rivers, Nepal.

This study investigates the contamination levels and risk assessments of 14 elements (Ba, Cd, Co, Cr, Cu, Pb, Li, Mn, Mo, Ni, Sb, Sr, V and Zn) in three sub-basins of Himalayan rivers. Water samples were collected and the hazard quotient (HQ), hazard index (HI), and water quality index (WQI) were calculated. Total average concentrations of the metals were 135.03, 80.10 and 98.34 µg/L in Gandaki, Indrawati and Dudh Koshi rivers, respectively. The results of HQ and HI were less than unity, suggesting a low risk of metals in the region. However, HQ for antimony (Sb) was found to be 4.4 × 10-1, 2.1 × 10-1 and 5.4 × 10-1 in three river basins and HI near unity, suggesting its potential risk. Additionally, HI for Cd in Indrawati was 5.4 × 10-1 also close to unity, suggesting that Cd could have a potential risk to the local residents and aquatic ecosystems. Further, WQI suggested that the rivers Gandaki and Indrawati fell into the excellent water quality and river Dudh Koshi fell into good water quality.

Characterizations of wet mercury deposition on a remote high-elevation site in the southeastern Tibetan Plateau.

Accurate measurements of wet mercury (Hg) deposition are critically important for the assessment of ecological responses to pollutant loading. The Hg in wet deposition was measured over a 3-year period in the southeastern Tibetan Plateau. The volume-weighted mean (VWM) total Hg (HgT) concentration was somewhat lower than those reported in other regions of the Tibetan Plateau, but the VWM methyl-Hg concentration and deposition flux were among the highest globally reported values. The VWM HgT concentration was higher in non-monsoon season than in monsoon season, and wet HgT deposition was dominated by the precipitation amount rather than the scavenging of atmospheric Hg by precipitation. The dominant Hg species in precipitation was mainly in the form of dissolved Hg, which indicates the pivotal role of reactive gaseous Hg within-cloud scavenging to wet Hg deposition. Moreover, an increasing trend in precipitation Hg concentrations was synchronous with the recent economic development in South Asia.

[Chemical speciation and risk assessment of heavy metals in the middle part of Yarlung Zangbo surface sediments].

Nine heavy metals (Cd, Co, Ni, Cu, Zn, Pb, Cs, As, Cr) of surface sediments collected from the Middle Part of the Yarlung Zangbo River were analyzed by BCR sequential extraction procedure. Based on speciation distributions of these metals, ecological risk of heavy metals was assessed with methods of risk assessment code (RAC) and sediment quality guideline quotient (SQG-Q). The results show that: (1) Large part of Cr and As belong to residual fraction(87%-96%). Ni, Cu, Co and Cs have similar distribution characteristics (non-residual part accounts for approximate 20%). Correspondingly, mass fraction of Cd exists mainly in acid soluble and reducible faction (65% ) , indicating high ecological risk level. (2) Based on calculation of RAC method, Cd is of high risk to the environment (37. 38%). Accordingly, Co, Ni, Cu and Zn are of low risk, and Pb, Cs, As and Cr pose extreme low risk to the environment. According to evaluation of heavy metal speciation distributions, the potential ecological risk of heavy metals is in the descending order of Cd > Co > Ni > Cu > Zn > Pb > Cs > As > Cr. (3) The SQG index of sediments is 0. 804, indicating that studied river sediment has a moderate potential biological toxicity effect. Given most of heavy metals exists in residual fraction, the sediments of this region pose a low ecological risk to the environment.

Historical trends of atmospheric black carbon on tibetan plateau as reconstructed from a 150-year lake sediment record.

Black carbon (BC) is one of the key components causing global warming. Especially on the Tibetan Plateau (TP), reconstructing BC's historical trend is essential for better understanding its anthropogenic impact. Here, we present results from high altitude lake sediments from the central TP. The results provide a unique history of BC over the past 150 years, from the preindustrial to the modern period. Although BC concentration levels in the Nam Co Lake sediments were lower than those from other high mountain lakes, the temporal trend of BC fluxes clearly showed a recent rise, reflecting increased emissions from anthropogenic activities. The BC records were relatively constant until 1900, then began to gradually increase, with a sharp rise beginning around 1960. Recent decades show about 2.5-fold increase of BC compared to the background level. The emission inventory in conjunction with air mass trajectories further demonstrates that BC in the Nam Co Lake region was most likely transported from South Asia. Rapid economic development in South Asia is expected to continue in the next decades; therefore, the influence of BC over the TP merits further investigations.

Assessment of elemental distribution and trace element contamination in surficial wetland sediments, Southern Tibetan Plateau.

An investigation was performed to measure concentrations of major and trace elements in surficial wetland sediments in the southern Tibetan Plateau in order to assess the sediment quality. Results showed that most of elements have concentrations comparable to those of the Tibetan surface soil (TSS) except for As, Ca, Cs, Sr, and Cu. Correlation analysis indicated that most elements were highly associated with major crustal elements, suggestive of their common natural origin. Sediment quality assessment revealed that the wetlands are unpolluted with most of trace elements except for Cs and As, which are likely associated with organic matters and biological activities. Despite that the wetland sediments are minimally influenced by either local or long-transported anthropogenic pollutants, and no notable trace element pollutants were detected, As was found in elevated concentrations which far exceed the level above which harmful effects on wildlife and humans are likely to be observed.