Changes in PM2.5-related health burden in China's poverty and non-poverty areas during 2000-2020: A health inequality perspective.

China suffers from severe PM2.5 pollution that has resulted in a huge health burden. Such PM2.5-related health burden has long been suspected to differ between China's poverty-stricken areas (PAs) and non-poverty-stricken areas (NPAs). Yet, evidence-based examination of this long-held belief, which is critical as a barrier of environmental injustice to advancing China's sustainability, is still missing. Here our study shows that the PM2.5 pollution is more serious in China's NPAs than PAs-with their annual averages being respectively 54.83 µg/m3 and 43.63 µg/m3-causing higher premature mortality in the NPAs. Compared to economic inequality, China's total PM2.5-related premature mortality was relatively evenly distributed during 2000-2015 across regions of varying levels of gross domestic product (GDP) per capita but increased slightly in 2015-2020 owing to the dramatic change in age structure. The elderly population increased by 31 %. PM2.5-related premature deaths were more severe for populations of low socioeconomic status, and such environmental health inequalities could be amplified by population aging. Additionally, population migration from China's PAs to developed cities contributed to 638, 779, 303, 954, and 896 premature deaths in 2000, 2005, 2010, 2015, and 2020, respectively. Changes in the age structure (53 %) and PM2.5 concentration (28 %) had the greatest impact on premature deaths, followed by changes in population (12 %) and baseline mortality (8 %). The contribution rate of changes in the age structure and PM2.5 concentration was higher in PAs than in NPAs. Our findings provide insight into PM2.5-related premature death and environmental inequality, and may inform more equitable clean air policies to achieve China's sustainable development goals.

Emission of primary microplastics in mainland China: Invisible but not negligible.

Primary microplastics are mostly produced as part of the daily plastic product use. The emission process is often invisible but poses potential ecological hazards. Thus, primary microplastics deserve public attention. Due to China's huge population base and its rapid economic development, primary microplastics emissions are of both regional and global significance. This study is the first to establish the emission inventory of primary microplastics in mainland China. It was estimated that the primary microplastic waste from mainland China amounts to 737.29 Gg, and one-sixth of this amount entered the aquatic environment in 2015. The highest proportion of this waste was attributable to tire dust and synthetic fiber, accounting for 53.91% and 28.77% of the total respectively, in mainland China. The primary microplastics emissions mainly depend on the population, followed by the level of economic development. It was roughly estimated that 538 g of microplastics is produced by each person in China. At the grid scale, the spatial difference in the total primary microplastics emissions in mainland China primarily depends on the population density distribution and transportation network. We studied the entire life cycle of several sources of microplastics, from production to discharge into the aquatic environment. We suggested different control measures under different nodes. Increasing microplastics treatment in sewage treatment plants should be a short-term viable way to achieve some measure of reduction in their entry to the environment in mainland China. Our research can not only raise public awareness about primary microplastics, but can also guide the development of environmental policies to reduce plastic pollution.

Characteristics, sources and health risk assessment of airborne particulate PAHs in Chinese cities: A review.

Polycyclic aromatic hydrocarbons (PAHs) are organic compounds composed of at least two benzene rings. This paper reviews the characteristics, sources and health risk of airborne particulate PAHs in Chinese cities. The airborne particulate PAH concentrations varied from 3.35 to 910 ng m-3, with an average of 75.0 ng m-3, and the pollution level of PAHs in northern cities was generally higher than that in southern cities. The PAH concentrations in different cities underwent similar seasonal variations, with high concentrations in the winter and relatively low concentrations in the summer. Many factors, such as meteorological conditions and source emissions, influenced the spatiotemporal pattern of PAHs. High temperatures, frequent flow exchanges, abundant rainfall and strong solar radiation reduced the level of particulate PAHs in the atmosphere. The historical changes in the level of airborne particulate PAHs in four cities were analyzed. The PAH concentrations in Beijing and Taiyuan presented a trend of first increasing and then decreasing, while the level of particulate PAHs in Nanjing and Guangzhou had a decreasing tendency from year 2000-2015. The airborne particulate PAHs in cities were derived from several sources, including coal combustion, vehicle emissions, coking industries, biomass burning and petroleum volatilization. The results of a health risk assessment indicated that the incremental lifetime cancer risk (ILCR) for people in the northern cities was higher than that for people in the other regions, especially during the cold season. Moreover, adults were at greater risk than people in other age groups, and the health risk to females was slightly higher than that to males. The potential risk of airborne particulate PAH exposure was relatively high in some cities, and controlling PAH emissions at the source should be required to prevent pollution.

Influence of Industrialization and Environmental Protection on Environmental Pollution: A Case Study of Taihu Lake, China.

In order to quantitatively study the effect of environmental protection in China since the twenty-first century and the environmental pollution projected for the next ten years (under the model of extensive economic development), this paper establishes a Bayesian regulation back propagation neural network (BRBPNN) to analyze the typical pollutants (i.e., cadmium (Cd) and benzopyrene (BaP)) for Taihu Lake, a typical Chinese freshwater lake. For the periods 1950⁻2003 and 1950⁻2015, the neural network model estimated the BaP concentration for the database with Nash-Sutcliffe model efficiency (NS) = 0.99 and 0.99 and root-mean-square error (RMSE) = 3.1 and 9.3 for the total database and the Cd concentration for the database with NS = 0.93 and 0.98 and RMSE = 45.4 and 65.7 for the total database, respectively. In the model of extensive economic development, the concentration of pollutants in the sediments of Taihu reached the maximum value at the end of the twentieth century and early twenty-first century, and there was an inflection point. After the early twenty-first century, the concentration of pollutants was controlled under various environmental policies and measures. In 2015, the environmental protection ratio of Cd and BaP reached 52% and 89%, respectively. Without environmental protection measures, the concentrations of Cd and BaP obtained from the neural network model is projected to reach 2015.5 µg kg-1 and 407.8 ng g-1, respectively, in 2030. Based on the results of this study, the Chinese government will need to invest more money and energy to clean up the environment.

Heavy metals in food crops, soil, and water in the Lihe River Watershed of the Taihu Region and their potential health risks when ingested.

Environmental pollution by heavy metals resulting from rapid economic development is a major concern. Soil, water, wheat, and rice samples were collected from the Lihe River Watershed in the Taihu Region (east China). In this study area, many types of industrial plants, including ceramics factories, plants working with refractory materials, and chemical plants are densely distributed and cause serious heavy metal pollution. In addition, well-developed transportation and agricultural activities are also important sources of heavy metals. Thus, the concentrations of selected heavy metals including cadmium (Cd), chromium (Cr), copper (Cu), nickel (Ni), lead (Pb), and zinc (Zn) in the samples were analyzed to evaluate their potential integral risk (IR) to the health of the local population. Accordingly, the spatial distribution pattern of the IR values was determined in the study. The soil in the study area showed heavy Cd pollution, whereas the pollution by other elements was relatively slight. When the proportions of grain samples in which the concentrations exceeded the tolerance limits were examined, the grains were primarily contaminated with Pb, Ni, Cd, and Zn; and less contaminated with Cu and Cr. The drinking water of the local inhabitants was safe. The average IR value was 3.53 for adults and 3.91 for children, indicating that both adults and children may experience adverse health effects. The spatial distribution pattern of the IR values among the exposed populations in the study area showed high values in the eastern and middle parts, with maximum values >5, and low values in the western part, with minimum values <2. This is consistent with the distributions of the industries and the population. The study may provide a basis for comparison to other regions both in China and worldwide.

Distribution, sources, and ecological risk assessment of polycyclic aromatic hydrocarbons in the water and suspended sediments from the middle and lower reaches of the Yangtze River, China.

Samples were collected from the middle and lower reaches of the Yangtze River, China, to study the concentrations, distributions, and compositions of 16 US-EPA priority polycyclic aromatic hydrocarbons (PAHs) in water and suspended particulate matter (SPM). We also evaluated sources of the PAHs and their potential toxicity. Total concentrations of the PAHs (ΣPAHs) in water ranged from 17.33 to 77.12 ng L(-1), and in SPM, the levels ranged from 595.91 to 2473.74 ng g(-1). Total concentrations of seven carcinogenic PAHs (ΣCPAHs) ranged from 7.63 to 13.02 ng L(-1) in water and 276.55 to 1216.89 ng g(-1) in SPM. PAH levels in water samples were relatively low, and those in the lower reaches were higher than in the middle reaches. SPM samples had higher levels of PAHs, especially in the lower reaches and in Dongting Lake and Poyang Lake. Principal component analysis (PCA) with multiple linear regression analysis (MLR) was performed to quantitatively characterize the PAH sources. Two factors and their contributions were identified from water samples. Coal and wood combustion accounted for 74.1 % of the PAHs, and petroleum emissions explained 25.9 % of the PAHs. Three source factors were identified from SPM samples: these were vehicular emissions (46.3 % of PAHs), wood and coal combustion (40.4 % of PAHs), and petrogenic sources (13.3 %). Ecological risk assessment indicated that a moderate undesirable impact will be caused by PAHs, and some control measures and remedial actions should be conducted.

[Source Apportionment and Ecological Risk Assessment of Polycyclic Aromatic Hydrocarbons in Surface Water from Yangtze River, China: Based on PMF Model].

To study the features and ecological risk of PAHs in surface water from Yangtze River, 19 water samples were collected from the main stream and branch of Yangtze River in August 2015. Solid phase extraction method was used to extract PAHs, and the concentrations of the 16 priority PAHs were determined using GC-MS. The results indicated that the concentration of total PAHs (∑PAHs) in the surface water ranged from 17.7-110 ng·L-1 with an average value of 42.6 ng·L-1. The predominant PAHs in the water were PAHs with 2-3 rings, accounting for 67.7% of ∑PAHs. The results of molecular diagnostic ratios indicated that the origin of PAHs was mostly combustion sources, including fossil fuel and biomass combustion. PMF model was used to quantitatively acquire the source contribution of PAHs, which indicated that four sources were identified and their contribution rates were respectively biomass and coal combustion (40.1%), petroleum source (19.6%), traffic source (17.5%) and coke oven source (22.8%). The results of ecological risk assessment indicated that PAHs with 2-3 rings had a relatively high risk level, and Wujiang station and lower reach had a relatively high risk level based on risk quotient. Overall, the ecological risk of PAHs in the Yangtze River was at a relatively low level.