Occurrence of BTX and PAHs in underground drinking water of coking contaminated sites: Linkage with altitude and health risk assessment by boiling-modified models.

The safety of underground drinking water has received widespread attention. However, few studies have focused on the occurrence and health risks of pollutants in underground drinking water of coking contaminated sites. In this study, the distribution characteristics, sources, and human health risks of benzene, toluene, xylene (BTX) and polycyclic aromatic hydrocarbons (PAHs) in underground drinking water from a typical coking contaminated site in Shanxi of China were investigated. The average concentrations of BTX and PAHs in coking plant (CP) were 5.1 and 4.8 times higher than those in residential area (RA), respectively. Toluene and Benzene were the main BTX, while Acenaphthene, Fluorene, and Pyrene were the main PAHs. Concentrations of BTX/PAHs were negatively correlated with altitude, revealing altitude might be an important geological factor influencing spatial distribution of BTX/PAHs. PMF model demonstrated that the BTX/PAHs pollution in RA mainly originated from coking industrial activities. Health risk assessments were conducted by a modified US EPA-based model, in which environmental concentrations were replaced by residual concentrations after boiling. Residual ratios of different BTX/PAHs were determined by boiling experiments to be 9.4-93.8 %. The average total carcinogenic risks after boiling were decreased from 2.6 × 10-6 to 1.4 × 10-6 for adults, and from 4.3 × 10-6 to 2.1 × 10-6 for children, suggesting boiling was an effective strategy to reduce the carcinogenic risks from BTX/PAHs, especially for ingestion pathway. Monte Carlo simulation results matched well with the calculated results, suggesting the uncertainty was acceptable and the risk assessment results were reliable. This study provided useful information for revealing the spatial distribution of BTX/PAHs in underground drinking water of coking contaminated sites, understanding their linkage with altitude, and also helped to more accurately evaluate the health risks by using the newly established boiling-modified models.

Pollution Profiles, Source Identification and Health Risk Assessment of Heavy Metals in Soil near a Non-Ferrous Metal Smelting Plant.

Heavy metal pollution related to non-ferrous metal smelting may pose a significant threat to human health. This study analyzed 58 surface soils collected from a representative non-ferrous metal smelting area to screen potentially hazardous heavy metals and evaluate their health risk in the studied area. The findings demonstrated that human activity had contributed to the pollution degrees of Cu, Cd, As, Zn, and Pb in the surrounding area of a non-ferrous metal smelting plant (NMSP). Cu, Cd, As, Zn, Pb, Ni, and Co pollution within the NMSP was serious. Combining the spatial distribution and Spearman correlations with principal component analysis (PCA), the primary sources of Cd, As, Pb, and Zn in surrounding areas were related to non-ferrous metal smelting and transportation activities. High non-cancer (THI = 4.76) and cancer risks (TCR = 2.99 × 10-4) were found for adults in the NMSP. Moreover, heavy metals in the surrounding areas posed a potential cancer risk to children (TCR = 3.62 × 10-6) and adults (TCR = 1.27 × 10-5). The significant contributions of As, Pb, and Cd to health risks requires special attention. The construction of a heavy metal pollution management system will benefit from the current study for the non-ferrous metal smelting industry.

Spatial distribution, source identification, and human health risk assessment of PAHs and their derivatives in soils nearby the coke plants.

The coking industry can generate large amounts of polycyclic aromatic hydrocarbons (PAHs) and their derivatives, which may negatively impact the environment and human health. In this study, soils nearby a typical coking plant were sampled to assess the impact of coke production on the surrounding residential areas and human health. The mean concentration of PAHs and their derivatives in residential area soils nearby the coke plant was 4270 ng/g dw, which was 1 order of magnitude higher than that observed in areas far from the coke plant and approximately 4 times lower than that revealed the coke plant. In addition, the results showed that coking processing area was the most contaminant area of the coke plant (mean: 74.4 µg/g dw), where was also the main source of pollutants in residential areas. In terms of vertical soils in coking plant, the maximum levels of chemicals (mean: 205 µg/g dw) were presented at the leakage of underground pipelines, where were much higher than those in surface soils, and decreased with the increase of depth. The analysis of variance (ANOVA) results showed obvious differences in the concentrations of 6-nitrochrysene between the plant, residential areas and control areas. Meanwhile, 6-nitrochrysene had potential cancer risk (CR) for human in the coking site. Thus, 6-nitrochrysene was the most noteworthy PAH derivatives. Furthermore, the CR (mean: 5.94 × 10-5) and toxic equivalent quantities (TEQs) (mean: 14.8 µg·TEQ/g) of PAHs and their derivatives was assessed in this study. This finding suggested that PAHs and their derivatives especially those extremely toxic chemicals (Nitro-PAHs (NPAHs) and Br/Cl-PAHs (XPAHs)) might pose a potential health risk to residents nearby the coke plant. The current study provides further insights into the pollution characteristics of PAHs and their derivatives in coke plants and potential risks to the workers and surrounding residents.

Urinary monohydroxylated polycyclic aromatic hydrocarbons in the general population from 26 provincial capital cities in China: Levels, influencing factors, and health risks.

Polycyclic aromatic hydrocarbons (PAHs) derived from the incomplete combustion of organic materials are associated with adverse health effects. However, little is known about PAH exposure levels and their influencing factors on a large scale in developing countries. In this study, urinary monohydroxylated metabolites of PAHs (OH-PAHs), including the metabolites of naphthalene, fluorene, phenanthrene, pyrene, chrysene, and benzo[a]pyrene, were measured in 1154 samples in the general population nationwide from 26 provincial capitals in China. Concentrations of OH-PAHs ranged from 1.39 to 228 µg/L. OH-Nap, metabolite of naphthalene, was the predominant compound, accounting for 65.1% of totals. People in eastern, southwest and northeast China, such as Shanghai, Kunming, Nanning, and Changchun, suffered more PAH exposure than other regions which might associate with sampling time, living habits of the subjects, and the imbalance of economic development and energy consumption across regions. Urinary OH-PAH concentrations were associated with body mass index, gender, and age, and smoking was the main correlating factor. Inhalation and diet might be the main exposure route of human exposure to PAHs, especially for smokers by inhalation. Hazard indices showed that no subject was exposed to PAHs with potential non-carcinogenic risk. Furthermore, the carcinogenic risk was the most significant health effects, with almost all subjects having carcinogenic risk values higher than the acceptable level of 10-6. Naphthalene and phenanthrene were the main contributors. The results also suggested a possible relationship between PAH exposure and lung cancer in the Chinese population. This first nationwide study on human internal exposure to PAHs provides a large body of scientific information for governmental decision-making about associated human health and the prevention of human exposure to PAHs.

Pollution profiles and human health risk assessment of atmospheric organophosphorus esters in an e-waste dismantling park and its surrounding area.

Recycling e-waste has been recognized as an important emission source of organophosphate triesters (tri-OPEs) and organophosphate diesters (di-OPEs), but the presence of di-OPEs in atmosphere has not been studied. Herein, tri-OPEs and di-OPEs in atmosphere of an e-waste dismantling park and surrounding area in South China were monitored for three consecutive years. Thirteen tri-OPEs and seven di-OPEs were identified. In 2017, 2018, and 2019, tri-OPE concentrations in e-waste dismantling park were 1.30 × 108, 4.60 × 106, and 4.01 × 107 pg/m3, while di-OPE concentrations were 1.14 × 103, 1.10 × 103, and 0.35 × 103 pg/m3, respectively, which were much higher than the surrounding area. Tri-OPEs and di-OPEs generated during e-waste dismantling affected surrounding area through diffusion. Triphenyl phosphate (TPhP) and diphenyl phosphate (DPhP) were the predominant congeners of tri-OPEs and di-OPEs, respectively. Additionally, TPhP concentration was extremely higher than other tri-OPEs, so TPhP could be used as an indicator of e-waste dismantling. Spearman correlation analysis showed significant correlations between DPhP and TPhP (R2 = 0.53, p < 0.01), bis-(1-chloro-2-propyl) phosphate (BCIPP) and tris(2-chloropropyl) phosphate (TCIPP) (R2 = 0.49, p < 0.01), as well as dibutyl phosphate (DBP) and tributyl phosphate (TBP) (R2 = 0.53, p < 0.01), indicating that they had the same source. Further, non-carcinogenic risk of them to people via inhalation was acceptable and non-carcinogenic risk of tri-OPEs decreased year by year in surrounding area.

Photocatalytic inactivation and destruction of harmful microalgae Karenia mikimotoi under visible-light irradiation: Insights into physiological response and toxicity assessment.

Harmful algal blooms (HABs) caused by Karenia mikimotoi have frequently happened in coastal waters worldwide, causing serious damages to marine ecosystems and economic losses. Photocatalysis has potential to in-situ inhibit algal growth using sustainable sunlight. However, the inactivation and detoxification mechanisms of microalgae in marine environment have not been systematically investigated. In this work, for the first time, visible-light-driven photocatalytic inactivation of K. mikimotoi was attempted using g-C3N4/TiO2 immobilized films as a model photocatalyst. The inactivation efficiency could reach 64% within 60 min, evaluated by real-time in vivo chlorophyll-a fluorometric method. The immobilized photocatalyst films also exhibited excellent photo-stability and recyclability. Mechanisms study indicated photo-generated h+ and 1O2 were the dominant reactive species. Algal cell rupture process was monitored by fluorescent microscope combined with SEM observation, which confirmed the damage of cell membrane followed by the leakage of the intracellular components including the entire cell nucleus. The physiological responses regarding up-regulation of antioxidant enzyme activity (i.e. CAT and SOD), intracellular ROSs level and lipid peroxidation were all observed. Moreover, the intracellular release profile and acute toxicity assessment indicated the toxic K. mikimotoi was successfully detoxified, and the released organic matter had no cytotoxicity. This work not only provides a potential new strategy for in-situ treatment of K. mikimotoi using sunlight at sea environments, but also creates avenue for understanding the inactivation and destruction mechanisms of marine microalgae treated by photocatalysis and the toxicity impacts on the marine environments.

Photochemical degradation of fragrance ingredient benzyl formate in water: Mechanism and toxicity assessment.

Recently, fragrance ingredients have attracted increasing attention due to their imperceptible risks accompanying the comfortable feeling. To understand transformation mechanisms and toxicity evolution of benzyl formate (BF) in environment, its photochemical degradation in water was thoroughly studied herein. Results showed that 83.5% BF was degraded under ultraviolet (UV) irradiation for 30 min. Laser flash photolysis and quenching experiments demonstrated that triplet excited state (3BF*), O2•-, and 1O2 were three main reactive species found during BF photodegradation. Eight degradation intermediates, including benzaldehyde, benzyl alcohol, o-cresol, bibenzyl, benzyl ether, 1,2-diphenylethanol, benzoic acid, and benzylhemiformal, were mainly formed as identified by LC-Q-TOF/MS and GC-MS analyses. Furthermore, the degradation mechanism was explained as the bond cleavage of 3BF* and BF•+, O2•-/1O2 oxidation, eaq- reduction, and •OH addition reactions. Aquatic assessment suggests that except benzyl alcohol, benzoic acid, and benzylhemiformal, all the products were persistent and could result in increased aquatic toxicity compared to original BF. Consequently, these degradation products may cause more toxicity to organisms if they remain accumulated in water environment for a long time.

A review on in-vitro oral bioaccessibility of organic pollutants and its application in human exposure assessment.

Generally, human oral exposure assessments of contaminants have not considered the absorption factor in the human gastrointestinal tract, thus overestimating human exposure and associated health risk. Currently, more researchers are adding the absorption factor into human exposure assessment, and bioaccessibility measured by in-vitro methods is generally replacing bioavailability for estimation because of the cheap and rapid determination. However, no single unified in-vitro method is used for bioaccessibility measurement of organic pollutants, although several methods have been developed for these pollutants and have shown good in vitro-in vivo correlation between bioaccessibility and bioavailability. The present review has focused on the development of in-vitro methods, validation of these methods through in-vivo assays, determination of factors influencing bioaccessibility, application of bioaccessibility in human exposure assessment, and the challenges faced. Overall, most in-vitro methods were validated using bioavailability, and better in vitro-in vivo correlations were obtained when absorption sinks were added to the digestion solution to mimic dynamic absorption of organic chemicals by small intestine. Incorporating bioaccessibility into the estimation of human exposure by oral ingestion significantly decreases the estimated exposure dose. However, more investigations on bioaccessibility of hydrophobic organic compounds are urgently needed because many challenges for in-vitro methods remain to be overcome.

Spatial and temporal distribution characteristics and ozone formation potentials of volatile organic compounds from three typical functional areas in China.

BACKGROUND: Ozone is currently one of the most important air pollutants. Volatile organic compounds (VOCs) can easily react with atmospheric radicals to form ozone. In-field measurement of VOCs may help in estimating the local VOC photochemical pollution level. METHOD: This study examined the spatial and temporal distribution characteristics of VOCs during winter at three typical sites of varying classification in China; industrial (Guangzhou Economic and Technological Development District (GETDD)), urban (Guangzhou higher education mega center (HEMC)), and rural (Pingyuan county (PYC)), using Proton-Transfer-Reaction Time-of-Flight Mass Spectrometry (PTR-ToF-MS). RESULTS: The concentrations of total VOCs (TVOCs) at the GETDD, HEMC and PYC sites were 352.5, 129.2 and 75.1 ppb, respectively. The dominant category of VOCs is nitrogen-containing VOCs (NVOCs, accounting for 43.3% of TVOCs) at GETDD, of which C4H11N (m/z+ = 74.10, butyl amine) was the predominant chemical species (80.5%). In contrast, oxygenated VOCs (OVOCs) were the most abundant at HEMC and PYC, accounting for 60.2% and 64.1% of the total VOCs, respectively; here, CH4O (m/z+ = 33.026, methanol) was the major compound, accounting for 40.5% of the VOCs at HEMC and 50.9% at PYC. The ratios of toluene to benzene (T/B) were calculated for different measured sites, as the ratios of T/B can reveal source resolution of aromatic VOCs. The average contributions to total ozone formation potentials (OFP) of the total measured VOCs in each area were 604.9, 315.9 and 111.7 µg/m3 at GETDD, HEMC and PYC, respectively; the highest OFP contributors of the identified VOCs were aliphatic hydrocarbons (AlHs) at GETDD, aromatic hydrocarbons (AHs) at HEMC, and OVOCs at PYC. CONCLUSIONS: OFP assessment indicated that the photochemical pollution caused by VOCs at GETDD was serious, and was also significant in the HEMC region. The dominant VOC OFP groups (AlHs and AHs) should be prioritized for control, in order to help reduce these effects.

Pollution evaluation and health risk assessment of airborne toxic metals in both indoors and outdoors of the Pearl River Delta, China.

BACKGROUND: Industries deveploped cities in the Pearl River Delta (PRD) are suffering serious atmospheric metals pollution, in which, people's health risks after inhaling particulate matter (PM) with airborne toxic metals might be rising. This study provides the latest and comprehensive pollution profiles of toxic metals both from indoors and outdoors in PRD. METHOD: Total 22 pairs of indoor and outdoor total suspended particulates (TSP), PM10 and PM2.5 samples in residential area were synchronously sampled and investigated in detail within 9 main cities of the PRD, China. The concentrations of the Zn, Pb, Mn, Ni, As, V, Sb and Cd in the samples were measured by inductively coupled plasma mass spectrometry (ICP-MS). Health risk assessment via inhalation of residents was estimated by EPA recommended model with exposure parameters of Chinese population indoor and outdoor activity pattern. RESULTS: The trends followed as Zn > Pb ≈ Mn > Ni > As > V > Sb ≈ Cd for both indoors and outdoors. Investigated metals were found to be dominantly distributed in PM2.5 for both indoors and outdoors. The concentrations of outdoor PM and the most of metals were significantly higher than those of indoors. The results concluded that toxic metals might be from regional emission, such as Pb from ceramic factory, Ni from motor factory and V from oil combustion of ship. In health risk assessments, LCR is higher than 1.00E-06 for adults, while contrary to children in the PRD. Among four carcinogenic metals, LCR of As and Cd are higher than 1.00E-06 in some cities. In addition, HI below one for both adults and children in the PRD. CONCLUSIONS: Outdoor metals concentrations are related to local industry types, while indoor metals are mainly from outdoor. Health risk assessments indicated that adults suffered unsafe cancer risk from metals, especially As and Cd in some cities, while both adults and children did not suffer non-carcinogenic risks.

The evolution of pollution profile and health risk assessment for three groups SVOCs pollutants along with Beijiang River, China.

Three important groups of semi-volatile organic compounds (SVOCs), polycyclic aromatic hydrocarbons (PAHs), organic chlorinated pesticides (OCPs) and phthalate esters (PAEs), were produced by various human activities and entered the water body. In this study, the pollution profiles of three species including 16 PAHs, 20 OCPs and 15 PAEs in water along the Beijiang River, China were investigated. The concentrations of Σ16PAHs in the dissolved and particulate phases were obtained as 69-1.5 × 102 ng L-1 and 2.3 × 103-8.6 × 104 ng g-1, respectively. The levels of Σ20OCPs were 23-66 ng L-1 (dissolved phase) and 19-1.7 × 103 ng g-1 (particulate phase). Nevertheless, higher levels of PAEs were found both in the dissolved and particulate phases due to abuse use of plastic products. Furthermore, non-cancer and cancer risks caused by these SVOCs through the ingestion absorption and dermal absorption were also assessed. There was no non-cancer risk existed through two kinds of exposure of them at current levels, whereas certain cancer risk existed through dermal absorption of PAHs in the particulate phase in some sampling sites. The results will show scientific insights into the evaluation of the status of combined pollution in river basins, and the determination of strategies for incident control and pollutant remediation.

Emission patterns and risk assessment of polybrominated diphenyl ethers and bromophenols in water and sediments from the Beijiang River, South China.

To reveal the emission patterns of brominated flame retardants (BFRs) in the Beijiang River, South China, concentrations of polybrominated diphenyl ethers (PBDEs) and phenolic BFRs (2,4,6-tribromophenol (TBP), pentabromophenol (PeBP), tetrabromobisphenol A (TBBPA)), and bisphenol A (BPA) in water and sediments were simultaneously measured, and the geographic information system (GIS) were applied to analyse their emission patterns. Results showed that PBDEs, TBP, PeBP, TBBPA and BPA were ubiquitous in the water and sediment samples collected from the Beijiang River. However, most of the concentrations were very low or below the detection limits (DL). In water, Σ20PBDEs (sum of all 20 PBDEs congeners) levels ranged from < DL to 232 pg L-1, with the predominant congeners containing low bromine contents. The levels of TBP, PeBP, TBBPA and BPA in water were lower than 810 pg L-1. In sediments, Σ20PBDEs varied from 260 to 5640 pg g-1 dry weight (d.w.), with the predominant congeners containing high bromine contents. The levels of TBP, PeBP, TBBPA and BPA were lower than 600 pg g-1 d.w.. Risk assessments indicated that the water and sediments at the sampling locations imposed no estrogenic risk (E2EQ < 1.0 ng E2 L-1), and the eco-toxicity assessment at three trophic levels also showed no risk at all sampling sites in water (RQTotal < 1.0), but with a potential eco-toxicity at some sampling points in sediments (1.0

Pollution characteristics and health risk assessment of volatile organic compounds emitted from different plastic solid waste recycling workshops.

The pollution profiles of volatile organic compounds (VOCs) emitted from different recycling workshops processing different types of plastic solid waste (PSW) and their health risks were investigated. A total of 64 VOCs including alkanes, alkenes, monoaromatics, oxygenated VOCs (OVOCs), chlorinated VOCs (ClVOCs) and acrylonitrile during the melting extrusion procedure were identified and quantified. The highest concentration of total VOCs (TVOC) occurred in the poly(acrylonitrile-butadiene styrene) (ABS) recycling workshop, followed by the polystyrene (PS), polypropylene (PP), polyamide (PA), polyvinyl chloride (PVC), polyethylene (PE) and polycarbonate (PC) workshops. Monoaromatics were found as the major component emitted from the ABS and PS recycling workshops, while alkanes were mainly emitted from the PE and PP recycling processes, and OVOCs from the PVC and PA recycling workshops. According to the occupational exposure limits' (OEL) assessment, the workers suffered acute and chronic health risks in the ABS and PS recycling workshops. Meanwhile, it was found that most VOCs in the indoor microenvironments were originated from the melting extrusion process, while the highest TVOC concentration was observed in the PS rather than in the ABS recycling workshop. Non-cancer hazard indices (HIs) of all individual VOCs were <1.0, whereas the total HI in the PS recycling workshop was 1.9, posing an adverse chronic health threat. Lifetime cancer risk assessment suggested that the residents also suffered from definite cancer risk in the PS, PA, ABS and PVC recycling workshops.

Pollution profiles and risk assessment of PBDEs and phenolic brominated flame retardants in water environments within a typical electronic waste dismantling region.

The aim of this study was to assess the pollution profiles of various typical brominated flame retardants in water and surface sediment near a typical electronic waste dismantling region in southern China. We found that polybrominated diphenyl ethers (PBDEs), 2,4,6-tribromophenol (TBP), pentabromophenol (PeBP), tetrabromobisphenol A (TBBPA), and bisphenol A (BPA) were ubiquitous in the water and sediment samples collected in the study region. In water, Σ19PBDEs (sum of all 20 PBDE congeners studied except BDE-209, which was below the detection limit) levels ranged from 0.31 to 8.9 × 10(2) ng L(-1). TBP, PeBP, TBBPA, and BPA concentrations in the water samples ranged from not being detectable (nd-under the detection limit) to 3.2 × 10(2) (TBP), from nd to 37 (PeBP), from nd to 9.2 × 10(2) (TBBPA) and from nd-8.6 × 10(2) ng L(-1) (BPA). In sediment, Σ19PBDEs ranged from nd to 5.6 × 10(3) ng g(-1), while BDE-209 was the predominant congener, with a range of nd to 3.5 × 10(3) ng g(-1). Tri- to hepta-BDE concentrations were significantly (p < 0.01) correlated with each other, except for BDE-71 and BDE-183, and octa- to nona-BDEs concentrations were significantly (p < 0.05) correlated with each other, except for BDE-208. BDE-209 was not significantly correlated with tri- to nona-BDEs. Risk assessments indicated that the water and sediment across the sampling sites posed no estrogenic risk. However, different eco-toxicity risk degrees at three trophic levels did exist at most sampling sites.

Pollution profiles and health risk assessment of VOCs emitted during e-waste dismantling processes associated with different dismantling methods.

Pollution profiles of typical volatile organic compounds (VOCs) emitted during dismantling of various printed circuit board assemblies (PCBAs) of e-wastes using different methods were comparatively investigated in the real e-waste dismantling workshops in South China in April 2013. Similar pollution profiles and concentrations of VOCs were observed between dismantling mobile phone and hard disk PCBAs by using electric blowers and between dismantling television and power supplier PCBAs using electric heating furnaces. Aromatic hydrocarbons (accounting for >60% of the sum of VOCs) were the dominant group during using electric blowers, while aromatic (accounting for >44% of the sum of VOCs) and halogenated hydrocarbons (accounting for >48% of the sum of VOCs) were the two dominant groups which contributed equally using electric heating furnaces. However, the distribution profiles of VOCs emitted during dismantling of televisions, hard disks and micro motors using rotary incinerators varied greatly, though aromatic hydrocarbons were still the dominant group. The combustion of e-wastes led to the most severe contamination of VOCs, with total VOCs (3.3×10(4) µg m(-3)) using rotary incinerators about 190, 180, 139, and 40 times higher than those using mechanical cutting, electric soldering iron, electric blower, and electric heating furnace, respectively. Both cancer and non-cancer risks existed for workers due to exposure to on-site emitted VOCs in all workshops especially in those using rotary incinerators according to the USEPA methodology, whereas only cancer risks existed in rotary incinerator workshops according to the American Conference of Industrial Hygienists methodology.

Experimental and theoretical insights into photochemical transformation kinetics and mechanisms of aqueous propylparaben and risk assessment of its degradation products.

The kinetics and mechanisms of ultraviolet photochemical transformation of propylparaben (PPB) were studied. Specific kinetics scavenging experiments coupled with quantum yield determinations were used to distinguish the roles of various reactive species induced by self-sensitized and direct photolysis reactions, and the excited triplet state of PPB ((3) PPB*) was identified as the most important species to initiate the photochemical degradation of PPB in aquatic environments. The computational results of time-resolved absorption spectra proved that (3) PPB* is a highly reactive electron acceptor, and a head-to-tail hydrogen transfer mechanism probably occurs through electron coupled with proton transfer. Physical quenching by, or chemical reaction of (3) PPB* with, O2 was confirmed as a key step affecting the initial PPB transformation pathways and degradation mechanisms. The transformation products were identified and the toxicity evolutions of PPB solutions during photochemical degradation under aerobic and anaerobic conditions were compared. The results indicate that anaerobic conditions are more likely than aerobic conditions to lead to the elimination and detoxification of PPB but less likely to lead to PPB mineralization.

Distribution, possible sources, and health risk assessment of SVOC pollution in small streams in Pearl River Delta, China.

The pollution levels of typical semivolatile organic compounds (SVOCs) consisting of 15 polycyclic aromatic hydrocarbons (PAHs), 20 organic chlorinated pesticides (OCPs), and 15 phthalate esters (PAEs) were investigated in small rivers running through the flourishing cities in Pearl River Delta region, China. The concentrations of ∑15PAHs were 2.0-48 ng/L and 29-1.2 × 10(3) ng/g in the water and sediment samples, respectively. The ∑20OCPs were 6.6-57 ng/L and 9.3-6.0 × 10(2) ng/g in the water and sediment samples, respectively. The concentrations of ∑15PAEs were much higher both in the water and sediments. The partition process of the detected SVOCs between the water and sediment did not reach the equilibrium state at most of the sites when sampling. The combustion of petroleum products and coal was the major source of the detected PAHs. The OCPs were mainly historical residue, whereas the new inputs of dichlorodiphenyltrichloroethane (DDT), chlordane, and endosulfan were possible at several sites. The industrial and domestic sewage were the major source for the PAEs; storm water runoff accelerated the input of PAEs. No chronic risk of the SVOCs was identified by a health risk assessment through daily water consumption, except for the ∑20OCPs that might cause cancer at several sites. Nevertheless, the integrated health risk of the SVOCs should not be neglected and need intensive investigations.

Mechanism, kinetics and toxicity assessment of OH-initiated transformation of triclosan in aquatic environments.

The mechanisms and kinetics of OH-initiated transformation of triclosan (TCS) in aquatic environments were modeled using high-accuracy molecular orbital theory. TCS can be initially attacked by OH in two ways, OH-addition and H-abstraction. Twelve OH-addition routes were reported, and the C atom adjacent to the ether bond in the benzene ring (RaddB1) was found as the most easily attacked position by OH, producing TCS-OHB1. Seven H-abstraction routes were reported, and the OH exclusively abstracted the phenolic hydroxyl (RabsOH) H atom, to form TCS(-H). The kinetics results showed that the RaddB1 and RabsOH routes would occur preferentially in aquatic environments, and the half-life depended on the OH concentration ([OH]). At low [OH], the main intermediates, TCS-OHB1 and TCS(-H), can be converted into 2,4-dichlorophenol and polychlorinated dibenzo-p-dioxins, respectively. However, when enough OH is present, such as in advanced oxidation process (AOP) systems, they would be fully decomposed. The acute and chronic toxicities of TCS and its products were assessed at three trophic levels using the "ecological structure-activity relationships" program. The toxicity of the products decreased through the RaddB1 route, while the toxicity of the products first increased and then decreased through the other degradation routes. These results should help reveal the mechanism of TCS transformation as well as risk assessment in aquatic environments, and will help design further experimental studies and industrial application of AOPs.

Advanced oxidation kinetics and mechanism of preservative propylparaben degradation in aqueous suspension of TiO2 and risk assessment of its degradation products.

The absolute kinetic rate constants of propylparaben (PPB) in water with different free radicals were investigated, and it was found that both hydroxyl radicals (HO(•)) and hydrated electrons could rapidly react with PPB. The advanced oxidation kinetics and mechanisms of PPB were investigated using photocatalytic process as a model technology, and the degradation was found to be a pseudo-first-order model. Oxidative species, particularly HO(•), were the most important reactive oxygen species mediating photocatalytic degradation of PPB, and PPB degradation was found to be significantly affected by pH because it was controlled by the radical reaction mechanism and was postulated to occur primarily via HO(•)-addition or H-abstraction reactions on the basis of pulse radiolysis measurements and observed reaction products. To investigate potential risk of PPB to humans and aqueous organisms, the estrogenic assays and bioassays were performed using 100 µM PPB solution degraded by photocatalysis at specific intervals. The estrogenic activity decreased as PPB was degraded, while the acute toxicity at three trophic levels first increased slowly and then decreased rapidly as the total organic carbon decreased during photocatalytic degradation.

On-site and off-site atmospheric PBDEs in an electronic dismantling workshop in south China: gas-particle partitioning and human exposure assessment.

Gas samples and total suspended particle during work and off work time were investigated on-site and off-site electronic waste dismantling workshop (I- and O-EWDW), then compared with plastic recycling workshop (PRW) and waste incineration plant (WIP). TSP concentrations and total PBDE were 0.36-2.21 mg/m(3) and 27-2975 ng/m(3) at different workshops, respectively. BDE-47, -99, and -209 were major ∑PBDE congeners at I-EWDW and WIP, while BDE-209 was only dominant congener in PRW and control sites during work time and all sites during off work time. The gas-particle partitioning result was well correlated with the subcooled liquid vapor pressure for all samples, except for WIP and I-EDWD, at park during work time, and residential area during off work time. The predicted urban curve fitted well with measured φ values at O-DEWD during work time, whereas it was slightly overestimated or underestimated for others. Exposure assessment revealed the highest exposure site was I-EDWD.