Screening of antimicrobials, fragrances, UV stabilizers, plasticizers and preservatives in sewage treatment plants (STPs) and their risk assessment in India.

Community/industrial wastewater is the prime source of anthropogenic chemicals, its treatment is often a daunting task and unaffordable for many countries. Emerging Contaminants (ECs) have been drained into wastewater after continuous use/misuse and Conventional treatments in STPs do not remove them completely. ECs including antimicrobial agents, synthetic musks, Benzotriazole UV stabilizers (BUVSs), plasticizers, and preservatives are frequently reported in environment, and cause health effects to non-target organisms. Monitoring of ECs is important to understand their status in aquatic environment. Hence, it was aimed to monitor ECs (n = 21) from 11 STPs in Tamil Nadu, India. The detection frequency of most of these analytes was >90%. Antimicrobials ranged from 247 to 22,714 ng/L and 11-14,369 ng/L in influents and effluents, respectively. The synthetic musks were in the order of Tonalide > Galaxolide > Musk Ketone. BUVSs ranged from 4 to 1632 ng/L (influents) and < LOD to 29,853 ng/L (effluents). Concentration of phthalates in influents and effluents were < LOD - 11,311 ng/L and < LOD - 17,618 ng/L, respectively. Parabens were found in the order of Prophyl > Methyl > Ethyl > Butyl in influents and Methyl > Prophyl > Butyl > Ethyl in effluents. Mass loads of ECs through STPs were found as antimicrobials > plasticizers > fragrances > BUVSs > Preservatives. This study reveals increasing usage of ECs and inadequate treatment processes at STPs in India. Also helps to adopt suitable treatment processes to remove ECs from wastewater and to reuse the wastewater.

Aquatic and human health risk assessment of Humanogenic Emerging Contaminants (HECs), Phthalate Esters from the Indian Rivers.

Phthalate esters (PEs) one of the widely used plasticizers, and are known for their environmental contamination and endocrine disruption. Hence, it is important to study their distribution in a riverine environment. This study was aimed to determine the Spatio-temporal trends of 16 PEs in surface water, sediment and fish from rivers in southern India, and to assess their environmental health risks. Phthalates were quantified in all matrices with the mean concentrations (∑16PEs) in water, sediment and fish as 35.6 µg/L, 1.25 µg/kg and 17.0 µg/kg, respectively. The Kaveri River is highly loaded with PEs compared to the Thamiraparani and Vellar Rivers. PEs such as DBP, DEHP, DCHP and DiBP were most frequently detected in all matrices, and at elevated concentrations in the dry season. The risk quotient (RQ < 1) suggests that the health risk of PEs from river water and fish to humans is negligible. However, DBP and DEHP from the Kaveri River pose some risk to aquatic organisms (HQ > 1). DEHP from the Vellar River may pose risks to algae and crustaceans. Non-priority phthalate (DiBP) may pose risks to Kaveri and Vellar River fish. The bioaccumulation factor of DCHP and DEHP was found to be very high in Sardinella longiceps and in Centropristis striata, and also exceeded the threshold limit of 5000 suggesting that PEs in the riverine environment may pose some health concerns. This is the first study to assess the spatio-temporal distribution, riverine flux and potential ecological effects of 16 PEs from the southern Indian Rivers.

Performance assessment of a single-layer moisture store-and-release cover system at a mine waste rock pile in a seasonally humid region (Nova Scotia, Canada).

Cover systems are commonly applied to mine waste rock piles (WRPs) to control acid mine drainage (AMD). Single-layer covers utilize the moisture "store-and-release" concept to first store and then release moisture back to the atmosphere via evapotranspiration. Although more commonly used in semi-arid and arid climates, store-and-release covers remain an attractive option in humid climates due to the low cost and relative simplicity of installation. However, knowledge of their performance in these climates is limited. The objective of this study was to assess the performance of moisture store-and-release covers at full-scale WRPs located in humid climates. This cover type was installed at a WRP in Nova Scotia, Canada, alongside state-of-the-art monitoring instrumentation. Field monitoring was conducted over 5 years to assess key components such as meteorological conditions, cover material water dynamics, net percolation, surface runoff, pore-gas, environmental receptor water quality, landform stability and vegetation. Water balances indicate small reductions in water influx to the waste rock (i.e., 34 to 28% of precipitation) with the diminished AMD release also apparent by small improvements in groundwater quality (increase in pH, decrease in sulfate/metals). Surface water quality analysis and field observations of vegetative/aquatic life demonstrate significant improvements in the surface water receptor. The WRP landform is stable and the vegetative cover is thriving. This study has shown that while a simple store-and-release cover may not be a highly effective barrier to water infiltration in humid climates, it can be used to (i) eliminate contaminated surface water runoff, (ii) minimize AMD impacts to surface water receptor(s), (iii) maintain a stable landform, and (iv) provide a sustainable vegetative canopy.