Occurrence, fate and risk assessment of per- and polyfluoroalkyl substances in wastewater treatment plants in Shaanxi, China.

Wastewater treatment plants (WWTPs) are considered as major sinks for per- and polyfluoroalkyl substances (PFASs). However, conventional WWTPs with low efficiency are also a secondary point source of PFASs entering the environment. Herein, a large-scale investigation of PFASs was conducted in 44 WWTPs throughout Shaanxi Province in the transitional zone between North and South China. The composition profiles of target PFASs differed between wastewater and sludge samples. Perfluorobutanoic acid was dominant in wastewater influent and effluent samples, with maximum concentrations of 59.8 and 11.4 ng/L, respectively. Perfluorooctane sulfonic acid occurred predominantly in sludge samples, with a maximum concentration of 73.2 ng/g. Through wastewater treatment, short-chain PFASs with an even number of carbon atoms were mostly removed, whereas short-chain PFASs with an odd number of carbon atoms were primarily discharged into receiving water. Long-chain PFASs (perfluoroalkyl carboxylic acids: C ≥ 8; perfluoroalkane sulfonic acids: C ≥ 6) were not removed efficiently and secondary production might occur during treatment. Based on the risk quotient, PFASs residues in wastewater effluent posed minimal ecological risk, but the residues in sludge posed low to high potential risk. The mass loadings of PFASs discharged through wastewater and sludge were 15.5 and 3.74 kg/year, respectively, from all WWTPs in Shaanxi Province.

Spatial distribution and risk assessment of certain antibiotics in 51 urban wastewater treatment plants in the transition zone between North and South China.

The release of antibiotics from WWTPs into the environment has raised increasing concern worldwide. The monitoring of antibiotics in WWTPs throughout a region is crucial for emerging pollutant management. A large-scale survey of the occurrence, distribution, and ecological risk of seven antibiotics in 51 WWTPs was conducted in Shaanxi Province, China. Norfloxacin and ofloxacin had the highest detection concentrations of 474.2 and 656.18 ng L-1, respectively. Antibiotic residues in effluents were decreased by 5.88-94.16 % after different treatment processes. In particular, A2O or mixed processes performed well in removing target antibiotic compounds simultaneously. The ecological risk posed by antibiotic compounds detected in effluents was calculated using the risk quotient (RQ). Norfloxacin, ofloxacin, tetracycline, and roxithromycin posed different levels of potential ecotoxicological risk (RQ = 0.02-7.59). Based on the sum of the RQ values of individual antibiotic compounds, each investigated WWTP showed potential ecological risk. WWTPs with high risk levels were mainly found in the central region, while those in the southern region exhibited low risk levels, and those in the northern region showed risk levels between medium and high. This comprehensive investigation provides promising results to support the safe use and control of antibiotics in the study area.

Microplastics in 48 wastewater treatment plants reveal regional differences in physical characteristics and shape-dependent removal in the transition zone between North and South China.

This study investigated the physical characteristics and removal efficiency of microplastics in wastewater from regions with different climatic conditions and economic development levels. Microplastics with different shapes and sizes were analyzed from the influent and effluent of 48 wastewater treatment plants in three regions of Shaanxi Province (China). Results indicated that the abundance of microplastics in the influent samples was higher in the region with less regional water resources. However, the per capita microplastics emissions was higher in the region with higher economic development level. There were less fibers and more foams and beads in the more developed region. The removal efficiency of microplastics was related to their shape and size. Particularly, the removal efficiency showed a significant negative correlation with the percentage of foams, while it had a significant positive relationship with the proportions of films and fibers. The highest removal efficiency was obtained when the size of microplastics was ranged from 0.5 to 1.0 mm. This study suggests, compared to improving the removal efficiency of microplastics, that reducing the input at source is a more scientific and promising method.