Assessment of Properties and Microstructure of Concrete with Cotton Textile Waste and Crushed Bricks.

Cotton textile waste (CW) and crushed bricks (CB) are wastes generated by the textile and construction industries that cause adverse effects on the environment. This paper explores the effect of adding 1, 2, 5, and 10 wt.% of CW and CB, instead of natural sand under 1 mm (50 to 100 vol.%), on the properties of concrete. The study included the analysis of workability, density, water absorption, thermal conductivity, mechanical strengths, and electron microscopy. The results show that the presence of CW and CB increased the water required to obtain the same slump value as reference, R. Concretes with CW provided better performance in terms of density, water absorption (for 1 wt.%), and splitting strength (for 1 to 2 wt.%). The 28 days of compressive strength decreased with increasing CW (33.3 MPa for R and 26.9 MPa for 2 wt.% of CW). The partial substitution of sand decreased the workability and density and increased the mechanical strength of concrete. The presence of both CW and CB decreased workability, density, and mechanical strengths. Regarding the ability of concrete to transfer heat, the addition of CW and CB decreased the thermal conductivity value (e.g., 0.32 W/(m·K) for 1 wt.% of CW compared to 0.37 W/(m·K) for reference).

Innovative Low-Cost Composite Nanoadsorbents Based on Eggshell Waste for Nickel Removal from Aqueous Media.

In a contemporary sustainable economy, innovation is a prerequisite to recycling waste into new efficient materials designed to minimize pollution and conserve non-renewable natural resources. Using an innovative approach to remediating metal-polluted water, in this study, eggshell waste was used to prepare two new low-cost nanoadsorbents for the retrieval of nickel from aqueous solutions. Scanning electron microscopy (SEM) results show that in the first eggshell-zeolite (EZ) adsorbent, the zeolite nanoparticles were loaded in the eggshell pores. The preparation for the second (iron(III) oxide-hydroxide)-eggshell-zeolite (FEZ) nanoadsorbent led to double functionalization of the eggshell base with the zeolite nanoparticles, upon simultaneous loading of the pores of the eggshell and zeolite surface with FeOOH particles. Structural modification of the eggshell led to a significant increase in the specific surface, as confirmed using BET analysis. These features enabled the composite EZ and FEZ to remove nickel from aqueous solutions with high performance and adsorption capacities of 321.1 mg/g and 287.9 mg/g, respectively. The results indicate that nickel adsorption on EZ and FEZ is a multimolecular layer, spontaneous, and endothermic process. Concomitantly, the desorption results reflect the high reusability of these two nanomaterials, collectively suggesting the use of waste in the design of new, low-cost, and highly efficient composite nanoadsorbents for environmental bioremediation.

Fly-Ash Evaluation as Potential EOL Material Replacement of Cement in Pastes: Morpho-Structural and Physico-Chemical Properties Assessment.

The main objective of the study was to produce alternative binder materials, obtained with low cost, low energy consumption, and low CO2 production, by regenerating end-of-life (EOL) materials from mineral deposits, to replace ordinary Portland cement (OPC). The materials analyzed were ash and slag from the Turceni thermal power plant deposit, Romania. These were initially examined for morphology, mineralogical composition, elemental composition, degree of crystallinity, and heating behavior, to determine their ability to be used as a potential source of supplementary cementitious materials (SCM) and to establish the activation and transformation temperature in the SCM. The in-situ pozzolanic behavior of commercial cement, as well as cement mixtures with different percentages of ash addition, were further observed. The mechanical resistance, water absorption, sorptivity capacity, resistance to alkali reactions (ASR), corrosion resistance, and resistance to reaction with sulfates were evaluated in this study using low-vacuum scanning electron microscopy.