Ecological Risk Assessment of Organochlorine Pesticides and Polychlorinated Biphenyls in Coastal Sediments in China.

Although the ecological risk of emerging contaminants is currently a research hotspot in China and abroad, few studies have investigated the ecological risk of pesticide pollutants in Chinese coastal sediments. In this study, nine pesticide pollutants included in the "List of New Key Pollutants for Control (2023 Edition)" issued by the Chinese government were used as the research objects, and the environmental exposure of pesticide pollutants in China's coastal sediments was analyzed. The baseline sediment quality criteria were deduced using the balanced distribution method, and a multi-level ecological risk assessment of pesticides in sediment was performed. The results showed that the nine pesticide pollutants were widespread in Chinese coastal sediments, with concentrations ranging from 0.01 ng·g-1 to 330 ng·g-1. The risk quotient assessment showed that endosulfan and DDT posed medium environmental risks to the Chinese coastal sediment environment, and PCBs posed medium risks in some bays of the East China Sea. The semi-probabilistic, optimized semi-probability evaluation and joint probability curve (JPC) assessments all show that endosulfan and DDT pose a certain degree of risk to the environment.

Research on freshwater water quality criteria, sediment quality criteria and ecological risk assessment of triclosan in China.

Triclosan (TCS) is a broad-spectrum antimicrobial agent commonly used in pharmaceuticals and personal care products (PPCPs). The widespread use of TCS makes it frequently detected in various environmental mediums. In view of the high detection frequency of TCS in the aquatic environment and sediments, and its toxic effects on aquatic species, it is critical and necessary to derive Chinese TCS water quality criteria (WQC) and sediment quality criteria (SQC) for protecting Chinese aquatic organisms, and perform the ecological risk assessment. In fact, former research had derived the WQC of TCS mainly based on acute and chronic toxicity data. As an endocrine disrupting chemical (EDC), TCS poses adverse effects on the growth, development and reproduction of aquatic organisms at much lower concentration. Considering nonlethal endpoints are sensitive endpoints for EDCs, TCS long-term water quality criteria (LWQC) was derived based on reproduction and growth related endpoints. In this work, the acute toxicity data of 19 aquatic organisms and the chronic toxicity data of 15 aquatic organisms were obtained through collection and screening. The best fitting model of species sensitivity distribution (SSD) models including Normal, Log-Normal, Logistic and Log-Logistic of toxicity data was selected to derive WQC. The short-term and long-term WQC of TCS for Chinese aquatic organisms were 6.22 µg/L and 0.25 µg/L, respectively. Furthermore, through the phase-equilibrium partitioning method, SQC was derived based on WQC. SQC-low (SQC-L) and SQC-high (SQCH) were 0.13 mg/kg and 3.26 mg/kg, respectively. Moreover, the exposure concentration (EPC) data of TCS in Chinese rivers and sediments were collected. And through the hazard quotient (HQ) method and the joint probability curve (JPC) method we found that there were certain TCS ecological risks in Chinese rivers and sediments. Our work will provide a valuable reference for protecting aquatic organisms and minimizing TCS ecological risk in China.

Derivation of aquatic life criteria for four phthalate esters and their ecological risk assessment in Liao River.

As a critical family of endocrine disruptors, phthalate esters (PAEs) attracted considerable attentions due to increasingly detected worldwide. Aquatic life criteria (ALC) for PAEs are crucial for their accurate ecological risk assessment (ERA) and have seldom been derived before. Given this concern, the purpose of the present study is to optimize the ALCs of four priority PAEs to estimate their ecological risks in Liao River. Reproductive endpoint was found to be more sensitive than other endpoints. Thus, reproduction related toxicity data were screened to derive ALCs applying species sensitivity distribution (SSD) method. ALCs of DEHP, DBP, BBP and DEP were calculated to be 0.04, 0.62, 4.71 and 41.9 µg L-1, which indicated decreased toxicity in sequence. Then, the derived ALCs of the four PAEs were applied to estimate their ecological risks in Liao River. A total of 27 sampling sites were selected to detect and analyze the exposure concentrations of PAEs. ERA using the hazard quotient (HQ) method was conducted. The results demonstrated that DEHP exhibited higher risks at 92.6% of sampling sites, and risks posed by DBP were moderate at 63.0% sampling sites. However, risks posed by BBP were low at 70.4% of sampling sites, and there were no risks posed by DEP at 96.3% of sampling sites. The results of probabilistic ecological risk assessment (PERA) indicated that probabilities of exceeding effects thresholds on 5% of species were 60.41%, 0%, 0.12%, 14.28% for DEHP, DEP, BBP and DBP, respectively. The work provides useful information to protect aquatic species in Liao River.

Progress of environmental management and risk assessment of industrial chemicals in China.

With China's rapid economic growth, chemical-related environmental issues have become increasingly prominent, and the environmental management of chemicals has garnered increased attention from the government. This review focuses on the current situation and the application of risk assessment in China's environmental management of industrial chemicals. The related challenges and research needs of the country are also discussed. The Chinese government promulgated regulations for the import and export of toxic chemicals in 1994. Regulations for new chemical substances came into force in 2003, and were revised in 2010 based on the concept of risk management. In order to support the implementation of new regulations, Guidance for Risk Assessment of Chemicals is under development in an attempt to provide the concepts and techniques of risk assessment. With increasing concern and financial support from Chinese government, China is embarking on the fast track of research and development in environmental management of industrial chemicals.