Benzoquinone-Pyrrole Polymers as Cost-Effective Cathodes toward Practical Organic Batteries.

Organic cathode materials (OCMs) for rechargeable Li and Na batteries show great advantages in resource sustainability and huge potential in electrochemical performance but suffer from dissolution problems and costly synthesis. Herein, for the first time, we investigated the copolymer of benzoquinone (BQ) and pyrrole (Py), namely, poly(benzoquinone-pyrrole) (PBQPy), as an OCM for Li batteries. The low-cost raw materials and solvent-free synthesis provide PBQPy much brighter prospects in large-scale production compared to other carbonyl-based polymer cathode materials. Nevertheless, PBQPy showed one of the best electrochemical performances among all OCMs, including excellent energy density (2.32 V × 255 mAh g-1 = 592 Wh kg-1), rate capability (79%@2000 mA g-1), and cycling stability (81%@1000th cycle). By introducing poly(benzoquinone-methyl pyrrole) for comparison, as well as employing density functional theory calculations and various characterizations for in-depth understanding, the synthesis mechanism, polymer structure, electrochemical behavior, and redox mechanism were clearly clarified. It is believed that this work will encourage more efforts to develop cost-effective OCMs toward practical organic batteries.

Wood-Inspired Compressible Superhydrophilic Sponge for Efficient Removal of Micron-Sized Water Droplets from Viscous Oils.

Efficient micron-sized droplet separation materials have become a new demand for environmental protection and economic development. However, existing separation methods are difficult to be effectively used for micron-sized water droplets surrounded by viscous oil, and common materials have difficulty maintaining hydrophilicity underoil. Here, inspired by the microstructure of tree xylem, we report a cellulose-polyurethane sponge (CP-Sponge) with wood-like pores and underoil superhydrophilicity using directional freeze-casting. The CP-Sponge has an excellent selective water absorption capacity underoil and compression resilience. This preparation strategy can flexibly control the sponge's dimensional morphology. The designed cylindrical CP-Sponge can be easily installed in the silicone tube of a peristaltic pump. During pump operation, with a simple absorption, compression, and recovery process, the CP-Sponge continuously and effectively removes micron-sized water from crude oil and lubricating oil, reducing residual water in the oil to less than 2 ppm. The absorption-saturated sponge can be dried to continue recycling. Eco-friendly, recyclable, and sustainable artificial porous sponges provide new ideas and inspiration for the practical application of deep dehydration of viscous oils.