Soil pollution indices and health risk assessment of metal(loid)s in the agricultural soil of pistachio orchards.

Elevated levels of metal(loid)s in soil may pose potential threats to the ecosystem and can be harmful for human health. The concentrations of As, Cd, Pb, Cr and Ni were determined in agricultural soil collected from 45 pistachio orchards around Feizabad city, Khorasan Razavi province, Iran using ICP-OES. Also, soil pollution indices including contamination factor (CF), pollution load index (PLI) and geo-accumulation index (Igeo) were evaluated. In addition, non-carcinogenic and carcinogenic risk indices were estimated. The mean concentrations of metal(loid)s were in the order of Ni = 466.256 > Cr = 120.848 > Pb = 12.009 > As = 5.486 > Cd = 0.394 mg/kg. Concentrations of As, Cd and Pb in the soil samples were within their respective permissible limits set by World Health Organization (WHO). But concentrations of Cr and Ni in 84.4 and 100% of the samples, respectively exceeded the WHO allowable limits. The CF, PLI and Igeo showed that soil of some of the pistachio orchards was contaminated with some metals. The possible sources of the metals in the soil are application of pesticides, chemical fertilizers, manures as well as irrigation water. Hazard quotient (HQ) ad Hazard index (HI) values from soil of all the orchards were found to be well below the respective threshold limit (1), suggesting that there is no immediate non-cancer threat arising from the contamination at all the orchards with metal(loid)s for children and adults. The highest cancer risk values (1.13E-02 for children and 1.25E-03 for adults) were estimated for Ni in the soil. Collectively, this study provides valuable information to improve the soil in the pistachio orchards to reduce metal(loid)s contamination and minimize the associated health risks to the population in the area.

Analysis of trace elements in processed products of grapes and potential health risk assessment.

Raisins and grape pekmez are consumed commonly by human all over the globe. Consumption of contaminated foods may be the likely pathway of heavy metal exposure. Therefore, the objectives of the present research were to quantify trace elements concentration in raisins and grape pekmez produced from locally grown grapes in Gonabad and to assess non-carcinogenic (HQ and HI) and carcinogenic (total cancer risk, CRt) health risks caused by trace elements exposure via oral intake of these products for children, teenagers, and adults. For this purpose, a totally 30 (15 raisins and 15 grape pekmez) samples were purchased from the vineyard gardeners and examined for ten trace elements including As, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, and Zn. The HI values signaled that the studied population consuming these products is at risk. The HQ, HI, and CRt values of the elements were in order of children > teenagers > adults. The highest cancer risk contribution was attributed to As and Ni for all the studied age groups in both raisins and grape pekmez samples. However, it is recommended that the concentration of trace elements in the soil and crops of the study area and its related health risks be regularly monitored to avoid significant health risks in the future.

Ecological risk assessment of trace elements (TEs) pollution and human health risk exposure in agricultural soils used for saffron cultivation.

Contamination of farmland soils by trace elements (TEs) has become an international issue concerning food safety and human health risks. In the present research, the concentrations of TEs including cadmium (Cd), cobalt (Co), chromium (Cr), copper (Cu), manganese (Mn), nickel (Ni), lead (Pb), zinc (Zn) and iron (Fe) in soils of 16 farmlands were determined in Gonabad, Iran. In addition, the human health risks due to exposure to the TEs from the soils were assessed. Moreover, the soil contamination likelihood was evaluated based on various contamination indices including contamination factor [Formula: see text]), enrichment factor (EF), geo-accumulation index (Igeo), and pollution load index (PLI) calculations. The soil mean concentrations for Cd, Co, Cr, Cu, Mn, Ni, Pb, Zn and Fe ranges as 0.102, 6.968, 22.550, 29.263, 475.281, 34.234, 13.617, 54.482 and 19,683.6 mg/kg in farmland soils. The mean concentrations of the TEs decreased in the order of Fe > Mn > Zn > Ni > Cu > Cr > Pb > Co > As > Cd. Levels of all metals in this study were within the FAO/WHO and Iranian soil standards. The HQ values from investigated elements for adults and children in the studied farms were less than the limit of 1, indicating no health risks for the studied subpopulations. The results of the present research indicated no significant carcinogenic health hazards for both adults and children through ingestion, skin contact and inhalation exposure routes. [Formula: see text] values of Ni and Zn in 100% and 6.25% of farmlands were above 1, showing moderate contamination conditions. EF values of metals in farmlands were recorded as "no enrichment", "minimal enrichment" and "moderate enrichment" classes. Furthermore, it can be concluded that the all farms were uncontaminated except Ni (moderately contaminated) based on Igeo. This is an indication that the selected TEs in the agricultural soils have no appreciable threat to human health.

Determination of Concentration of Metals in Grapes Grown in Gonabad Vineyards and Assessment of Associated Health Risks.

Metals are considered major public health hazards, and they are known to accumulate in fruits, which are consumed by humans because of their unique sweet taste and potential health benefits. Therefore, the aims of this study were to determine the concentration of ten metals, namely arsenic (As), cadmium (Cd), cobalt (Co), chromium (Cr), copper (Cu), iron (Fe), manganese (Mn), nickel (Ni), lead (Pb), and zinc (Zn) in red grape samples grown in Gonabad vineyards and to estimate the associated health risks of metals in terms of chronic daily intake (CDI), carcinogenic and non-carcinogenic risks by hazard quotient (HQ), hazard index (HI), and cancer risk (CR) for children, teenagers, and adults. The overall concentrations of the metals in red grapes were in the range 0.07-0.5 (mean 0.14), 0.08-0.13 (mean 0.10), 0.07-0.13 (mean 0.09), 0.06-1.49 (mean 0.29), 0.52-4.12 (mean 1.65), 6.43-42.17 (mean 19.01), 0.89-4.04 (mean 1.89), 0.07-9.23 (mean 0.71), 0.07-0.37 (mean 0.18), and 0.40-4.13 (mean 1.05) mg/kg dry weight for As, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, and Zn, respectively. Based on the results, As in 11.76% and Zn in 5.88% of the samples exceeded the FAO/WHO permissible limits. The estimated non-carcinogenic and carcinogenic risk indices for children, teenagers, and adults showed that the results were lower than the critical value (1) and were in acceptable range. Therefore, red grape is safe for consumption with no impact on the human health. However, red grape consumption was just one part of fruit consumption, and the potential health hazards for inhabitants might actually be higher than in this research when other routes of heavy metal intake and also other fruits are considered.

Assessment of human health risks and pollution index for heavy metals in farmlands irrigated by effluents of stabilization ponds.

Areas contaminated with heavy metals can pose major risks to human health and ecological environments. The aims of this study are to assess human health risk and pollution index for heavy metals in agricultural soils irrigated by effluents of stabilization ponds in Birjand, Iran. The results revealed that the levels of Cr, Mn, Zn, Fe, Cu, Cd, and Pb were in range of 70.3-149.65, 355-570, 31.15-98.45, 23,925-29,140, 22.75-25.95, 0.17-6.51, and 8.5-23.5 mg/kg in topsoils, respectively. Total hazard index values from heavy metals through three exposure routes for adults and children were 9.13E-01 and 1.10, respectively, indicating that there was non-carcinogenic risk for children. The total risk of carcinogenic metals (Cr, Cd, and Pb) through the three exposure routes for adults and children was 1.06E-04 and 9.76E-04, respectively, which indicates that the metals in the soil will not induce carcinogenic risks to these age groups. Pollution levels of heavy metals in soil samples including enrichment factor (EF), contamination factor (CF), pollution load index (PLI), and geo-accumulation index (Igeo) showed heavy metal contamination of agricultural soils. The results of the present study provide basic information about heavy metal contamination control and human health risk assessment management in the study area.

Assessment of Heavy Metal Pollution and Human Health Risks Assessment in Soils Around an Industrial Zone in Neyshabur, Iran.

Heavy metal pollution of soils in industrial zones continues to attract attention because of its potential human health risks. The present research is an attempt to assess the pollution status of heavy metals including As, Cd, Cr, Ni, and Pb using various indices like contamination factor (CF), pollution index (IPOLL), and geo-accumulation index (Igeo). In total, 60 surface soil samples were collected from four area (north, south, east, and west) in Khayyam industrial zone from depths of 10-20 cm. The results indicated that average metal concentration ranges (in mg/kg) observed in study soils were 8.84, 1.9, 37.66, 15.77, and 57.33 for As, Cd, Cr, Ni, and Pb, respectively. The concentrations of heavy metals As, Cr, Ni, and Pb with the exception of Cd in soils of southern areas of the industrial zone were higher. Cd concentration vary negligibly in sampling sites of north, south, east, and west. Based on the CF, IPOLL, and Igeo indices, the pollution of soil in regard to concentration of heavy metals was in the following order: Cd > As > Pb > Ni > Zn. Industrial activities have therefore resulted in elevated concentrations of so in the soil environments in the Khayyam industrial zone. Based on the results of human health risk assessments, the soil metals pose negligible carcinogenic and non-carcinogenic risks to the adults and children living in this area. The need for the monitoring of the soil around the industrial zone, especially for Cd and As, is needed to reduce potential environmental issues.

Carcinogenic and non-carcinogenic health risk assessment of heavy metals in drinking water of Khorramabad, Iran.

The continuous urbanization and industrialization in many parts of the world and Iran has led to high levels of heavy metal contamination in the soil and then on the surface and groundwater. In this study, the concentrations of 8 heavy metals were determined in forty water samples along distribution drinking water of Khorramabad, Iran. The ranges of heavy metals in this study were lower than EPA and WHO drinking water recommendations and guidelines and so were acceptable. The mean values of CDItotal of heavy metals concentrations in adults were found in the order of Zn > Ba > Pb > Ni > Cr > Cu > Cd > Mo. The health-risk estimation indicated that total hazard quotient (HQing + HQderm) and hazard index values were below the acceptable limit, representing no non-carcinogenic risk to the residents via oral intake and dermal adsorption of water. Moreover, the results of total risk via ingestion and dermal contact showed that the ingestion was the predominant pathway. This study also presents that the carcinogenic risk for Pb, Cr, Cd and Ni were observed higher than the acceptable limit (1 × 10-6). The present study will be quite helpful for both inhabitants in taking protective measures and government officials in reducing heavy metals contamination of urban drinking water. •The data analyzed in this study show a clear situation regarding the quality of drinking water in Khorramabad.•The results of this study can be used to improve and develop the quality of drinking water that directly affects the health of consumers.•The present study will be quite helpful for both inhabitants in taking protective measures and government officials in reducing heavy metals contamination of urban drinking water.

Cadmium in Groundwater Consumed in the Rural Areas of Gonabad and Bajestan, Iran: Occurrence and Health Risk Assessment.

Evidences show that high levels of cadmium intake may be contributing to a wide range of deleterious health effects. This study was performed to estimate the concentration of cadmium and the health risk to human by cadmium through the ingestion of groundwater in 39 rural areas of Gonabad and Bajestan, eastern Iran. The mean cadmium concentrations in groundwater in the studied rural areas of Gonabad and Bajestan ranged from 0.087 to 14.32 µg/L and from 0.417 to 18.36 µg/L, respectively. Health risk quotient for cadmium contamination for 16 and 38% of children and infants in rural areas of Gonabad and Bajestan, respectively, was more than 1 which causes non-carcinogenic risk to the local population. The carcinogenic risk of cadmium in drinking water for adults, children, and infants in 16, 33, and 33% of studied rural areas of Gonabad and Bajestan, respectively, was higher than the safe limit of 1.0 × 10-4. For rural areas of Bajestan, the cancer risk in 42, 52, and 52% of adults, children, and infants was above the safe limit. It was strongly suggested that the accessible procedures of treatment should be taken for a portion of contaminated rural areas before the distribution of the groundwater for the local population.