Fractionation, source, and ecological risk assessment of heavy metals in cropland soils across a 100-year reclamation chronosequence in an estuary, South China.

Coastal reclamation for cropland has led to the accumulation of heavy metals in soils, bringing about pervasive and severe risks for environment and human health. However, less is known about the influence of long-term reclamation on heavy metals risk, mobility and bioavailability in cropland soil. In this study, we determined six heavy metals (Cd, Cr, Ni, Cu, Zn and Pb) and their fractionations in soils from five croplands across a 100-year reclamation chronosequence in the Pearl River estuary. Results showed that across five reclaimed soils, Cd posed seriously ecological risk and bioavailability according to assessments based on both total contents (single-metal pollution index: Cd > Cu > Zn > Ni > Cr > Pb) and fractionations (risk assessment code: Cd > Zn > Cu > Ni > Pb > Cr). Cr, Ni, Cu, Zn and Pb posed slightly to moderately ecological risks, and were mainly bound to residual (73.70%) and reducible (15.86%) fractions with lower mobility and bioavailability. With the highest risks level, mobility, toxicity and bioavailability (5.67% exchangeable and 11.75% carbonate fractions bound), Cd was identified as the main pollution factor in study area. Principal component analysis and Pearson's correlation analysis revealed that anthropogenic reclamation activities (including phosphate fertilizers, pesticides and sewage irrigation) were the major sources of these heavy metals. Long-term reclamation activities induced the increases of soil organic matter, clay contents, total concentrations and non-residual fractions of heavy metals by 46.14%, 538.98%, 42.87% and 219.78%, respectively, demonstrating significant promotions in level and mobility of heavy metals due to longer-term agricultural activities, higher soil clay and organic matter content.

Selection of pallet management strategies from the perspective of supply chain cost with Anylogic software.

Pallet is a very important innovation in logistics industry. Pallets are so widely used that we can find them in nearly every logistical operation scenario. In order to manage pallets efficiently, researchers have developed several pallet management strategies (PMS). The most common and widely accepted PMS includes extensive management of pallets (EMP), transfer of pallet's ownership (TPO), and pallet rent (PR). This paper addresses mainly on how to help pallet managers choose a certain kind of PMS from the perspective of supply chain cost. Firstly, cost models of three kinds of PMS are presented. Secondly, all parameters involved in the models are valued based on data that is collected from industry survey. The results show that the cost of PR is constantly lower than EMP, and also lower than TPO when the operation period is no more than 37 months. Finally, the effect of several important parameters on the cost is studied by sensitivity analysis. The selection strategies of PMS are proposed based on the results.

Heavy metal fractions and ecological risk assessment in sediments from urban, rural and reclamation-affected rivers of the Pearl River Estuary, China.

Rapid urbanization and reclamation processes in coastal areas have resulted in serious pollution to the aquatic environment. Less is known on the geochemical fractions and ecological risks in river sediment under various human activities pressures, which is essential for addressing the connections between heavy metal pollution and anthropogenic influences. River sediments were collected from different landscapes (i.e., urban, rural and reclamation areas) to investigate the impacts of urbanization and reclamation on the metallic pollution levels and ecological risks in the Pear River Estuary of China. Results showed that Cd, Zn and Cu with high total contents and geoaccumulation index (Igeo) were the primary metals in the Peal River sediments. Generally, urban river sediments, especially the surface sediment layer (0-10 cm), exhibited higher metallic pollution levels. As for geochemical fractions, reducible and residual fractions were the dominant forms for six determined metals. And the percentage of heavy metals bound to Fe-Mn oxides decreased with increasing soil depth but the reverse tendency was observed for residual fractions. Compared with rural river sediments, heavy metals were highly associated with the exchangeable and carbonate fractions in both urban and reclamation-affected river sediments, suggesting that anthropogenic activities mainly increased the active forms of metals. Approximately 80% of Cd existed in the non-residual fraction and posed medium to high ecological risk according to the risk assessment code (RAC) values. The redundancy analysis (RDA) revealed that both urbanization and reclamation processes would cause similar metallic characteristics, and sediment organic matter (SOC) might be the prominent influencing factor.

Occurrence, sources, and risk assessment of OCPs in surface sediments from urban, rural, and reclamation-affected rivers of the Pearl River Delta, China.

Sediments were collected to a depth of 20 cm from urban, rural, and reclamation-affected rivers in the Pearl River Delta of China. In total, 16 organochlorine pesticides (OCPs) were analyzed in all sediment samples, and the occurrence, possible sources, toxicity, and health risks of OCPs were evaluated to compare the contamination characteristics of OCPs in sediments among the three types of rivers. The results showed that concentrations of Σ16OCPs in sediments from the three rivers followed the order urban river > reclamation-affected river > rural river, with a mean value of 247.21, 232.91, and 114.92 µg/kg, respectively, and the predominant OCPs were hexachlorobenzene (HCB), dieldrin, aldrin, endrin, and hexachlorocyclohexanes (HCHs). Source diagnostics illustrated that there might be recent input of HCHs, dichlorodiphenyltrichloroethanes (DDTs), and endosulfan in some sampling sites. Based on the soil quality thresholds of China, both HCHs and DDTs fell within the range of class II criteria except for some sediment samples in urban rivers with lower levels (below class I criteria). According to sediment quality guidelines, 92.86 % of samples were predicted to be toxic. The health risk assessment showed that OCPs would not pose a threat to people via dermal contact, ingestion, and inhalation, and the followed order of incremental lifetime cancer risks for OCPs in sediment samples was reclamation-affected river > urban river > rural river.