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1.
J Environ Sci (China) ; 130: 114-125, 2023 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-37032028

RESUMO

Volatile organic compounds (VOCs) are the dominant pollutants in industrial parks. However, they are not generally considered as part of the air quality index (AQI) system, which leads to a biased assessment of pollution in industrial parks. In this study, a supplementary assessment system of AQI-V was established by analyzing VOCs characteristics with vehicle-mounted PTR-TOFMS instrument, correlation analysis and the standards analysis. Three hourly and daily scenarios were considered, and the hierarchical parameter setting was further optimized by field application. The hourly and daily assessments revealed the evaluation factors for the discriminability of different air quality levels, practiced value for regional air quality improvement, and the reservation of general dominant pollutants. Finally, the universality testing in ZPIP successfully recognized most of the peaks, with 54.76%, 38.39% and 6.85% for O3, VOCs and NO2 as the dominant pollutant, and reflected the daily ambient air quality condition, together with the dominant pollutant. The AQI-V system with VOCs sub-index is essential for air quality evaluation in industrial parks, which can further provide scientific support to control the pollution of VOCs and the secondary pollutant, therefore significantly improve the air quality in local industrial parks.


Assuntos
Poluentes Atmosféricos , Poluição do Ar , Poluentes Ambientais , Compostos Orgânicos Voláteis , Poluentes Atmosféricos/análise , Poluição do Ar/prevenção & controle , Poluição do Ar/análise , Poluentes Ambientais/análise , Indústrias , Ar/análise , Compostos Orgânicos Voláteis/análise , Monitoramento Ambiental , China , Material Particulado/análise
2.
Environ Sci Pollut Res Int ; 29(35): 52336-52354, 2022 Jul.
Artigo em Inglês | MEDLINE | ID: mdl-35257347

RESUMO

The soiling of the external façades of buildings caused by air pollution has economic costs that are generally not borne entirely by the polluters but by society in general. The present paper attempts to estimate the maintenance costs attributable to the soiling of the façades of residential buildings exposed to ambient air pollution in Italy. In this study, dose-response functions were used to link the environmental concentrations of pollutants to the soiling rate of the opaque and transparent surfaces of the building façades. It was assumed that the spatial distribution of façade materials follows the distribution of population. The basic assumption was that maintenance is performed when critical levels, 35% loss of reflectance for opaque surfaces and 1% haze for glass surfaces, are reached. Several important elements seem to emerge from the analysis carried out. The cost of damage to opaque surfaces due to air pollution appears to be a non-negligible fraction of the total maintenance costs of building façades incurred in Italy. Moreover, the cost of soiling damage to residential buildings from particulate matter has the potential to significantly increase total external costs due to air pollution. The costs of cleaning window panes due to air pollution also appear significant. Finally, if the levels of atmospheric pollution in the most populated areas become similar to the concentrations currently present in the most remote areas in Italy, the overall cost at national level due to the soiling of the building façades could be reduced by about 50%.


Assuntos
Poluentes Atmosféricos , Poluição do Ar , Ar/análise , Poluentes Atmosféricos/análise , Poluição do Ar/análise , Monitoramento Ambiental , Material Particulado/análise
3.
Chemosphere ; 263: 127903, 2021 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-32841873

RESUMO

In this study, seasonal/regional variations of Polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/DFs) and dioxin like-polychlorinated biphenyls in the ambient air were monitored for ten years (2008-2017) using a high volume air sampler. As a result of strict regulation enforced by Korea Ministry of Environment in 2008, PCDD/DFs concentrations in the ambient air decreased from 0.051 pg I-TEQ Sm-3 in 2009 to 0.014 pg I-TEQ Sm-3 in 2017 which was comparably associated with cut-down of their emission sources from 880.2 g I-TEQ Sm-3 in 2001 to 24.2 g I-TEQ Sm-3 in 2015; revealing that it was only 2.7% against that of 2001. In 2017, mean TEQ concentration level of PCDD/DFs in the air of South Korea was quite low in comparison to its ambient environmental standards of 0.6 pg I-TEQ Sm-3 for PCDD/DFs. Particularly, the sum of PCDD/DFs in the background revealed the lowest level, however, the fraction of octachlorodibenzodioxin among other isomers exposed at the highest level in this study, suggesting that the ambient air quality in the background being studied was severely and persistently impaired by inflowing unknown sources of any possible anthropogenic transboundary migratory air pollutants. Moreover, this study conducted the scientific analysis of the long-term variations in the ambient air and emission sources using principal component analysis. From this of 10 years long-term nationwide assessments for the PCDD/DFs and dl-PCBs in the ambient air, it is possible to prove that South Korean environmental policy to manage POPs has been successfully conducted for the last ten years.


Assuntos
Poluentes Atmosféricos/análise , Poluição do Ar/estatística & dados numéricos , Dibenzofuranos Policlorados/análise , Monitoramento Ambiental , Dibenzodioxinas Policloradas/análise , Ar/análise , Poluição do Ar/análise , Benzofuranos/análise , Dibenzofuranos/análise , Dioxinas/análise , Bifenilos Policlorados/análise , República da Coreia , Estações do Ano
4.
Ecotoxicol Environ Saf ; 201: 110833, 2020 Sep 15.
Artigo em Inglês | MEDLINE | ID: mdl-32535368

RESUMO

The largest mercury (Hg) mining district in the world is located in Almadén (Spain), with well-known environmental impacts in the surrounding ecosystem. However, the impact of mercury on the health of the inhabitants of this area has not been documented accordingly. This study aims to carry out a probabilistic human health risk assessment using Bayesian modeling to estimate the non-carcinogenic risk related to Hg through multiple exposure pathways. Samples of vegetables, wild mushrooms, fish, soil, water, and air were analyzed, and adult residents were randomly surveyed to adjust the risk models to the specific population data. On the one hand, the results for the non-carcinogenic risk based on Hazard Quotient (HQ) showed unacceptable risk levels through ingestion of Hg-contaminated vegetables and fish, with HQ values 20 and 3 times higher, respectively, than the safe exposure threshold of 1 for the 97.5th percentile. On the other hand, ingestion of mushrooms, dermal contact with soil, ingestion of water, dermal contact with water and inhalation of air, were below the safety limit for the 97.5th percentile, and did not represent a risk to the health of residents. In addition, the probabilistic approach was compared with the conservative deterministic approach, and similar results were obtained. This is the first study conducted in Almadén, which clearly reveals the high levels of human health risk to which the population is exposed due to the legacy of two millennia of Hg mining.


Assuntos
Exposição Ambiental/análise , Poluentes Ambientais/análise , Mercúrio/análise , Mineração , Adulto , Agaricales/química , Ar/análise , Animais , Teorema de Bayes , Ecossistema , Peixes/metabolismo , Humanos , Distribuição Aleatória , Medição de Risco , Solo/química , Espanha , Verduras/química
5.
Ecotoxicol Environ Saf ; 185: 109708, 2019 Dec 15.
Artigo em Inglês | MEDLINE | ID: mdl-31563748

RESUMO

In this study, the effluent from the Bayer process of transforming bauxite into alumina, followed by dissolved air flotation (DAF) treatment, was evaluated to identify the best experimental conditions that generate less toxic or nontoxic effluent for discharge. Two freshwater organisms, the Chlorophyceae microalga Raphidocelis subcapitata (96-h algal growth inhibition test), and the microcrustacean Daphnia similis (48-h acute immobility test), were used to analyze the efficiency of effluent treatment by detecting and comparing the toxicity of the treated effluent. Experimental factorial planning used different concentrations of the coagulant ferric chloride and the flocculant Nalco® N-99-005B, and different recycle ratios. The highest recycle ratio (30%) and highest flocculant concentration (150 mg/L) had the best solids removal efficiency, above 90%. Probably the higher concentration of flocculant led to the formation of a more stable froth, promoting an increase in the hydrophobic characteristics of the flocs. Two operating conditions were satisfactory according to acute and chronic bioassays, with removal efficiencies of total suspended solids and turbidity higher than 98%, for both variables. Producers, R. subcapitata microalga, were more sensitive than the primary consumers, D. similis microcrustaceans, indicating the importance of performing tests with different bioindicators.


Assuntos
Ar/análise , Óxido de Alumínio/toxicidade , Material Particulado/toxicidade , Poluentes Químicos da Água/toxicidade , Purificação da Água/métodos , Óxido de Alumínio/análise , Animais , Daphnia/efeitos dos fármacos , Ecotoxicologia , Floculação , Microalgas/efeitos dos fármacos , Modelos Teóricos , Tamanho da Partícula , Material Particulado/análise , Poluentes Químicos da Água/análise
6.
Bioelectrochemistry ; 130: 107335, 2019 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-31400569

RESUMO

High carbon catalyst loadings are commonly used for the catalyst layer (CL) in air-cathodes to obtain a performance comparable with that using platinum. This results in a much thicker CL, which severely limits mass transfer. In this study, we developed a porosity-gradient CL to passively enhance mass transfer in the air-cathode of microbial fuel cells (MFCs) for the first time. Computational results demonstrated that a cathode CL with increasing porosity (CL-IP) and decreasing porosity (CL-DP) from the water to the air-facing side exhibited improved transport of oxygen and OH-, respectively, alleviating concentration overpotentials in the CL. Experimental results also showed that an MFC that included a cathode with CL-IP achieved a maximum power density of 1781 ±â€¯92 mW m-2, which was higher than that achieved with CL-DP and a homogeneous CL (1614 ±â€¯72 and 1183 ±â€¯205 mW m-2).


Assuntos
Fontes de Energia Bioelétrica , Ar/análise , Fontes de Energia Bioelétrica/economia , Carbono/química , Catálise , Simulação por Computador , Eletrodos , Desenho de Equipamento , Oxigênio/química , Porosidade , Água/química
7.
Int Urogynecol J ; 30(12): 2061-2067, 2019 12.
Artigo em Inglês | MEDLINE | ID: mdl-30888456

RESUMO

INTRODUCTION AND HYPOTHESIS: To determine whether pressure readings measured with air-filled catheter (AFC) and water-filled catheter (WFC) systems are equivalent during cystometric assessment, especially in case of pressure measurements at Valsalva manoeuvres and coughs. METHODS: Twenty-five subjects were recruited. The commercially available 7-Fr TDOC AFC, which simultaneously reads water and air pressures in the bladder and rectum, was used to compare filling and voiding data recordings. Data were compared using paired t-tests, Bland-Altman plots and linear correlation methods, respectively. RESULTS: Pressure readings measured by the two systems showed a good correlation at Valsalva manoeuvres [R2 = 0.988, 0.968 for vesical pressure (Pves) and abdominal pressure (Pabd), respectively] and at coughs (R2 = 0.972, 0.943 for Pves and Pabd, respectively). There was a statistically significant difference between the two different measurement modalities at coughs (p < 0.01), initial resting pressure (p < 0.01) and the maximum pressure at detrusor overactivity (p < 0.01). This indicated that the difference between the two measurement modalities during Valsalva manoeuvres could reach up to 5.2 cmH2O and 8.1 cmH2O in Pves and Pabd measurements, respectively. During coughs, the difference could reach up to 20 cmH2O and 19.5 cmH2O in Pves and Pabd measurements, respectively. CONCLUSIONS: Pressure recordings from AFC and WFC systems appear to be interchangeable for some urodynamics parameters such as Pves at Valsalva manoeuvres if the baseline pressure is compensated, but not for fast-changing pressure signals such as coughs. This has to be considered when pressures are being taken with the AFC.


Assuntos
Ar/análise , Manometria/instrumentação , Cateteres Urinários , Doenças Urológicas/diagnóstico , Água/análise , Adulto , Tosse , Desenho de Equipamento , Feminino , Humanos , Masculino , Manometria/métodos , Pessoa de Meia-Idade , Pressão , Reto/fisiopatologia , Reprodutibilidade dos Testes , Bexiga Urinária/fisiopatologia , Cateterismo Urinário/instrumentação , Manobra de Valsalva , Adulto Jovem
8.
Sci Rep ; 9(1): 3110, 2019 02 28.
Artigo em Inglês | MEDLINE | ID: mdl-30816239

RESUMO

Despite increasingly growth in waterpipe smoking in Tehran, so far no study has been conducted on the air quality of the waterpipe and cigarette cafés. Thirty-six cafés were selected and the concentration of three pollutants including formaldehyde, carbon monoxide and nicotine were measured in both indoor and outdoor air of cafés two times (week-day and weekend's session). Air sampling was performed for 180 min for each pollutant. It was observed that the concentration of pollutants inside the cafés was higher during weekend session (with a higher number of "active waterpipe heads") compared with findings during the week-day sessions. Furthermore, the concentration of pollutants in the indoor air of the cafés was significantly higher than that of the outdoors (p < 0.05). According to path analysis, the number of "active waterpipe heads" had the maximum impact on generation of pollutants inside the cafés, followed by the type of tobacco as the second influential factor. The average of lifetime cancer risk (LTCR) resulted by formaldehyde exposure through inhalation in waterpipe (WS), cigarette (CS), waterpipe and cigarette (WCS) and none-smoking (NS) cafés in week-day and weekend sessions were estimated to be 111 × 10-5 and 61.2 × 10-5, 33.7 × 10-5 and 39.4 × 10-5, 271 × 10-5 and 322 × 10-5, and 4.80 × 10-5 and 5.90 × 10-5, respectively, which exceed the limit value by the U.S.EPA and WHO. The concentration of pollutants in the indoor air of smoking cafés in Tehran is significantly high, such that it can pose serious risks for the health of both personnel and customers. Therefore, decision makers are expected to enact applicable and strict policies so as to abate this public health risk.


Assuntos
Poluentes Atmosféricos/análise , Poluição do Ar em Ambientes Fechados/análise , Ar/análise , Exposição por Inalação/efeitos adversos , Medição de Risco , Poluição por Fumaça de Tabaco/efeitos adversos , Monóxido de Carbono/análise , Monitoramento Ambiental/métodos , Formaldeído/análise , Humanos , Irã (Geográfico) , Nicotina/análise , Fumar Tabaco/efeitos adversos , Fumar Cachimbo de Água/efeitos adversos
9.
Environ Sci Pollut Res Int ; 26(9): 9099-9112, 2019 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-30715717

RESUMO

The aim of this paper is to examine the relationship between CO2 emissions and its possible determinants and their direction of causality for Pakistan over the period of 1972 to 2017. The survey of literature guides us that the most frequently discussed factors are real GDP per capita, energy consumption, urbanization, trade openness, and financial development. Testing of environmental Kuznets curve (EKC) hypothesis is the most common in environment literature so we also incorporated the real GDP per capita squared term in the model. Autoregressive distributed lag (ARDL) bound testing approach to cointegration with structural break and error correction method (ECM) are applied to the selected time series to investigate the long-run relationship between CO2 emissions and real GDP per capita, real GDP per capita squared term, energy consumption, urbanization, trade openness, and financial development. The empirical evidence confirms the cointegration among the variables and EKC holds for Pakistan support H1 of the study, which though contradictory to the previous studies conducted on Pakistan but all of previous work faces the exclusion bias and their findings were skewed. The findings also suggest that energy consumption and urbanization have a positive effect on CO2 emissions, supporting H2 and H3. However, H4 and H5 rejected as trade openness and financial development found positively significant. Moreover, bidirectional Granger causality was exists only between CO2 emissions and trade openness. The findings suggests that Pakistan need to settle the economic agenda of the nation through the resolution of economic controversies, energy mix need to tilt toward clean and renewable energy, and rural-urban migration need to manage for better air, water, and living.


Assuntos
Ar/análise , Dióxido de Carbono/análise , Poluição do Ar/economia , Paquistão , Urbanização
10.
J Air Waste Manag Assoc ; 69(1): 71-88, 2019 01.
Artigo em Inglês | MEDLINE | ID: mdl-30204538

RESUMO

Novel aerial methane (CH4) detection technologies were used in this study to identify anomalously high-emitting oil and gas (O&G) facilities and to guide ground-based "leak detection and repair" (LDAR) teams. This approach has the potential to enable a rapid and effective inspection of O&G facilities under voluntary or regulatory LDAR programs to identify and mitigate anomalously large CH4 emissions from a disproportionately small number of facilities. This is the first study of which the authors are aware to deploy, evaluate, and compare the CH4 detection volumes and cost-effectiveness of aerially guided and purely ground-based LDAR techniques. Two aerial methods, the Kairos Aerospace infrared CH4 column imaging and the Scientific Aviation in situ aircraft CH4 mole fraction measurements, were tested during a 2-week period in the Fayetteville Shale region contemporaneously with conventional ground-based LDAR. We show that aerially guided LDAR can be at least as cost-effective as ground-based LDAR, but several variable parameters were identified that strongly affect cost-effectiveness and which require field research and improvements beyond this pilot study. These parameters include (i) CH4 minimum dectectable limit of aerial technologies, (ii) emission rate size distributions of sources, (iii) remote distinction of fixable versus nonfixable CH4 sources ("leaks" vs. CH4 emissions occurring by design), and (iv) the fraction of fixable sources to total CH4 emissions. Suggestions for future study design are provided. Implications: Mitigation of methane leaks from existing oil and gas operations currently relies on on-site inspections of all applicable facilities at a prescribed frequency. This approach is labor- and cost-intensive, especially because a majority of oil and gas-related methane emissions originate from a disproportionately small number of facilities and components. We show for the first time in real-world conditions how aerial methane measurements can identify anomalously high-emitting facilities to enable a rapid, focused, and directed ground inspection of these facilities. The aerially guided approach can be more cost-effective than current practices, especially when implementing the aircraft deployment improvements discussed here.


Assuntos
Poluentes Atmosféricos/análise , Exposição Ambiental/prevenção & controle , Monitoramento Ambiental , Poluição Ambiental , Metano/análise , Indústria de Petróleo e Gás/normas , Ar/análise , Ar/normas , Aeronaves , Análise Custo-Benefício , Saúde Ambiental/métodos , Saúde Ambiental/normas , Monitoramento Ambiental/economia , Monitoramento Ambiental/métodos , Poluição Ambiental/análise , Poluição Ambiental/prevenção & controle , Recuperação e Remediação Ambiental/métodos , Humanos , Projetos Piloto
11.
Integr Environ Assess Manag ; 14(2): 185-188, 2018 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-29193666

RESUMO

This commentary examines recent shifts in air temperature data coinciding with high-magnitude precipitation events at climate stations spanning an elevational and longitudinal gradient on the south coast of British Columbia, Canada. Results presented show that high-magnitude winter precipitation events are occurring on British Columbia's south coast under progressively warmer conditions. In the future, proportionally more winter precipitation is anticipated to report as rainfall versus snow, and over time these changes will have a marked impact on the snowmelt-dominated hydrographs that characterize local watersheds. Robust preparedness strategies will be needed to balance competing interests such as the security of domestic water supplies, the permitting and operation of major projects (e.g., mines, hydrodevelopments), and the achievement of broader ecosystem health goals under these changing hydroclimatic conditions. Integr Environ Assess Manag 2018;14:185-188. © 2018 SETAC.


Assuntos
Ar/análise , Monitoramento Ambiental , Temperatura , Colúmbia Britânica , Conservação dos Recursos Naturais , Estações do Ano
12.
Adv Exp Med Biol ; 977: 191-197, 2017.
Artigo em Inglês | MEDLINE | ID: mdl-28685445

RESUMO

The accuracy of images obtained by Diffuse Optical Tomography (DOT) could be substantially increased by the newly developed time resolved (TR) cameras. These devices result in unprecedented data volumes, which present a challenge to conventional image reconstruction techniques. In addition, many clinical applications require taking photons in air regions like the trachea into account, where the diffusion model fails. Image reconstruction techniques based on photon tracking are mandatory in those cases but have not been implemented so far due to computing demands. We aimed at designing an inversion algorithm which could be implemented on commercial graphics processing units (GPUs) by making use of information obtained with other imaging modalities. The method requires a segmented volume and an approximately uniform value for the reduced scattering coefficient in the volume under study. The complex photon path is reduced to a small number of partial path lengths within each segment resulting in drastically reduced memory usage and computation time. Our approach takes advantage of wavelength normalized data which renders it robust against instrumental biases and skin irregularities which is critical for realistic clinical applications. The accuracy of this method has been assessed with both simulated and experimental inhomogeneous phantoms showing good agreement with target values. The simulation study analyzed a phantom containing a tumor next to an air region. For the experimental test, a segmented cuboid phantom was illuminated by a supercontinuum laser and data were gathered by a state of the art TR camera. Reconstructions were obtained on a GPU-installed computer in less than 2 h. To our knowledge, it is the first time Monte Carlo methods have been successfully used for DOT based on TR cameras. This opens the door to applications such as accurate measurements of oxygenation in neck tumors where the presence of air regions is a problem for conventional approaches.


Assuntos
Processamento de Imagem Assistida por Computador/métodos , Tomografia Óptica/métodos , Ar/análise , Algoritmos , Gráficos por Computador , Simulação por Computador , Difusão , Humanos , Método de Monte Carlo , Imagens de Fantasmas , Espectroscopia de Luz Próxima ao Infravermelho/métodos
13.
Indoor Air ; 27(6): 1039-1051, 2017 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-28683161

RESUMO

Based on a review of literature published in refereed archival journals, ventilation rates in classrooms often fall far short of the minimum ventilation rates specified in standards. There is compelling evidence, from both cross-sectional and intervention studies, of an association of increased student performance with increased ventilation rates. There is evidence that reduced respiratory health effects and reduced student absence are associated with increased ventilation rates. Increasing ventilation rates in schools imposes energy costs and can increase heating, ventilating, and air-conditioning system capital costs. The net annual costs, ranging from a few dollars to about 10 dollars per person, are less than 0.1% of typical public spending on elementary and secondary education in the United States. Such expenditures seem like a small price to pay given the evidence of health and performance benefits.


Assuntos
Desempenho Acadêmico , Dióxido de Carbono/análise , Instituições Acadêmicas/estatística & dados numéricos , Ventilação/estatística & dados numéricos , Ar/análise , Poluição do Ar em Ambientes Fechados/efeitos adversos , Nível de Saúde , Humanos , Instituições Acadêmicas/economia , Ventilação/economia
14.
Regul Toxicol Pharmacol ; 86: 148-156, 2017 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-28257852

RESUMO

As part of a joint project between the Research Institute for Fragrance Materials (RIFM) and Creme Global, a Monte Carlo model (here named the Creme RIFM model) has been developed to estimate consumer exposure to ingredients in personal care products. Details of the model produced in Phase 1 of the project have already been published. Further data on habits and practises have been collected which enable the model to estimate consumer exposure from dermal, oral and inhalation routes for 25 product types. . In addition, more accurate concentration data have been obtained which allow levels of fragrance ingredients in these product types to be modelled. Described is the use of this expanded model to estimate aggregate systemic exposure for eight fragrance ingredients. Results are shown for simulated systemic exposure (expressed as µg/kg bw/day) for each fragrance ingredient in each product type, along with simulated aggregate exposure. Highest fragrance exposure generally occurred from use of body lotions, body sprays and hydroalcoholic products. For the fragrances investigated, aggregate exposure calculated using this model was 11.5-25 fold lower than that calculated using deterministic methodology. The Creme RIFM model offers a very comprehensive and powerful tool for estimating aggregate exposure to fragrance ingredients.


Assuntos
Ar/análise , Cosméticos/química , Administração Cutânea , Exposição Ambiental , Modelos Teóricos , Método de Monte Carlo , Perfumes/química
15.
J Hazard Mater ; 327: 35-43, 2017 Apr 05.
Artigo em Inglês | MEDLINE | ID: mdl-28038430

RESUMO

Degradation of mechanically sorted organic fraction (MSOF) of municipal solid waste in composting facilities is among the major contributors of volatile compounds (VCs) generation and emission, causes nuisance problems and health risks on site as well as in the vicinages. The aim of current study was to determine the seasonal (summer and winter) variation and human health risk assessment of VCs in the ambient air of different processing units in MSOF at composting plant in China. Average concentration of VCs was 58.50 and 138.03mg/m3 in summer and winter respectively. Oxygenated compounds were found to be the highest concentration (46.78-91.89mg/m3) with ethyl alcohol as the major specie (43.90-85.31mg/m3) in the two seasons respectively. Nevertheless, individual non-carcinogenic (Hazard relation i.e HR<1) and carcinogenic risk (CR<1.0E-04) of the quantified VCs were within acceptable limit except naphthalene at biofilter unit. In addition, cumulative non-carcinogenic risk exceeded from the threshold limit both in summers and winters in all units except at biofilter unit during winter. Furthermore cumulative carcinogenic risk also exceeded at same unit during the summer season. Therefore special attention should be made to minimize cumulative non-carcinogenic and carcinogenic risk as people are well exposed to mixture of compounds, not to individual.


Assuntos
Compostagem , Eliminação de Resíduos , Resíduos Sólidos/análise , Compostos Orgânicos Voláteis/análise , Compostos Orgânicos Voláteis/toxicidade , Ar/análise , Poluentes Ocupacionais do Ar/análise , Poluentes Ocupacionais do Ar/toxicidade , Algoritmos , Carcinógenos/toxicidade , China , Monitoramento Ambiental , Humanos , Naftalenos/toxicidade , Medição de Risco , Estações do Ano
16.
J Res Health Sci ; 16(3): 133-140, 2016.
Artigo em Inglês | MEDLINE | ID: mdl-27840341

RESUMO

BACKGROUND: Heat stress evaluation and timely notification, especially using meteorological data is an important issue attracted attention in recent years. Therefore, this study aimed at answering the following research questions: 1) can enthalpy as a common environmental parameter reported by meteorological agencies be applied accurately for evaluation of thermal condition of outdoor settings, and 2) if so, what is it's the best criterion to detect areas in stress or stress-free situations, separately. METHODS: Nine climatic regions were selected throughout Iran covering a wide variety of climatic conditions like those, which exist around the world. Three types of parameters including measured (ta, RH, Pa and WBGT), estimated (metabolic rate and cloth thermal insulation), and calculated parameters (enthalpy and effective WBGT) were recorded for 1452 different situations. Enthalpy as a new indicator in this research was compared to WBGT in selected regions. RESULTS: Altogether, a good consistency was obtained between enthalpy and WBGT in selected regions (Kappa value: 0.815). Based on the good ROC curve obtained using MedCal software, the criterion of the values more than 74.24 for the new index was determined to explain heat stress situation for outdoor environments. CONCLUSIONS: Because of simplicity in measurement, applicability of the indicator for weather agencies, the consistency observed between enthalpy and a valid as well as accurate index (WBGT), sensor requirements which take only a few seconds to reach equilibrium and so on, enthalpy indicator can be introduced and applied as a good substitute for WBGT for outdoor settings.


Assuntos
Ar/análise , Monitoramento Ambiental/métodos , Transtornos de Estresse por Calor/etiologia , Temperatura Alta , Exposição Ocupacional/efeitos adversos , Tempo (Meteorologia) , Clima , Humanos , Irã (Geográfico) , Medição de Risco
17.
Environ Monit Assess ; 188(9): 499, 2016 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-27485615

RESUMO

The Second-order Closure Integrated Puff (SCIPUFF) model was used to study the impact on urban air quality caused by two cement plants emissions located near the city of Caserta, Italy, during the entire year of 2015. The simulated and observed PM10 concentrations were compared using three monitoring stations located in urban and sub-urban area of Caserta city. Both simulated and observed concentrations are shown to be highest in winter, lower in autumn and spring and lowest in summer. Model results generally follow the pattern of the observed concentrations but have a systematic under-prediction of the concentration values. Measures of the bias, NMSE and RMSE indicate a good correlation between observed and estimated values. The SCIPUFF model data analysis suggest that the cement plants are major sources for the measured PM10 values and are responsible for the deterioration of the urban air quality in the city of Caserta.


Assuntos
Poluentes Atmosféricos/análise , Materiais de Construção , Monitoramento Ambiental/métodos , Modelos Teóricos , Material Particulado/análise , Ar/análise , Ar/normas , Cidades , Itália , Estações do Ano
18.
J Environ Sci (China) ; 39: 62-68, 2016 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-26899645

RESUMO

Quartz particles are a toxic component of airborne particulate matter (PM). Quartz concentrations were analyzed by X-ray diffraction in eighty-seven airborne PM samples collected from three locations in Beijing before, during, and after the Asia-Pacific Economic Cooperation (APEC) Leaders' Meeting in 2014. The results showed that the mean concentrations of quartz in PM samples from the two urban sites were considerably higher than those from the rural site. The quartz concentrations in samples collected after the APEC meeting, when the pollution restriction lever was lifted, were higher than those in the samples collected before or during the APEC meeting. The quartz concentrations ranged from 0.97 to 13.2 µg/m(3), which were among the highest values amid those reported from other countries. The highest quartz concentration exceeded the Californian Office of Environmental Health Hazard Assessment reference exposure level and was close to the occupational threshold limit values for occupational settings. Moreover, a correlation analysis showed that quartz concentrations were positively correlated with concentrations of pollution parameters PM10, PM2.5, SO2 and NOx, but were negatively correlated with O3 concentration. The results suggest that the airborne quartz particles may potentially pose health risks to the general population of Beijing.


Assuntos
Poluentes Atmosféricos/análise , Ar/análise , Monitoramento Ambiental , Material Particulado/análise , Quartzo/análise , Pequim , Saúde
19.
Environ Int ; 86: 84-91, 2016 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-26550706

RESUMO

We present a method to assess the air quality of an environment based on the chemosensory irritation impact of mixtures of volatile organic compounds (VOCs) present in such environment. We begin by approximating the sigmoid function that characterizes psychometric plots of probability of irritation detection (Q) versus VOC vapor concentration to a linear function. First, we apply an established equation that correlates and predicts human sensory irritation thresholds (SIT) (i.e., nasal and eye irritation) based on the transfer of the VOC from the gas phase to biophases, e.g., nasal mucus and tear film. Second, we expand the equation to include other biological data (e.g., odor detection thresholds) and to include further VOCs that act mainly by "specific" effects rather than by transfer (i.e., "physical") effects as defined in the article. Then we show that, for 72 VOCs in common, Q values based on our calculated SITs are consistent with the Threshold Limit Values (TLVs) listed for those same VOCs on the basis of sensory irritation by the American Conference of Governmental Industrial Hygienists (ACGIH). Third, we set two equations to calculate the probability (Qmix) that a given air sample containing a number of VOCs could elicit chemosensory irritation: one equation based on response addition (Qmix scale: 0.00 to 1.00) and the other based on dose addition (1000*Qmix scale: 0 to 2000). We further validate the applicability of our air quality assessment method by showing that both Qmix scales provide values consistent with the expected sensory irritation burden from VOC mixtures present in a wide variety of indoor and outdoor environments as reported on field studies in the literature. These scales take into account both the concentration of VOCs at a particular site and the propensity of the VOCs to evoke sensory irritation.


Assuntos
Poluentes Atmosféricos/análise , Ar , Irritantes/análise , Limiar Sensorial/efeitos dos fármacos , Compostos Orgânicos Voláteis/análise , Ar/análise , Ar/normas , Poluentes Atmosféricos/toxicidade , Olho/efeitos dos fármacos , Humanos , Irritantes/toxicidade , Modelos Teóricos , Nariz/efeitos dos fármacos , Detecção de Sinal Psicológico , Níveis Máximos Permitidos , Compostos Orgânicos Voláteis/toxicidade
20.
Chemosphere ; 138: 546-52, 2015 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-26210018

RESUMO

2-Ethylhexyl 4-methoxycinnamate is one of the UVB blocking agents more widely used in a variety of industrial fields. There are more than one hundred industrial suppliers worldwide. Given the enormous annual consumption of octinoxate, problems that arise due to the accumulation of this compound in nature should be taken into consideration. The GC-RT was used in this work with the aim of determining the vapor pressure, enthalpies of vaporization and octanol-air partition coefficient, for the BBP, DOP, E- and Z-EHMC esters. The results showed that Z-EHMC is almost five times more volatile than E-EHMC. Moreover, BBP, Z-EHMC and E-EHMC can be classified as substances with a relatively low mobility since they lie within the range of 810 and log(PL/Pa)<-4, therefore, a low mobility can be expected. From these parameters, their particle-bound fraction and gas-particle partition coefficient were also derived.


Assuntos
Ar/análise , Cinamatos/química , Meio Ambiente , Poluentes Ambientais/química , Octanóis/química , Pressão de Vapor , Estereoisomerismo , Termodinâmica , Volatilização
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