The large-scale expansion of rubber plantations in southern India: major impacts and the changing nature of drivers.

This study investigates the major environmental and socio-economic impacts of an increase in the area of rubber plantations and the changing patterns of drivers of land use changes. Using a combination of geospatial techniques and socio-economic methods, we mainly analyzed the rate of increase in area under rubber plantations, the major impacts of land use changes, and the changing drivers of land use changes. Our results show that the area under rubber plantations has increased significantly within the study area, with the area under rubber plantations increasing from 30 to 74% of the total area within five decades. Impact assessment of land use changes based on household surveys showed significant improvement in the socio-economic conditions of the farmers, however, at the expense of severe environmental degradation. Our results also indicate that while areas under rubber plantations continue to increase, the drivers of land use changes have changed over time. Furthermore, it has been observed that in the past, many interventions prioritized social and economic development and placed less emphasis on the ecological stability of the region. Perceptions of farmers revealed that the effects of ecological fragility already affected the economic robustness of the whole area. Therefore, we conclude that government interventions to support additional rubber cultivation should also focus on ecosystem stabilization in order to minimize the risk of an ecological catastrophe that would significantly affect the economic prosperity of the region.

Comparing the wound healing potential of natural rubber latex serum and F1-protein: An in vivo approach.

Chronic wounds pose significant health concerns. Current treatment options include natural compounds like natural rubber latex (NRL) from Hevea brasiliensis. NRL, particularly the F1 protein fraction, has demonstrated bioactivity, biocompatibility, and angiogenic effects. So far, there is no study comparing F1 protein with total NRL serum, and the necessity of downstream processing remains unknown. Here, we evaluated the angiogenic potential of F1 protein compared to total NRL serum and the need for downstream processing. For that, ion exchange chromatography (DEAE-Sepharose), antioxidant activity, physicochemical characterization, cell culture in McCoy fibroblasts, and wound healing in Balb-C mice were performed. Also, the evaluation of histology and collagen content and the levels of inflammatory mediators were quantified. McCoy fibroblast cell assay showed that F1 protein (0.01 %) and total NRL serum (0.01 %) significantly increased cell proliferation by 47.1 ± 11.3 % and 25.5 ± 2.5 %, respectively. However, the AA of F1 protein (78.9 ± 0.8 %) did not show a significant difference compared to NRL serum (77.0 ± 1.1 %). F1 protein and NRL serum were more effective in wound management in rodents. Histopathological analysis confirmed accelerated healing and advanced tissue repair. Similarly, the F1 protein (0.01 %) increased collagen, showing that this fraction can stimulate the synthesis of collagen by fibroblastic cells. Regarding cytokines production (IL-10, TNF-α, IFN-γ), F1 protein and NRL serum did not exert an impact on the synthesis of these cytokines. Furthermore, we did not observe statistically significant changes in dosages of enzymes (MPO and EPO) among the groups. Nevertheless, Nitric Oxide dosage was reduced drastically when the F1 protein (0.01 %) protein was applied topically. These findings contribute to the understanding of F1 protein and NRL serum properties and provide insights into cost-effectiveness and practical applications in medicine and biotechnology. Therefore, further research is needed to assess the economic feasibility of downstream processing for NRL-based herbal medicine derived from Hevea brasiliensis.

Non-targeted analysis based on quantitative prediction and toxicity assessment for emerging contaminants in tire particle leachates.

Non-targeted analysis (NTA) has great potential to screen emerging contaminants in the environment, and some studies have conducted in-depth investigation on environmental samples. Here, we used a NTA workflow to identify emerging contaminants in used tire particle (TP) leachates, followed by quantitative prediction and toxicity assessment based on hazard scores. Tire particles were obtained from four different types of automobiles, representing the most common tires during daily transportation. With the instrumental analysis of TP leachates, a total of 244 positive and 104 negative molecular features were extracted from the mass data. After filtering by a specialized emerging contaminants list and matching by spectral databases, a total of 51 molecular features were tentatively identified as contaminants, including benzothiazole, hexaethylene glycol, 2-hydroxybenzaldehyde, etc. Given that these contaminants have different mass spectral responses in the mass spectrometry, models for predicting the response of contaminants were constructed based on machine learning algorithms, in this case random forest and artificial neural networks. After five-fold cross-validation, the random forest algorithm model had better prediction performance (MAECV = 0.12, Q2 = 0.90), and thus it was chosen to predict the contaminant concentrations. The prediction results showed that the contaminant at the highest concentration was benzothiazole, with 4,875 µg/L in the winter tire sample. In addition, the joint toxicity assessment of four types of tires was conducted in this study. According to different hazard levels, hazard scores increasing by a factor 10 were developed, and hazard scores of all the contaminants identified in each TP leachate were summed to obtain the total hazard score. All four tires were calculated to have relatively high risks, with winter tires having the highest total hazard score of 40,751. This study extended the application of NTA research and led to the direction of subsequent targeting studies on highly concentrated and toxic contaminants.

Assessment of the effect of different pulping by-products on enhancing the reuse of rubber waste in producing of cement-mortar.

This work deals with avoiding the pollution risks from paper pulping liquors and rubber wastes that result from routine disposal tools; moreover, finding an approach to minimize the drawback of incorporating the rubber waste in weakening the strength of building materials. In this respect, pulping black liquors (BLs) is assessed as a treating agent for rubber waste and substituting the water in cement mortar formulation. The assessment was achieved by testing the mechanical properties, water resistance (reduction in water absorption and dimensional change against water), and morphology. The results showed that all BLs from different pulping agents, used in mixtures with water, provided improvements in both strength and water resistance properties. Kraft black liquor is most effective in providing improvements in compressive strength and flexural strength, as well as resistance to water absorption and change in dimension after exposure to water for 24 h, where the improvements were 688.2 %, 494.3 %, 27 %, and 65.3 %, respectively. It is interesting to note that this investigated route provided improvements in the impact resistance property of mortar. This last property is essential for minimizing accidents on the highway.

Trade margins of rubber exporters: The case of Indonesia.

This study used a two-step system generalized method of moment (GMM) and spatial aspects to analyze Indonesia's trade margins of a rubber product to export destination countries over the period 2009-2018. The study unraveled the role of non-tariff measures such as sanitary and phytosanitary (SPS), technical barriers to trade (TBT), and gravity factors in determining rubber trade margins. Our empirical strategies revealed that sanitary and phytosanitary policies negatively affect trade margins, while the technical barrier to trade and foreign direct investment (FDI) asserts a positive impact on trade margins. However, the economics of scale, port, and contiguity increases extensive margin and reduces intensive, population size, distance, and language barrier reduce extensive margin and increase intensive margin. Further evidence revealed that high population size and port quality accompanied by high FDI and distance increases extensive margin and reduces intensive margin. High economics of scale accompanied by distance, port quality, FDI, and population size reduces both trade margins. Our empirical strategy from the spatial analysis does not give overall significant results on each variable as only economies of scale and population size seem to have a spatial influence on trade margins. The study, therefore, recommends that innovation both in terms of technology, like industrial innovation in the field of rubber processing and certification related to rubber commodities, needs to be increased to intensify and expand Indonesia's rubber market share.

Assessment of Contact Allergens in "Hypoallergenic" Athletic Shoes by Mass Spectrometry.

Background: Identification of athletic shoes for patients with contact allergy is difficult. Company reports of allergen content are often incorrect. Objectives: To determine whether chemical analysis of 4 athletic shoes, previously reported to be free of the most common contact allergens, contain quantifiable allergen levels. Methods: Samples from the uppers and insoles of 4 shoes believed to be free of common allergens were assessed by mass spectrometry. A total of 4 rubber accelerators and 2 adhesives were directly quantified and additional 7 rubber accelerators were assessed using semiquantitative measures. Results: Aside from carbamates (assayed as 59 ppm zinc in insoles) in SeaVee's Sixty-Six sneakers, para-tertiarybutylphenol formaldehyde resin (PTBFR) (assayed as 7.6 ppm paratertiary butylphenol or 4-tertiary butylphenol [4TBP] in uppers) in Allbirds Tree Runners and rosin (assayed as 628 ppm sodium abietate in uppers) and carbamates (24 ppm zinc in uppers) in Saucony Jazz sneakers, these shoes had low levels of all allergens assayed in this study. Tom's Carlo sneakers contained rosin (127 ppm sodium abietate in insoles), PTBFR (6.5 ppm 4TBP in uppers), and carbamates (112 ppm sodium abietate in insoles) but had low levels of all other assayed allergens. Conclusions: Although identifying allergen-free shoes is challenging, the results of this analysis will help patch testing physicians recommend athletic shoes to patients with specific allergies.

Uncovering the energy-carbon-water footprint of waste rubber recycling: Integrated environmental and economic perspectives.

The commitment to waste management has gained increasing momentum as global waste generation continues to skyrocket and threaten the environment. However, detailed assessments and clear insights remain absent to address the global waste utilization conundrum. This study evaluated the impact-oriented energy, carbon, and water (ECW) footprints of three typical scenarios for a waste recycling activity (i.e., waste rubber recycling) from environmental and economic dimensions, and explored key factors, nexus characteristics, and optimization measures. Results indicated that the rubber powder as an asphalt modifier scenario had a 93% greater environmental impact and 87% higher economic cost compared with the pyrolysis and reclaimed rubber production scenarios. Key processes, such as direct processes, electricity generation, and transportation, were identified as the major contributors to the ECW footprints, with the internal costs of raw materials, equipment, and taxes coupled with the external costs of human health dominating the economic impact. The nexus analysis results highlighted the urgent need to optimize the energy system for waste rubber recycling. Greening the production process revealed the benefits, with natural additives mitigating 85% of the environmental burden and 97% of the external costs compared with conventional additives. Industrial green microgrids, clean energy generation, proximity waste management, and electrified transportation were explored to foster sustainable optimization of waste rubber recycling systems. Moreover, a joint tax-subsidy mechanism for rubber production-recycling systems can stimulate recycling-oriented product design and increase the motivation to recycle waste rubber.

Imperative assessment on the current status of rubber wastewater treatment: Research development and future perspectives.

The environment has been significantly impacted by the rubber industry through the release of large quantities of wastewater during various industrial processes. Therefore, it is crucial to treat the wastewater from the rubber industry before discharging it into natural water bodies. With the understanding that alarmingly depleting freshwater sources need to be preserved for future generations, this paper reviews the status of the rubber industry and the pollution caused by them, focusing mainly on water pollution. The review pays special attention to the recent advancements in wastewater treatment techniques for rubber industry wastewater categorizing them into pre-treatment, secondary, and tertiary treatment processes while discussing the advantages and disadvantages. Through a comprehensive analysis of existing literature, it was determined that organic content and NH4+ are the most frequently focused water quality parameters, and despite some treatment methods demonstrating superior performance, many of the methods still face limitations and require further research to improve systems to handle high organic loading on the treatment systems and to implement them in industrial scale. The paper also explores the potential of utilizing untreated or treated wastewater and byproducts of wastewater treatment in contributing towards achieving several United Nations sustainable development goals (UN-SDGs); SDG 6, SDG 7, SDG 9, and SDG 12.

Synthesis of a new biocomposite for fertiliser coating: assessment of biodegradability and thermal stability.

The bio- and thermal degradation as well as the water absorption properties of a novel biocomposite comprising cellulose nanoparticles, natural rubber and polylactic acid have been investigated. The biodegradation process was studied through an assembled condition based on the soil collected from the central Malaysian palm oil forests located in the University of Nottingham Malaysia. The effects of the presence of the cellulose nanoparticles and natural rubber on the biodegradation of polylactic acid were investigated. The biodegradation process was studied via thermal gravimetric analysis and scanning electron microscopy. It was understood that the reinforcement of polylactic acid with cellulose nanoparticles and natural rubber increases the thermal stability by ~ 20 °C. Limited amorphous regions on the surface of the cellulose nanoparticles accelerated the biodegradation and water absorption processes. Based on the obtained results, it is predicted that complete biodegradation of the synthesised biocomposites can take place in 3062 h, highlighting promising agricultural applications for this biocomposite.

Valorisation of spent tire rubber as carbon adsorbents for Pb(II) and W(VI) in the framework of a Circular Economy.

Spent tire rubber-derived chars and their corresponding H3PO4 and CO2-activated chars were used as adsorbents in the recovery of Pb(II) ion and (W(VI)) oxyanion from synthetic solutions. The developed chars (both raw and activated) were thoroughly characterized to have insight about their textural and surface chemistry properties. H3PO4-activated chars presented lower surface areas than the raw chars and an acidic surface chemistry which affected the performance of these samples as they showed the lowest removals of the metallic ions. On the other hand, CO2-activated chars presented increased surface areas and increased mineral content compared to the raw chars, having presented higher uptake capacities for both Pb(II) (103-116 mg/g) and W(VI) (27-31 mg/g) ions. Cation exchange with Ca, Mg and Zn ions was appointed as a mechanism for Pb removal, as well as surface precipitation in the form of hydrocerussite (Pb3(CO3)2(OH)2). W(VI) adsorption might have been ruled by strong electrostatic attractions between the negatively charged tungstate species and the highly positively charged carbons' surface.The results shown in this work allow concluding that the valorisation of spent tire rubber through pyrolysis and the subsequent activation of the obtained chars is an alternative and a feasible option to generate adsorbent materials with a high uptake capacity of critical metallic elements.

Assessment of the bioaccessibility of PAHs and other hazardous compounds present in recycled tire rubber employed in synthetic football fields.

Recycled tire crumb rubber (RTCR) surfaces contain harmful and carcinogenic substances, which can be ingested by the users of these facilities, mainly athletes and children. In this work, the potential in-vitro oral bioaccessibility of eighteen polycyclic aromatic hydrocarbons (PAHs) from RTCR employed as infill in synthetic football fields was studied in human synthetic body fluids (saliva, gastric, duodenal and bile), prepared according the Unified Bioaccessibility Method. Solid-phase extraction (SPE) using commercial sorbents and a new green material based on cork (cork industry by-product) were used to isolate the bioaccessible PAHs before gas chromatography-tandem mass spectrometry analysis. The method was optimized and validated attending the analytical figures of merit. The feasibility of cork biosorbent for the extraction of the compounds was demonstrated, as well as the suitability of the UBM method to perform the digestion with good precision. The application to real samples collected from football fields demonstrated the presence of 17 of the 18 target PAHs in the biofluids. Most volatile PAHs such as NAP, ACY, ACE, FLU, PHN and ANC, achieved the highest bioaccessibility percentage levels. The carcinogenic B[a]P was detected in 75 % of the samples at concentrations up to 2.5 ng g-1 (bioaccessible fraction). Children exposure assessment was carried out to identify potential risk. Other hazardous and environmentally problematic compounds such as N-(1,3-Dimethylbutyl)-N'-phenyl-p-phenylenediamine-quinone (6PPD-quinone), recently related with the dead of coho salmon, and hexamethoxymethylmelamine (HMMM), among others, were also detected. This is the first study in which the bioaccesibility from real crumb rubber samples of 15 out of the 16 PAHs considered as priority pollutants by the United States Environmental Protection Agency (EPA) and the presence of 6PPD-quinone and HMMM in the bioaccessible fractions is reported.

A new monitoring approach for sustainability assessment of subsurface utilities gasket materials against gasoline and chlorinated solvents: Field evaluation and model development.

Once installed, underground concrete pipes with rubber gaskets might be exposed to contaminated soil and groundwater. A pipe material monitoring capsule (PMMC) has been developed to evaluate volatile organic compounds (VOCs) breaking through three types of pipe gaskets; Neoprene, Buna-N, and Viton. The PMMCs were deployed in three contaminated sites: two with gasoline and one with chlorinated solvent (CS). A 3-D field-domain numerical model has been developed for each site to calibrate equivalent hydraulic parameters of each gasket material (ke, D) against benzene and PCE diffusion. The calibrated parameters were then used to compute the concentrations as well as rate of breakthrough of the two study contaminants. A protocol was developed for installing/retrieval of PMMCs to monitor PCE and benzene mass breaking through the gasket material with time. Employing PMMC, benzene concentrations breaking through the Neoprene and Buna-N after 4 months were approximately 70% and 60% respectively of the monitoring wells concentration. The corresponding value for PCE breakthrough after 4 months was 60% for both the Neoprene and Buna-N. Both gasket materials of Neoprene and Buna-N yielded similar performances, including higher rate of contaminant breakthrough compared to Viton. A nonlinear relationship of mass breaking through the gaskets of benzene and PCE with time was discerned from the modeling and field data.

Recycling waste vehicle tyres into crumb rubber and the transition to renewable energy sources: A comprehensive life cycle assessment.

This study conducts a comprehensive life cycle assessment (LCA) on converting waste vehicle tyres into recycled crumb rubber (CR) granules as an alternative polymer for enhancing asphalt properties. The LCA study has been performed on acquired industrial primary data by incorporating CR at different proportions of binder in one ton (1-ton) of asphalt mix following the wet method. The uncertainty analysis of design variables identified a relatively strong positive relation of emissions with the equipment energy consumption (r = 0.98). Monte Carlo simulations evaluate the potential renewable sources (solar, hydro, and wind) in sequence over fossil fuels for the possible transition in the Australian grid by 2030 and 2050, as per the Paris Agreement. 71.91% reduction of CO2 emissions is achievable by recycling vehicle tyres into crumb rubber compared to landfill and incineration. Recycling by-products of CR production, such as steel and textile, significantly mitigates negative impacts. A decrease of 2.23% emissions was associated to the use of crumb rubber as a binder modifier in the asphalt mixture via the midpoint assessment. In endpoint LCA, a higher association of resource (US$) saving costs was observed than for other protective zones, i.e., human health and ecosystem damage. Recycling 466,000 tonnes of disposable waste tyres contributes to 16.1 million US$ worth of resource savings. An equitable industry-based LCA and uncertainty analysis of design parameters can assist in prioritizing suitable options to improve efficiency and future emission strategies on a global scale.

Safety assessment of charcoal usage and effects of common charcoal ignition aiders on combustion indices.

Charcoal is a popular form of biofuel embraced for domestic and industrial purposes. However, the use of Charcoal has some associated challenges, such as the required charcoal pot and setting it into the fire at first by using Charcoal-Ignition-Aiders (CIA) (e.g. discarded paper, nylon, rubber, plastics, petrol, the residue of processed palm oil, maise cob, wood, and kerosene). Coupled with the chemical properties of Charcoal, the resulting gases from CIA are capable of polluting the environment with perceived Adverse-Health-Implications (AHI) on the ecosystem. Therefore, this study conducted a safety assessment of charcoal biofuel usage and the effects of common CIA on combustion indices. This study followed standard methods and the use of peculiar equipment. This study established that Charcoal is commonly used in the studied area because it is cheap, readily available and requires less technical know-how. Considering the combustion indices, using paper as a CIA generated the lowest carbon monoxide (CO) value, 28.1 ppm, with 3,434.54 ppm volatile organic compound, VOC. Compared with the ACGIH standard permissible exposure level of ≤ 30 ppm, the paper gave a lesser CO value of 28.10 ppm among all the CIA. At the same time, all the CIA recorded higher VOC compared with EPA standard permissible exposure level of ≤ 15 ppm. ANOVA analysis conducted on the socio-demographic profile of the respondents, cooking attributes of the respondents, and use of charcoal pot types by the respondents in Zone 1, Zone 2, and Zone 3 gave p-values of 0.032, 0.028, and 0.039, respectively. These imply significant differences within the zones in each of the indices. The average energy content reported for charcoals sourced from oak trees, afara, obeche, mahogany, and iroko woods is 3,2149 kJ/kg compared to the lower ones. Therefore, this study recommended using these charcoals alongside discarded paper as CIA because they are a better combination to reduce AHI.

Estimation of air pollution tolerance and anticipated performance index of roadside plants along the national highway in a tropical urban city.

One of the most serious environmental issues is air pollution. Unlike other environmental concerns, this form of pollution is extremely challenging to regulate. The greenery of roadside trees plays a significant role in air purification and pollutant absorption, therefore helping to mitigate environmental pollution. Several plants can absorb and store toxins in their leaves from the atmosphere. Green plants have the potential to work as sinks and filters for air pollutants. Green belt development along national highways is a cost-effective and environmentally sustainable method of reducing air pollution. Sensitive and tolerant plants against air pollution can be identified by evaluating their air pollution tolerance index (APTI) and anticipated performance index (API) values. In this study, the susceptibility level of plant species to air pollution was assessed using APTI and API. The four parameters on which APTI depends are ascorbic acid content, total chlorophyll content, relative water content, and leaf extract pH. For the estimation of API, the plant's biological and socioeconomic factors like tree habit, canopy structure, type, size, texture, and hardness of the plant are also assessed. These parameters were determined and incorporated into a formula that represents the APTI and API of plants. Moreover, multilinear regression modeling was performed using a Statistical Package for the Social Sciences (SPSS, V25) and found that pH and ascorbic acid content in plant leaves have a significant role in the calculation of APTI and tolerance potential of plants. Therefore, APTI was assessed with seventeen plant species that are abundant in the area along the national highway in Kanpur, Uttar Pradesh, from Jan to Mar 2020. The APTI showed that Saraca asoca was the most resistant to air pollution, whereas Vachellia nilotica was the most sensitive. In addition, plants with higher APTI can also be used to reduce air pollution, while plants with lower APTI can be utilized to monitor air pollution. Based on the calculated API score, it is found that Ficus elastica (% score > 90) is the best option for green belt development. Urban local body (ULB) can also adopt Ficus religiosa, Saraca asoca, and Aucuba japonica (having % a grade score of 80-90) for mitigation of air pollution. The study indicates that plantations of tolerant species are useful for biomonitoring and developing green belts on and along national highways.

The migration of CO and PM under different working conditions of trackless rubber-tyred vehicle and health risk assessment of underground personnel.

Trackless rubber-tyred vehicles are among the most widely used underground auxiliary transportation equipment in major coal mines at present. The migration of exhaust gas that threaten human health varies with the working conditions of trackless rubber-tyred vehicles. In order to better evaluate the health risks faced by underground personnel in the process of exhaust emission from underground diesel vehicles, in this paper, the migration of carbon monoxide (CO) and particulate matter (PM) emitted by trackless rubber-tyred vehicle under three working conditions was analyzed by using the method of CFD (Computational Fluid Dynamics) numerical simulation and field measurement. It can be concluded that the concentrations of CO and PM changed with the change of airflow field under different working conditions, and their distribution tended to be consistent on the whole. Although the migration of CO and PM were different under different working conditions, CO with high concentration (C ≥ 44.74 ppm) and PM with high concentration (C ≥ 89.47 mg/m³) were mainly distributed in the area near the exhaust pipe of trackless rubber-tyred vehicle. Therefore, the drivers of trackless rubber-tyred vehicle and underground personnel need to comprehensively consider the risk factors under different working conditions when carrying out personal protection.

Turning lignin into treasure: An innovative filler comparable to commercial carbon black for the green development of the rubber industry.

Driven by the global carbon neutrality action, biomass-derived functional materials have been applied in many fields to alleviate the pressure brought by the depletion of fossil energy. However, due to the complex structure, lignin faces many difficulties in its high-value utilization. The second largest biomass in the world has become the largest "natural waste". In this paper, the lignin-based biochar-silica (LB-S) hybrid nanoparticles were prepared via a combination of two-step acid precipitation and carbonization using lignin black liquor extracted from xylose residue and sodium silicate as raw materials. The effects of carbonization temperature and lignin-based biochar (LB) content on the reinforcing properties of LB-S were studied. The results show that the particle size, specific surface area, pore characteristics, and surface polarity of LB-S all affect the mechanical properties of the final vulcanizates. The reinforcement performance of the best sample (LMB500-S) with "high structure" characteristics can be comparable to that of commercial carbon black (CB) N550. This study shows that LMB500-S hybrid nanoparticles with economic benefits possess the potential to completely replace commercial CB, which can turn lignin waste into treasure and promote the green development of traditional rubber industry in the context of carbon neutrality.

Thermo-soil weathering and life cycle assessment of carbon black, silica and cellulose nanocrystal filled rubber nanocomposites.

Carbon black (CB) and silica (Sil) as rubber reinforcement have raised environmental concerns for being high resources consumptive and less susceptible towards biodegradability. Cellulose nanocrystal (CNC) has demonstrated great potentials for use as biodegradable nanofillers in rubber nanocomposites while evaluation of its environmental impacts with optimal end-of-life (EOL) choices is not carried out. To simulate realistic EOL, thermo-oxidative aging and soil burial aging behaviors of rubber nanocomposites with 33.3% filler were performed. The environmental weathering performance modeled with the help of life cycle assessment (LCA) illustrates increased biodegradation susceptibility with partial replacement of CB or Sil with CNC in the nanocomposites, hence promoting the environmental solutions for waste minimalization by enhancing the biodegradability potentials. In terms of LCA, the CNC incorporation contributes more to the environmental impacts in manufacturing but greatly lowers the EOL choices, by reducing the global warming potential values.

Presence of metals and metalloids in crumb rubber used as infill of worldwide synthetic turf pitches: Exposure and risk assessment.

Crumb rubber derived from end-of-life tires (ELTs) is frequently used as infill of synthetic turf pitches, promoting circular economy. Although important to reduce the accumulation of waste, the use of recycled ELTs can be a problem to human health and the environment, both by direct contact during pitch use and by the release of these elements to the surroundings, mostly via volatilization and leaching. The present study aimed to evaluate the distribution of metals in ELT-derived crumb rubber collected in artificial turf worldwide and assess possible trends by country, pitch age and type (indoor vs. outdoor). The concentration ranges observed are very wide, especially in outdoor fields and for the most abundant metals, namely Zn (2989-5246 mg/kg), Fe (196-5194 mg/kg), Mg (188-1795 mg/kg) and Al (159-1882 mg/kg). For Zn, the levels were mostly above the safe limits set in European directives for relatable matrices (soils and toy materials), and the same happened for Pb, a much more toxic metal at lower concentrations. A multi-pathway human exposure study was also performed, and the risk assessment shows non-carcinogenic and carcinogenic risks from accidental crumb rubber ingestion (with Cr and Pb as major contributors) above the acceptable values for all the receptors except adult bystanders, with a higher significance to younger individuals. These results bring a different perspective regarding most of the studies reporting low risks related with exposure to metals in crumb rubber.

Comparative analysis of the characteristics of carbonaceous material obtained via single-staged steam pyrolysis of waste tires.

The two-stage technology of porous carbonaceous material obtained via pyrolysis in inert medium with subsequent activation by steam is well known. While steam could be a suitable substance for pyrolysis as well, single-staged technology for waste tire recycling is yet to be developed. A comparative analysis of the characteristics of the carbonaceous materials obtained by the single-staged steam pyrolysis of waste tires was carried out, which could provide a theoretical background for the development of such technology. The steam pyrolysis was performed in a tubular reactor in an overheated steam medium (500°C with 5 kg/h mass flow rate). The technical characteristics of the obtained samples were evaluated in the context of their potential for further application as absorbent and raw material for rubber production according to Chemical Abstracts Service No. 1333-86-4. The composition and physico-chemical properties of the obtained samples were studied using BET and thermogravimetric analysis, atomic emission, transmission and scanning electron microscopies, Raman, X-ray diffraction, and photoelectron spectroscopies. The results revealed that the structure and properties of all obtained carbonaceous material samples were similar. The samples consisted of amorphous carbon (with a disordered graphite lattice) and contained a significant amount of metal oxides. According to experimental data, zinc was present in the form of ZnO with a binding energy of 1022.4 eV, while sulfur was observed in the form of sulfide and oxysulfide with binding energies of 161.8 and 163.2 eV, respectively. According to electron microscopy, the morphology of samples was represented by a set of spherical agglomerates comprising nanosized particles. According to the BET analysis of the samples, the specific surface area varied in the range between 52.0 and 66.0 m2/g and the pore volume values were within a range of 0.53-0.87 cm3/g, while the average pore size varied from 412 to 527 Å.Implications: Our paper presents original research in the field of characterization of solid material obtained by single-staged steam gasification of waste tires, which were produced and exploited in conditions of Russia. Modern technology allows thermal utilization of waste tires by obtaining powders of carbonaceous material, which could be used as fuel, adsorbent, etc., but this process usually consists of two stages - pyrolysis in inert medium and activation in steam or carbon dioxide. One of the most promising directions of technological development is simplifying this process into single step, ensuring that the obtained material could be used as carbon black or adsorbent for gas steam cleansing. No data on suitability of carbonaceous material obtained by single-step steam pyrolysis of all-season waste tires to be adsorbent and/or carbon black is present in the literature. In order to evaluate the suitability of the obtained material to be adsorbent, the high specific surface area should be determined, while CAS technical standards specify many chemical and physical properties of industrial carbon black.The aim of the current article is to study the properties of carbonaceous material obtained during single-staged steam gasification of four different all-season tires (due to their widespread application worldwide) and evaluate its fitness as industrial-scale carbon black or adsorbent. The additional problem addressed was the evaluation of the variation in characteristics of carbonaceous material obtained due to different origins of tires. Experiments were conducted in a tubular lab reactor in order to simplify the experimental procedure while ensuring the applicability of the obtained results to practical conditions.The obtained results could be used for the development of the technology for closed-cycle tire processing (because black carbon is used for tire production) and adsorbent production. The characteristics of the materials obtained allow us to choose optimal parameters for such treatment and develop special policies and programs, which will integrate and regulate waste tire utilization via steam gasification.