RESUMO
Currently, the world faces an existential threat of climate change, and every government across the globe is trying to come up with strategies to tackle the severity of climate change in every way possible. To this end, the use of clean energy rather than fossil fuel energy sources is critical, as it can reduce greenhouse gas emissions and pave the way for carbon neutrality. This study examines the impact of the energy cleanability gap on four different climate vulnerabilities, such as ecosystem, food, health, and housing vulnerabilities, considering 47 European and non-European high-income countries. The study considers samples from 2002 to 2019. This study precedes the empirical analysis in the context of a quadratic relationship between the energy cleanability gap and climate vulnerability. The study uses system-generalized methods of the moment as the main technique, while panel quantile regression is a robustness analysis. Fixed effect and random effect models have also been incorporated. The study finds that the energy cleanability gap and all four climate vulnerabilities demonstrate a U-shaped relationship in both European and non-European countries, implying that when the energy cleanability gap increases, climate vulnerability decreases, but after reaching a certain threshold, it starts to increase. Development expenditure is found to be negatively affecting food and health vulnerabilities in European nations, while it increases food vulnerability and decreases health vulnerability in non-European nations. Regarding industrialization's impact on climate vulnerabilities, the study finds opposite effects for the European and non-European economies. On the other hand, for both groups, trade openness decreases climate vulnerabilities. Based on these results, the study recommends speeding up the energy transition process from fossil fuel energy resources towards clean energy resources to obtain carbon neutrality in both European and non-European groups.
Assuntos
Ecossistema , Gases de Efeito Estufa , Países Desenvolvidos , Gases de Efeito Estufa/análise , Desenvolvimento Econômico , Combustíveis Fósseis/análise , Carbono/análise , Dióxido de Carbono/análise , Energia RenovávelRESUMO
This study explores the viability of utilizing municipal solid waste (MSW) and legacy waste as a renewable energy source through pyrolysis, akin to solid fuels. The heating value of MSW and legacy waste were found to be 37737.89 and 40432.84 kJ/kg, respectively. Proximate analysis shows that MSW fits within Tanner diagram parameters, eliminating the need for auxiliary fuel in pyrolysis. With 47.6 % and 44.16 % lignin content in MSW and legacy waste were deemed suitable for char production. Thermal degradation resulted in mass losses of 68 % for MSW and 82 % for legacy waste. The kinetic and thermodynamic assessment indicates lower activation energy (Ea) and Gibbs free energy (ΔG) for MSW (5.72 kJ/mol and 170.37 kJ/mol, respectively) compared to fossil fuels, suggesting faster reactions without additional energy requirement. MSW emerges as a promising alternative to fossil fuels, aligning with the United Nations' 2030 Sustainable Development Goals.
Assuntos
Eliminação de Resíduos , Resíduos Sólidos , Resíduos Sólidos/análise , Pirólise , Fontes Geradoras de Energia , Energia Renovável , Combustíveis Fósseis/análiseRESUMO
The Sustainable system-of-systems (SSoS) approach, complemented with econometric analysis was used to address China's decarbonisation problem, i.e. selecting fossil fuel consumption sources to be reduced in various regions to meet CO2 reduction targets with minimal effect on population and economic growth. In the SSoS, the micro-level system is represented by residents' health expenditure, the meso-level system by industry's CO2 emissions intensity, and the macro-level system by the government's achievement of economic growth. Regional panel data from 2009 to 2019 were used in an econometric analysis conducted using structural equation modelling. The results show that health expenditure was affected by CO2 emissions from the consumption of raw coal and natural gas. To support economic growth, the government should reduce raw coal consumption. For CO2 emissions reduction, industry in the eastern region should reduce raw coal consumption. The key advantage is SSoS with econometrics offers a way to reach a common goal among stakeholders.Practitioner summary: This research shows that the use of the SSoS approach, complemented with an econometric analysis of key social, economic, and natural capital data, can address a complex decarbonisation problem facing a nation (China, in the present case) while considering the goals of all stakeholders (the government, industrial communities, and residential communities).Abbreviations: CEADs: Carbon Emissions Accounts and Datasets for Emerging Countries; CEIC: CEIC Global Database; GRPS: World Economic Forum's Global Risks Perception Survey; HFE: human factors/ergonomics; ML-SEM: maximum likelihood estimation method; NDRC: National Development and Reform Commission of China; SEM: structural equation modelling; SSoS: Sustainable system-of-systems; TBL: triple bottom line.
Assuntos
Dióxido de Carbono , Combustíveis Fósseis , Humanos , Dióxido de Carbono/análise , Combustíveis Fósseis/análise , Carvão Mineral/análise , China , Análise de SistemasRESUMO
This analysis explores the complicated relationship between oil price fluctuations, the oil industry's finances, and the resulting increase or decrease in carbon emissions. Oil price changes have far-reaching effects on the global economy because of its dependence on fossil fuels; therefore, understanding these patterns is essential for effective policymaking and long-term energy planning. The study uses a dataset built from secondary data collected in China over 15 years, starting in 2008 and ending in 2022. This information comes from a wide range of authoritative places, including public records, trade journals, university studies, and the records of international organizations, and provides a solid foundation for study. Oil prices on a global and national scale, oil sector financial performance indicators (such as revenues, earnings, and investment levels), and carbon emission statistics are all significant factors under investigation. As one of the world's largest oil consumers, China has been singled out in this study to allow for a more comprehensive analysis of reactions within this crucial subset of the energy industry. To understand the complex interplay between oil price shocks, the financial dynamics of the oil sector, and carbon emissions, the research utilizes statistical and econometric methods, most notably time-series analysis and regression models. The results are meant to shed light on how oil price shocks consistently affect the monetary aspects of the oil business and, by extension, the patterns in carbon emissions. This study helps us understand these vital interrelationships more completely and nuancedly.
Assuntos
Carbono , Indústrias , Humanos , Carbono/análise , Combustíveis Fósseis/análise , Comércio , China , Dióxido de Carbono/análiseRESUMO
Material footprint is vital for playing a role in increasing the pace of climate change and the sustainability of development efforts. Fossil fuels material footprint (FFMF) remains a critical indicator of environment-friendly economic development. Fossil fuels have also retained their dominance as prominent drivers of global growth since the Industrial Revolution. FFMF levels show considerable variations in economic growth worldwide as awareness of sustainability and climate change propagates. Although biomass/carbon emission convergence have been discussed extensively in the existing literature, FFMF convergence is still scanty despite its vital role in climate change. Hence, this study adds to the existing literature by examining the convergence of FFMF for 154 countries for the period from 1970 to 2019 using club convergence analysis. The results show that FFMF converges to a single steady state, stating a symmetric decline in FFMF growth. Further, the findings from sigma and beta tests are consistent with the main results. Thus, the demonstrated convergence of FFMF directs that global efforts regarding FFMF control should be continued. Moreover, future climate change policies should also be formulated to enhance the awareness of FFMF and long-term sustainability.
Assuntos
Mudança Climática , Combustíveis Fósseis , Combustíveis Fósseis/análise , Dióxido de Carbono/análise , Desenvolvimento EconômicoRESUMO
This study investigates the impact of renewable and non-renewable energy sources on carbon emissions in the context of China's 14th Five-Year Plan (2021-2025). The plan emphasises a "Dual-control" strategy of simultaneously setting energy consumption limits and reducing energy intensity for GDP (gross domestic product) in order to meet the targets of the five-year plan. Using a comprehensive dataset of Chinese energy and macroeconomic information spanning from 1990 to 2022, we conduct a Granger causality analysis to explore the relationship between energy sources and the level of air pollution. Our findings reveal a unidirectional link, wherein renewable energy contributes to a reduction in air pollution, while non-renewable energy sources lead to an increase. Despite the government's investment in renewable energy, our results show that China's economy remains heavily reliant on traditional energy sources (e.g., fossil fuels). This research is the first systematic examination of the interplay between energy usage and carbon emissions in the Chinese context. Our findings provide valuable insights for policy and market strategies aimed at promoting carbon neutrality and driving technological advancements in both government and industries.
Assuntos
Poluição do Ar , Carbono , Carbono/análise , Poluição do Ar/análise , Energia Renovável , Fontes Geradoras de Energia , Combustíveis Fósseis/análise , China , Dióxido de Carbono/análise , Desenvolvimento EconômicoRESUMO
To clarify the impact of human activities on the natural environment, as well as the current ecological risks to the environment surrounding Zhushan Bay in Taihu Lake, the characteristics of deposited organic materials, including elements and 16 polycyclic aromatic hydrocarbons (∑16PAHs), in a sediment core from Taihu Lake were determined. The nitrogen (N), carbon (C), hydrogen (H), and sulfur (S) contents ranged from 0.08 to 0.3%, 0.83 to 3.6%, 0.63 to 1.12%, and 0.02 to 0.24%, respectively. The most abundant element in the core was C followed by H, S, and N, while elemental C and the C/H ratio displayed a decreasing trend with depth. The ∑16PAH concentration was in the range of 1807.48-4674.83 ng g-1, showing a downward trend with depth, with some fluctuations. Three-ring PAHs dominated in surface sediment, while 5-ring PAHs dominated at a depth of 55-93 cm. Six-ring PAHs appeared in the 1830s and gradually increased over time before slowly decreasing from 2005 onward due to the establishment of environmental protection measures. The ratio of PAH monomers indicated that PAHs in samples from a depth of 0 to 55 cm were mainly derived from the combustion of liquid fossil fuels, while the PAHs in the deeper samples mainly originated from petroleum. The results of a principal component analysis (PCA) showed that the PAHs in the sediment core of Taihu Lake were mainly derived from the combustion of fossil fuels, such as diesel, petroleum, gasoline, and coal. The contributions of biomass combustion, liquid fossil fuel combustion, coal combustion, and unknown source were 8.99%, 52.68%, 1.65%, and 36.68%, respectively. The results of a toxicity analysis indicated that most of the PAH monomers had little impact on the ecology, and the annual increase of a small number of monomers might have toxic effects on the biological community, resulting in a serious ecological risks, that requires the imposition of control measures.
Assuntos
Poluentes Ambientais , Petróleo , Hidrocarbonetos Policíclicos Aromáticos , Poluentes Químicos da Água , Humanos , Poluentes Ambientais/análise , Poluentes Químicos da Água/análise , Monitoramento Ambiental/métodos , Sedimentos Geológicos/análise , China , Combustíveis Fósseis/análise , Petróleo/análise , Carvão Mineral/análise , Medição de Risco , Hidrocarbonetos Policíclicos Aromáticos/análise , Lagos/análiseRESUMO
China's carbon emissions account for approximately a quarter of the world's total greenhouse gas emissions. In 2020, China's fossil fuels accounted for approximately 85% of the primary energy demand, with coal alone accounting for 60%. Considering the severe global warming situation, it is necessary to reveal the spatial and temporal differences and analyze the spillover effects of carbon emissions between regions. In this study, a positive and significant spatial correlation between regional carbon emissions in China was found using an exploratory spatial data analysis. The spatial Durbin model was then utilized to explore the direct and spillover effects of factors that included economic growth, the energy intensity, and the level of technological innovation on regional carbon emissions. Whether a direct effect or a spillover effect, economic growth and improvements in the regional levels of technological innovation had significant inhibitory effects on carbon emissions both in the long term and in the short term. Specifically, an increase of 1% in the level of technological innovation led to a reduction of approximately 0.17% in the region's carbon emissions. However, a growth in the energy intensity will increase carbon emissions. In addition, an increase in the technological input intensity will lead to an increase in carbon emissions in local regions. However, an increase in neighboring regions will restrain carbon emissions in a local region. Based on these findings, it is recommended that the government accelerate regional innovation synergies and increase investment in clean energy technologies.
Assuntos
Carbono , Gases de Efeito Estufa , Carbono/análise , Dióxido de Carbono/análise , Desenvolvimento Econômico , Combustíveis Fósseis/análise , Gases de Efeito Estufa/análise , ChinaRESUMO
There are many advantages of geothermal energy, as an environmental friend resource. This heat radiation emanating from beneath the earth's surface presents man with good opportunities to harness it and makes a good level of agricultural food production and its processing in the EU region. The primary objective of this research is to examine the impact of geothermal energy on agri-food supply among the 27 European countries (EU27), within the time frame 1990 to 2021. The study adopted the autoregressive distributed lag (ARDL), and the findings from this study revealed that agri-food supply can increase significantly among the 13 European countries (EU13 emerging economies), leveraging on geothermal energy and economic growth variables than in the EU14 emerged economies. Furthermore, the outcome of this study showed that there could be a significant decrease in the food products coming from agricultural practices among the 13 European countries (EU13 emerging economies), due to an ineffective population density than in EU14 emerged economies. Furthermore, fossil fuel and institutional quality contribute more positively to the agri-food supply in the EU14 emerged economies than in the EU13 emerging economies. This results in an outcome that means that the agri-food supply among the EU13 emerging economies could be greatly boosted by replacing fossil fuel consumption with geothermal energy, and this facilitates the attainment of the European energy goals by the year 2030. Substituting fossil fuels with geothermal will also assist in minimizing the risks of environmental pollution and climate change. All projected calculations were seen as valid in this study, and this was confirmed by the three estimators adopted which are the pooled mean group, the mean group, and the dynamic fixed effect. This study, therefore, recommends that the 27 European countries should lay more emphasis on geothermal energy production as this will help in ensuring food security in the region. Policymakers and other government authorities as well as local and foreign investors should make more investments in geothermal energy resources as this study has proven that this will lead to agri-food security and sustainability. Not only this, it will as well curb the incidence of climate change and environmental pollution.
Assuntos
Energia Geotérmica , Humanos , Poluição Ambiental/análise , Desenvolvimento Econômico , Combustíveis Fósseis/análise , Segurança Alimentar , Dióxido de Carbono/análise , Energia RenovávelRESUMO
Agrowaste sources can be utilized to produce biogas by anaerobic digestion reaction. Fossil fuels have damaged the environment, while the biogas rectifies the issues related to the environment and climate change problems. Techno-economic analysis of biogas production is followed by nutrient recycling, reducing the greenhouse gas level, biorefinery purpose, and global warming effect. In addition, biogas production is mediated by different metabolic reactions, the usage of different microorganisms, purification process, upgrading process and removal of CO2 from the gas mixture techniques. This review focuses on pre-treatment, usage of waste, production methods and application besides summarizing recent advancements in biogas production. Economical, technical, environmental properties and factors affecting biogas production as well as the future perspective of bioenergy are highlighted in the review. Among all agro-industrial wastes, sugarcane straw produced 94% of the biogas. In the future, to overcome all the problems related to biogas production and modify the production process.
Assuntos
Biocombustíveis , Gases de Efeito Estufa , Anaerobiose , Biocombustíveis/análise , Dióxido de Carbono/análise , Combustíveis Fósseis/análise , Gases de Efeito Estufa/análise , Resíduos Industriais/análise , Metano/análiseRESUMO
For nations already facing pollution issues, fossil fuel energy consumption is deteriorating living standards. Though prevailing infrastructure makes fossil fuel energy use feasible for production, it still pollutes our environment. This study in the domain of environment and development assesses the impact of fossil fuel energy consumption on the infant mortality rate in 15 Asian economies during 1996 and 2019. The living standards are assessed using infant mortality rate, while non-linear fossil fuel energy consumption is used with gross capital formation, employment, and preprimary education as independent variables. The feasible generalized least square method evaluates the effects. The study concludes that fossil fuel energy consumption follows a U-shaped relationship explaining infant mortality. The results point out that over-consumption of fossil fuel energy is deteriorating the living standards considering low air quality levels in Asian economies.
Assuntos
Poluição do Ar , Combustíveis Fósseis , Poluição do Ar/análise , Dióxido de Carbono/análise , Desenvolvimento Econômico , Fontes Geradoras de Energia , Combustíveis Fósseis/análise , Humanos , Mortalidade Infantil , Energia RenovávelRESUMO
Fossil fuel (FF) combustion emissions account for a large, but uncertain, amount of the soot in the atmosphere, play an important role in climate change, and adversely affect human health. However, historical estimates of FF contributions to air pollution are limited by uncertainties in fuel usage and emission factors. Here, we constrained FF soot emissions from southeastern China over the past 110 years, based on a novel radiocarbon method applied to sedimentary soot. The reconstructed soot accumulations reflect the integrated effects of increased FF use caused by economic development and reductions in emissions due to pollution controls. A sharp increase in FF soot started in 1950 as southeastern China industrialized and developed economically, but decreased FF soot fluxes in recent years suggest that pollution controls reduced soot emissions. We compare FF soot history to changes in CO2 emissions, industrial and economic activities, and pollution controls and show that FF soot fluxes are more readily controlled than atmospheric CO2. Our independent FF soot record provides insights into the effects of economic development and controls on air pollution and the environmental impacts from the changes in soot emissions.
Assuntos
Combustíveis Fósseis , Fuligem , Carbono/análise , Dióxido de Carbono , China , Monitoramento Ambiental/métodos , Combustíveis Fósseis/análise , Humanos , Fuligem/análiseRESUMO
In this study, the sedimentary records, sources, and ecological risks of polycyclic aromatic hydrocarbons (PAHs) in Dianchi Lake were analyzed. The concentrations of ΣPAH16 in the sediments of Dianchi Lake ranged from 368 to 990 ng/g, with an average value of 572 ng/g, peaking in 1988. Economic development, rapid population growth, and rapid growth of coal consumption have a greater impact on the HMW (high molecular weight) PAHs than on the LMW (low molecular weight) PAHs in the sedimentary environment. The results of the diagnostic ratios and PCA (principal component analysis) model show that the main sources of PAHs were coal and biomass combustion, as well as the fossil fuel combustion in individual years. The risk assessment results showed that the PAH concentrations in the sediment were within a safe range. In the past 100 years of sediment pore water, other 2-3 ring LMW PAHs were within a safe range (except for Phe, which reached chronic toxic pollution levels in some years). With an increase in industrialization and urbanization, the burning of fossil fuels such as coal and petroleum has increased, and some of the 4-6 ring HMW PAHs have reached chronic toxicity or even acute toxicity in the sediment pore water.
Assuntos
Hidrocarbonetos Policíclicos Aromáticos , Poluentes Químicos da Água , China , Carvão Mineral/análise , Monitoramento Ambiental/métodos , Combustíveis Fósseis/análise , Sedimentos Geológicos/análise , Lagos/análise , Hidrocarbonetos Policíclicos Aromáticos/análise , Medição de Risco , Água/análise , Poluentes Químicos da Água/análiseRESUMO
Recent studies conclude that the global coronavirus (COVID-19) pandemic decreased power sector CO2 emissions globally and in the United States. In this paper, we analyze the statistical significance of CO2 emissions reductions in the U.S. power sector from March through December 2020. We use Gaussian process (GP) regression to assess whether CO2 emissions reductions would have occurred with reasonable probability in the absence of COVID-19 considering uncertainty due to factors unrelated to the pandemic and adjusting for weather, seasonality, and recent emissions trends. We find that monthly CO2 emissions reductions are only statistically significant in April and May 2020 considering hypothesis tests at 5% significance levels. Separately, we consider the potential impact of COVID-19 on coal-fired power plant retirements through 2022. We find that only a small percentage of U.S. coal power plants are at risk of retirement due to a possible COVID-19-related sustained reduction in electricity demand and prices. We observe and anticipate a return to pre-COVID-19 CO2 emissions in the U.S. power sector.
Assuntos
COVID-19/epidemiologia , Centrais Elétricas/estatística & dados numéricos , Poluentes Atmosféricos/análise , Dióxido de Carbono/análise , Clima , Carvão Mineral/análise , Carvão Mineral/economia , Eletricidade , Combustíveis Fósseis/análise , Humanos , Centrais Elétricas/economia , Centrais Elétricas/tendências , SARS-CoV-2 , Estados Unidos/epidemiologiaRESUMO
The COVID-19 pandemic is impacting human activities, and in turn energy use and carbon dioxide (CO2) emissions. Here we present daily estimates of country-level CO2 emissions for different sectors based on near-real-time activity data. The key result is an abrupt 8.8% decrease in global CO2 emissions (-1551 Mt CO2) in the first half of 2020 compared to the same period in 2019. The magnitude of this decrease is larger than during previous economic downturns or World War II. The timing of emissions decreases corresponds to lockdown measures in each country. By July 1st, the pandemic's effects on global emissions diminished as lockdown restrictions relaxed and some economic activities restarted, especially in China and several European countries, but substantial differences persist between countries, with continuing emission declines in the U.S. where coronavirus cases are still increasing substantially.
Assuntos
Poluentes Atmosféricos/análise , Dióxido de Carbono/análise , Infecções por Coronavirus/epidemiologia , Pneumonia Viral/epidemiologia , Poluentes Atmosféricos/economia , Betacoronavirus , COVID-19 , Dióxido de Carbono/economia , Infecções por Coronavirus/economia , Infecções por Coronavirus/prevenção & controle , Monitoramento Ambiental , Combustíveis Fósseis/análise , Combustíveis Fósseis/economia , Humanos , Indústrias/economia , Dióxido de Nitrogênio/análise , Dióxido de Nitrogênio/economia , Pandemias/economia , Pandemias/prevenção & controle , Pneumonia Viral/economia , Pneumonia Viral/prevenção & controle , SARS-CoV-2Assuntos
Poluição do Ar/prevenção & controle , Infecções por Coronavirus , Pandemias , Pneumonia Viral , Poluentes Atmosféricos/análise , Poluição do Ar/economia , Poluição do Ar/estatística & dados numéricos , Betacoronavirus , COVID-19 , Infecções por Coronavirus/epidemiologia , Infecções por Coronavirus/prevenção & controle , Análise Custo-Benefício , Combustíveis Fósseis/análise , Combustíveis Fósseis/economia , Humanos , Desenvolvimento Industrial/tendências , Pandemias/prevenção & controle , Pneumonia Viral/epidemiologia , Pneumonia Viral/prevenção & controle , Energia Renovável/economia , SARS-CoV-2 , Planejamento SocialRESUMO
Ambient air monitoring and phone survey data were collected in three environmental justice (EJ) and three non-EJ communities in Sacramento County during winter 2016-2017 to understand the differences in air toxics and in wood smoke pollution among communities. Concentrations of six hazardous air pollutants (HAPs) and black carbon (BC) from fossil fuel (BCff) were significantly higher at EJ communities versus non-EJ communities. BC from wood burning (BCwb) was significantly higher at non-EJ communities. Correlation analysis indicated that the six HAPs were predominantly from fossil fuel combustion sources, not from wood burning. The HAPs were moderately variable across sites (coefficient of divergence (COD) range of 0.07 for carbon tetrachloride to 0.28 for m- and p-xylenes), while BCff and BCwb were highly variable (COD values of 0.46 and 0.50). The BCwb was well correlated with levoglucosan (R2 of 0.68 to 0.95), indicating that BCwb was a robust indicator for wood burning. At the two permanent monitoring sites, wood burning comprised 29-39% of the fine particulate matter (PM2.5) on nights when PM2.5 concentrations were forecasted to be high. Phone survey data were consistent with study measurements; the only significant difference in the survey results among communities were that non-EJ residents burn with indoor devices more often than EJ residents.
Assuntos
Poluentes Atmosféricos/análise , Poluição do Ar/estatística & dados numéricos , Monitoramento Ambiental , Combustíveis Fósseis/análise , Material Particulado/análise , Fumaça/análise , Madeira , Poluição do Ar/análise , California , Monitoramento Ambiental/métodos , Calefação/métodos , Calefação/estatística & dados numéricos , Humanos , Estações do Ano , Inquéritos e QuestionáriosRESUMO
Using the extended STIRPAT model, this research examines the influence of various factors on China carbon emission from 1971 to 2014, including total nuclear and alternative energy, total fossil energy, GDP per capita, total population, total urban population, merchandise trade of GDP, and services value added of GDP. Ridge regression was employed to perform the study. The research results show the positivity and significance of all factors on carbon emission. The estimated elastic coefficients reveal the most important factor influencing carbon emission is GDP per capita. Total fossil energy, total urban population, and nuclear energy of total energy use are also prominent influencing factors, while other factors such as value-added services of GDP and merchandise trade of GDP have less significant impacts on carbon emission in China. These findings of the research will be of great significance for China to control its carbon emission in the future and to mitigate global warming to some extent.
Assuntos
Dióxido de Carbono/análise , Conservação de Recursos Energéticos/economia , Desenvolvimento Econômico , Combustíveis Fósseis/análise , Modelos Teóricos , China , Produto Interno Bruto , Energia Nuclear/economia , Energia Renovável/economia , UrbanizaçãoRESUMO
In this study, nine congeners of polybrominated diphenyl ethers (PBDEs) and sixteen congeners of polycyclic aromatic hydrocarbons (PAHs) were measured in water samples to elucidate their spatial distribution, congener profiles, sources and ecological risks in the Guanlan River during both the dry season (DS) and the wet season (WS). The concentration of Σ9PBDE ranged from 58.40 to 186.35â¯ng/L with an average of 115.72â¯ng/L in the DS, and from 8.20 to 37.80â¯ng/L with an average of 22.15â¯ng/L in the WS. Meanwhile, the concentration of Σ16PAHs was ranged from 121.80 to 8371.70â¯ng/L with an average of 3271.18â¯ng/L in the DS and from 1.85 to 7124.25â¯ng/L with an average of 908.11â¯ng/L in the WS. The concentrations of PBDEs and PAHs in the DS were significantly higher than those in the WS, probably due to the dilution of the river during the rainy season. Moreover, the spatial distribution of pollutants revealed decreasing trend in the concentration from upstream to downstream and almost identical pattern was observed during both seasons. The source apportionment suggested that penta-BDE and to some extent octa-BDE commercial products were major sources of PBDEs in the study area. However, the sources of PAHs were mainly comprised of fossil fuels and biomass burning, followed by the petroleum products and their mixtures. The results of the ecological risk assessment indicated PBDEs contamination posed high ecological risks, while PAHs exhibited low or no ecological risks in the study area. Consistent with the environmental levels, the ecological risks of pollutants were relatively lower in the WS, compared to that in the DS. The results from this study would provide valuable baseline data and technical support for policy makers to protect the ecological environment of the Guanlan River.
Assuntos
Monitoramento Ambiental/métodos , Éteres Difenil Halogenados/análise , Hidrocarbonetos Policíclicos Aromáticos/análise , Rios/química , Poluentes Químicos da Água/análise , China , Combustíveis Fósseis/análise , Sedimentos Geológicos/química , Petróleo/análise , Medição de Risco , Estações do Ano , Análise Espaço-Temporal , UrbanizaçãoRESUMO
This paper presents a demonstration of an integrated risk assessment and site investigation for groundwater contamination through a case study, in which the geologic and hydrogeological feature of the site and the blueprint of the fossil power plant (FPP) were closely analyzed. Predictions for groundwater contamination in case of accidents were performed by groundwater modeling system (GMS) and modular three-dimensional multispecies transport model (MT3DMS). Results indicate that the studied site area presents a semi-isolated hydrogeological unit with multiplicity in stratum lithology, the main aquifers at the site are consisted of the filled karst development layer with a thickness between 6.0 and 40.0 m. The poor permeability of the vadose zone at the FPP significantly restricted the infiltration of contaminants through the vadose zone to the subsurface. The limited influence of rarely isotropic porous karstified carbonate rocks on the groundwater flow system premised the simulate scenarios of plume migration. Analysis of the present groundwater chemistry manifested that that the groundwater at the site and the local area are of the HCO3-Ca, HCO3, and SO4-Ca types. A few of the water samples were contaminated by coliform bacteria and ammonia nitrogen as a result of the local cultivation. Prediction results indicate that the impact of normal construction and operation processes on the groundwater environment is negligible. However, groundwater may be partly contaminated within a certain period in the area of leakage from the diesel tanks, the industrial wastewater pool, and the cooling tower water tank in case of accidents. On a positive note, none of the plumes would reach the local sensitive areas for groundwater using. Finally, an anti-seepage scheme and a monitoring program are proposed to safeguard the groundwater protection. The integrated method of the site investigation and risk assessment used in this case study can facilitate the protection of groundwater for the construction of large-scale industrial project.