Your browser doesn't support javascript.
loading
Mostrar: 20 | 50 | 100
Resultados 1 - 20 de 411
Filtrar
Mais filtros

Intervalo de ano de publicação
1.
Food Chem ; 451: 139475, 2024 Sep 01.
Artigo em Inglês | MEDLINE | ID: mdl-38678648

RESUMO

In this work, we aimed to evaluate human intake of triclosan (TCS) associated with real-life use of different brands of Microban™ microwave-safe food packaging. Calculations were based on: TCS migration data (under the worst-case foreseeable conditions), MPs abundance and TCS bioaccessibility from microplastics (MPs), leached from containers under microwave heating. Bioaccessibility studies were performed with in vitro digestion of MPs, followed by liquid-liquid extraction of TCS from digestive fluids and LC-QqQ-MS analysis yielding values of 46 ± 9%. The estimated weekly intake (EWI) of TCS ranged between 11 and 42 µg/kg body weight/week, with migration being the largest contribution (0.6-2.3 mg/week), compared to leaching of MPs (75-300 µg/week). These values represent a significant source of human exposure to TCS, emphasizing the need to harmonize the ban of TCS in food contact materials worldwide and improve compliance testing of food contact articles, particularly those marketed through online sales platforms.


Assuntos
Embalagem de Alimentos , Polipropilenos , Triclosan , Triclosan/análise , Triclosan/química , Embalagem de Alimentos/instrumentação , Humanos , Polipropilenos/química , Contaminação de Alimentos/análise , Exposição Dietética/análise
2.
Adv Food Nutr Res ; 108: 135-177, 2024.
Artigo em Inglês | MEDLINE | ID: mdl-38460998

RESUMO

Packaging is fundamental to maintaining the quality of food, but its contribution with a negative footprint to the environment must be completely changed worldwide to reduce pollution and climate change. Innovative and sustainable packaging and new strategies of reutilization are necessary to reduce plastic waste accumulation, maintain food quality and safety, and reduce food losses and waste. The purpose of this chapter is to present innovations in food packaging for a sustainable and circular economy. First, to present the eco-design packaging approach as well as new strategies for recycled or recyclable materials in food packaging. Second, to show current trends in new packaging materials developed from the use of agro-industrial wastes as well as new methods of production, including 3D/4D printing, electrostatic spinning, and the use of nanomaterials.


Assuntos
Embalagem de Alimentos , Nanoestruturas , Reciclagem , Alimentos , Resíduos Industriais
3.
NanoImpact ; 34: 100503, 2024 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-38514026

RESUMO

TiO2 is the most widely used white pigment in plastics and food packaging industry, thus the question of its migration towards food and hence the impact on consumers is raised. Since recent research indicate its potential toxicity, it is necessary to study TiO2 contamination as a consequence of food storage. For this purpose, plastic containers from commercially-available dairy products and custom-made TiO2-spiked polypropylene materials were put in contact with 50% (v/v) ethanol and 3% (w/v) acetic acid, which were used here as food simulants. The migration assays were carried out under standard contact conditions of packaging use (as recommended by Commission Regulation (EU) N° 10/2011 for food contact migration testing), and under conditions of extreme mechanical degradation of the packaging. The TiO2 (nano)particles released in the food simulants were analysed by single particle inductively coupled plasma-tandem mass spectrometry in mass-shift mode and using a high efficiency sample introduction system (APEX™ Ω) to avoid matrix effects from food simulants. For the dairy product containers and for the spiked polypropylene, results showed release of TiO2 particles of rather large sizes (average size: 164 and 175 nm, respectively) under mechanical degradation conditions, i.e. when the polymeric structure is damaged. The highest amounts of TiO2 were observed in 50% ethanol after 10 days of storage at 50 °C (0.62 ng cm-2) for the dairy product containers and after 1 day of storage at 50 °C (0.68 ng cm-2) for the spiked polypropylene. However, the level of Ti released in particle form was very small compared to the total Ti content in the packaging and far below the acceptable migration limits set by European legislation. Release under standard contact conditions of use of the container was not measurable, thus the migration of TiO2 particles from this packaging to dairy products among storage is expected to be negligible.


Assuntos
Contaminação de Alimentos , Embalagem de Alimentos , Espectrometria de Massas em Tandem , Titânio , Titânio/análise , Titânio/química , Contaminação de Alimentos/análise , Polipropilenos/química , Polipropilenos/análise , Tamanho da Partícula , Nanopartículas/análise , Nanopartículas/efeitos adversos
4.
Environ Res ; 251(Pt 1): 118622, 2024 Jun 15.
Artigo em Inglês | MEDLINE | ID: mdl-38442816

RESUMO

Bioplastics have been used as alternatives to conventional petroleum-based plastics to lessen the burdens on marine and terrestrial environments due to their non-biodegradability and toxicity. However, recent studies have shown that not all bioplastics may be environmentally friendly. Microalgae, such as Spirulina that do not require arable land, have been identified as a potential bioplastic source. In this study, cradle-to-gate life cycle assessment (LCA) was carried out in openLCA program using the Agribalyse database, to evaluate the environmental impacts of Spirulina bioplastic, formed from plasticization of Spirulina powder with glycerol. Two processes were created for the inventories of (i) Spirulina powder and (ii) Spirulina bioplastic, where the output of the former served as an input for the latter. The extruded bioplastic sheets were food-grade and could be used as edible packaging materials. The bioplastic was also compared to conventional plastics and it was found that the energy consumption was 3.83 ± 0.26 MJ/kg-bioplastic, which was 12% and 22% higher than that of LDPE and PVC plastic films, respectively. The impacts on the environment showed that the chemical growth medium (Zarrouk medium) and electricity were the main contributors in most of the categories. Compared to the PVC and LDPE films, the Spirulina bioplastic's impacts on the aquatic ecosystems were 2-3 times higher. The global warming potential of the Spirulina bioplastic was 1.99 ± 0.014 kg CO2 eq, which was 23% and 47% lower than that of LDPE and PVC films, respectively. Sensitivity analysis was carried out by changing the electricity source and using alternative growth media. Except for the case of switching to solar energy, the results for other cases did not differ significantly from the base case scenario. Future studies were suggested to identify different greener alternatives to the growth medium as well as different energy mixes for more environmentally benign solutions.


Assuntos
Glicerol , Spirulina , Spirulina/crescimento & desenvolvimento , Spirulina/química , Glicerol/química , Plásticos , Embalagem de Alimentos
5.
Food Chem Toxicol ; 185: 114484, 2024 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-38280474

RESUMO

Can's polyester coatings are intended to replace epoxy-phenolic ones due to rising safety concern regarding the potential release of bisphenol A under increased regulations and consumer pressure. In this study, hazard linked to the migration of non-intentionally added substances from a single polyester-coated tin plate (5 batches) to canned food has been studied. Migration tests were performed using acetonitrile (ACN) and ethanol (EtOH) 95 %. Non-targeted analyses by liquid chromatography-high-resolution mass spectrometry revealed the presence of four cyclic oligoesters classified as Cramer class III substances with an estimated exposure (calculated for French population only) below the threshold of toxicological concern value of 1.5 µg/kg b.w./day, suggesting a no safety concern. Moreover, migrates were tested using in vitro genotoxicity DNA damage response (DDR) test and mini mutagenicity test (MMT) with different strains of S. Typhimurium using direct incorporation (TA100, TA98, TA102, TA1537) and pre-incubation (TA100, TA98) methods. Samples were negative in both bioassays suggesting the absence of genotoxicity/mutagenicity of the mixtures. To verify any false negative response due to matrix effect, migrates were spiked with corresponding positive controls in parallel with the MMT and the DDR test. No matrix effect was observed in these experimental conditions.


Assuntos
Contaminação de Alimentos , Poliésteres , Poliésteres/toxicidade , Poliésteres/química , Contaminação de Alimentos/análise , Embalagem de Alimentos , Alimentos , Mutagênicos/toxicidade , Mutagênicos/análise , Testes de Mutagenicidade
6.
Food Chem ; 438: 137957, 2024 Apr 16.
Artigo em Inglês | MEDLINE | ID: mdl-37976877

RESUMO

In order to obtain innovative, high-quality biodegradable packaging, double-layer films based on furcellaran and gelatin, enriched with plant extracts were created. The films were assessed considering their potential utility, applications and environmental impact. The mechanical properties over a period of nine months were studied and it was noted that the passing of time had a beneficial effect on these parameters. The antioxidant properties was also examined, with the highest results obtained using the DPPH and metal chelating activity methods for GE (76.64 % and 9.85 % respectively), while this film showed the lowest FRAP value (5.99 %) compared to the highest obtained for DTE (52.62 %). For the first time, the possibility of using the double-layer active FUR/GEL film as packaging for salad-dressing was evaluated, but no improvement in parameters was observed regardless of the extract used. The environmental impact analysis showed the ability to completely decomposed in vermicompost within several days.


Assuntos
Embalagem de Alimentos , Saladas , Embalagem de Alimentos/métodos , Alginatos/química , Bandagens
7.
Int J Biol Macromol ; 254(Pt 3): 128038, 2024 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-37963501

RESUMO

The present work deals with the eco-friendly preparation of highly degradable food packaging films consisting of O-CMC (O-Carboxymethyl Chitosan) and pectin, incorporated with neem (Azadirachta indica) leaves powder and extract. This study aimed to investigate the tensile properties, antimicrobial activity, biodegradability, and thermal behavior of the composite films. The results of tensile strength and elongation at break, showed that the incorporation of neem leaves powder improved the tensile properties (7.11 MPa) of the composite films compared to the neat O-CMC and pectin films (3.02 MPa). The antimicrobial activity of the films was evaluated against a panel of microorganisms including both gram-positive and gram-negative bacteria as well as fungi. The composite films exhibited excellent antimicrobial activity with a zone of inhibition (12-17.6 mm) against the tested microorganisms. The opacity of the composite films ranges from 1.14 to 4.40 mm-1 and the addition of fiber causes a decrease in opacity value. Biodegradability studies were conducted by Soil burial method and the films demonstrated complete biodegradability within 75 days. The results of thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) of composite films show that they are thermally stable and might be used in food packaging.


Assuntos
Anti-Infecciosos , Azadirachta , Quitosana , Pectinas , Embalagem de Alimentos/métodos , Antibacterianos/farmacologia , Pós , Bactérias Gram-Negativas , Bactérias Gram-Positivas , Anti-Infecciosos/farmacologia , Anti-Infecciosos/química , Quitosana/química
8.
Environ Pollut ; 337: 122518, 2023 Nov 15.
Artigo em Inglês | MEDLINE | ID: mdl-37678737

RESUMO

Rapid economic growth and urbanization have led to significant changes in the world's consumption patterns. Accelerated urbanization, the spread of the mobile Internet, and the increasing pace of work globally have all contributed to the demand for the food takeaway industry. The rapid development of the takeaway industry inevitably brings convenience to life, and with it comes great environmental pressure from waste packaging materials. While maintaining the convenience of people's lives, further reducing the environmental pollution caused by takeaway packaging materials and promoting the recycling and reuse of takeaway packaging waste need to attract the attention and concern of the whole society. This review systematically and comprehensively introduces common takeaway food types and commonly used packaging materials, analyzes the impacts of discarded takeaway packaging materials on human health and the ecological environment, summarizes the formulation and implementation of relevant policies and regulations, proposes treatment methods and resourceful reuse pathways for discarded takeaway packaging, and also provides an outlook on the development of green takeaway packaging. Currently, only 20% of waste packaging materials are recycled worldwide, and there is still a need to develop more green takeaway packaging materials and continuously improve relevant policies and regulations to promote the sustainable development of the takeaway industry. The review is conducive to further optimizing the takeaway packaging management system, alleviating the environmental pollution problem, and providing feasible solutions and technical guidance for further optimizing takeaway food packaging materials and comprehensive utilization of resources.


Assuntos
Meio Ambiente , Gerenciamento de Resíduos , Humanos , Embalagem de Produtos , Poluição Ambiental , Indústrias , Desenvolvimento Sustentável , Embalagem de Alimentos , Reciclagem
9.
Mar Pollut Bull ; 194(Pt B): 115387, 2023 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-37595453

RESUMO

We examined the vertical distribution of per- and polyfluoroalkyl substances (PFASs) and total organic carbon in sediment cores located in Shenzhen Bay area. We investigated the 210Pbex specific activity of the sediments and calculated the flux of PFASs to understand the temporal variation of PFASs in the past 65 years. The results showed that the concentrations of PFASs generally decreased with depth, ranging from 13 to 251 pg/g dw. The highest PFASs detected were perfluorobutanesulfonic acid, perfluorooctanoic acid, and perfluorohexanoic acid, which correspond to raw materials used in fire-fighting foam and food packaging industries. The flux of PFASs in Shenzhen Bay showed varying growth after 1978 when China's GDP entered a rapid growth stage. Our findings suggest that the vertical distribution of PFASs in Shenzhen Bay is fluctuating with the changes in industrial types and economic development, with implications for studying the fate of other persistent pollutants in the oceans.


Assuntos
Poluentes Ambientais , Fluorocarbonos , Embalagem de Alimentos , Indústrias
10.
Food Chem ; 428: 136759, 2023 Dec 01.
Artigo em Inglês | MEDLINE | ID: mdl-37418883

RESUMO

To improve the quality of multi-layer film, four-layer films based on furcellaran and active ingredients: gelatin hydrolysate, curcumin, capsaicin, montmorillonite and AgNPs, were produced in an innovative manner. The films were characterised by SEM and AFM analysis. Along with an increase in the concentration of active ingredients, the structure of the film becomes less homogeneous, which may affect the functional properties. The objective of the study was to analyse changes in the functional properties of the newly-obtained films and to verify their potential as packaging materials for fish products. With the increase in active ingredient concentration, water properties also improved, but there were no noticeable significant effects on mechanical properties. For antioxidant properties, the obtained values were within 1.04-2.74 mM Trolox/mg (FRAP) and 7.67-40.49% (DPPH). The obtained multi-layer films were examined with regard to the shelf-life of salmon. For this purpose, salmon fillets were packed in films having good antioxidant and functional properties. The films were effective in microorganism growth inhibition responsible for fillet spoilage during storage. The microorganism number in the active film-stored samples was lower by 0.13 log CFU/g on day 12 versus the control. However, film application did not retard lipid oxidation in the salmon fillets. Nonetheless, the films show great potential as active packaging materials, extending the shelf-life of the packed foods.


Assuntos
Antioxidantes , Embalagem de Alimentos , Animais , Antioxidantes/química , Alginatos/química , Gomas Vegetais/química
11.
Environ Int ; 177: 108010, 2023 07.
Artigo em Inglês | MEDLINE | ID: mdl-37307603

RESUMO

Organophosphate esters (OPEs) are widely used as plasticizers in plastic food packaging; however, the migration of OPEs from plastic to food is largely unstudied. We do not even know the specific number of OPEs that exist in the plastic food packaging. Herein, an integrated target, suspect, and nontarget strategy for screening OPEs was optimized using ultrahigh-performance liquid chromatography-high-resolution mass spectrometry (UHPLC-HRMS). The strategy was used to analyze 106 samples of plastic food packaging collected in Nanjing city, China, in 2020. HRMS allowed full or tentative identification of 42 OPEs, of which seven were reported for the first time. Further, oxidation products of bis(2,4-di-tert-butylphenyl) pentaerythritol diphosphite (AO626) in plastics were identified, implying that the oxidation of organophosphite antioxidants (OPAs) could be an important indirect source of OPEs in plastics. The migration of OPEs was examined with four simulated foods. Twenty-six out of 42 OPEs were detected in at least one of the four simulants, particularly isooctane, in which diverse OPEs were detected at elevated concentrations. Overall, the study supplements the list of OPEs that humans could ingest as well as provides essential information regarding the migration of OPEs from plastic food packaging to food.


Assuntos
Retardadores de Chama , Plásticos , Humanos , Plásticos/análise , Embalagem de Alimentos , Ésteres/análise , Retardadores de Chama/análise , Monitoramento Ambiental , Organofosfatos/análise , China , Suplementos Nutricionais/análise
12.
Food Chem ; 425: 136499, 2023 Nov 01.
Artigo em Inglês | MEDLINE | ID: mdl-37285625

RESUMO

The chemical safety of representative polysaccharide films made with pea starch, organocatalytic acetylated pea starch and pectin was investigated at different migration conditions (20 °C/10 days, 70 °C/2 h) using two official simulants signifying hydrophilic (simulant A, 10% ethanol) or lipophilic (simulant D1, 50% ethanol) foods. Migrating semi-volatile and non-volatile compounds were identified and semi-quantified by ultra-high performance liquid chromatography-trap ion mobility time-of-flight mass spectrometry (UHPLC-TIMS-TOF-MS/MS), whereas their toxicity was evaluated by in silico models based on qualitative structure activity (QSAR). Physicochemical analysis revealed polymer wash-off into the simulants. Migration testing at 70 °C for 2 h using simulant D1 resulted in detectable concentrations of glycerol (≤72.1 mg/kg), monoacetylated maltose (≤6.5 mg/kg), and dibutyl phthalate (DBP) (≤0.5 mg/kg, compliant with the existing legislative migration limits) in samples containing acetylated starch. Migrating 3-ß-galactopyranosyl glucose (≤8.9 mg/kg) and 2,5-diketo-d-gluconic acid (≤4.9 mg/kg) were detected at 20 °C/10 days. In-silico toxicity emphasized no significant toxicity and categorized organocatalytic acetylated pea starch of no safety concern.


Assuntos
Alimentos , Espectrometria de Massas em Tandem , Polímeros/análise , Amido , Etanol/análise , Embalagem de Alimentos , Contaminação de Alimentos/análise
13.
Food Microbiol ; 114: 104306, 2023 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-37290880

RESUMO

Chicken meat is the most popularly consumed meat worldwide, with free-range and ethically produced meat a growing market among consumers. However, poultry is frequently contaminated with spoilage microbes and zoonotic pathogens which impact the shelf-life and safety of the raw product, constituting a health risk to consumers. The free-range broiler microbiota is subject to various influences during rearing such as direct exposure to the external environment and wildlife which are not experienced during conventional rearing practices. Using culture-based microbiology approaches, this study aimed to determine whether there is a detectable difference in the microbiota from conventional and free-range broilers from selected Irish processing plants. This was done through analysis of the microbiological status of bone-in chicken thighs over the duration of the meat shelf-life. It was found that the shelf-life of these products was 10 days from arrival in the laboratory, with no statistically significant difference (P > 0.05) evident between free-range and conventionally raised chicken meat. A significant difference, however, was established in the presence of pathogenesis-associated genera in different meat processors. These results reinforce past findings which indicate that the processing environment and storage during shelf-life are key determinants of the microflora of chicken products reaching the consumer.


Assuntos
Galinhas , Microbiota , Animais , Galinhas/microbiologia , Microbiologia de Alimentos , Embalagem de Alimentos/métodos , Carne/microbiologia
14.
Sci Total Environ ; 894: 164781, 2023 Oct 10.
Artigo em Inglês | MEDLINE | ID: mdl-37321496

RESUMO

Packaging can play a substantial role in moving towards more sustainable food systems by affecting the amount of food loss and waste. However, the use of plastic packaging gives rise to environmental concerns, such as high energy and fossil resource use, and waste management issues such as marine litter. Alternative biobased biodegradable materials, such as poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) could address some of these issues. For a careful comparison in terms of environmental sustainability between fossil-based, non-biodegradable and alternative plastic food packaging, not only production but also food preservation and end-of-life (EoL) fate must be considered. Life cycle assessment (LCA) can be used to evaluate the environmental performance, but the environmental burden of plastics released into the natural environment is not yet embedded in classical LCA. Therefore, a new indicator is being developed that accounts for the effect of plastic litter on marine ecosystems, one of the main burdens of plastic's EoL fate: lifetime costs on marine ecosystem services. This indicator enables a quantitative assessment and thus addresses a major criticism of plastic packaging LCA. The comprehensive analysis is performed on the case of falafel packaged in PHBV and conventional polypropylene (PP) packaging. Considering the impact per kilogram of packaged falafel consumed, food ingredients make the largest contribution. The LCA results indicate a clear preference for the use of PP trays, both in terms of (1) impact of packaging production and dedicated EoL treatment and (2) packaging-related impacts. This is mainly due to the higher mass and volume of the alternative tray. Nevertheless, since PHBV has limited persistence in the environment compared to PP packaging, the lifetime costs for marine ES are about seven times lower, and this despite its higher mass. Although further refinements are needed, the additional indicator allows for a more balanced evaluation of plastic packaging.


Assuntos
Ecossistema , Plásticos , Animais , Embalagem de Alimentos , Polipropilenos , Poliésteres , Estágios do Ciclo de Vida
15.
J Food Prot ; 86(8): 100121, 2023 08.
Artigo em Inglês | MEDLINE | ID: mdl-37355008

RESUMO

Antioxidants are widely used to prevent oxidative degradation of food-contact plastics materials. However, when plastic products come into contact with food, antioxidants may contaminate food. Herein, twenty-three kinds of possible antioxidants were monitored in 257 products of seven polymers. The migration of antioxidants into the food simulants at different temperatures and times was detected by using HPLC-MS/MS. Risk assessment was performed based on the EU, U.S. FDA methods and Monte Carlo simulation. The antioxidants migrated mainly to fatty food simulant, with the highest concentration and occurrence frequency of Irgafos 168, followed byIrganox 1010, Irganox 1076, and Antioxidant LTDP in polyethylene terephthalate, polyvinyl chloride, polypropylene, polyethylene. No antioxidants were detected in polystyrene, polycarbonate, and polyvinylidene chloride. Additionally, antioxidants exhibited the highest detection rate of 0.81 in polyethylene. Risk assessment demonstrated that the antioxidants have no obvious health risk to the exposed population. However, the risk of polypropylene was relatively high compared to other polymers.


Assuntos
Antioxidantes , Plásticos , Antioxidantes/análise , Polipropilenos , Espectrometria de Massas em Tandem , Cromatografia Líquida de Alta Pressão , Embalagem de Alimentos , Polímeros , Polietileno , Contaminação de Alimentos/análise
16.
Environ Int ; 176: 107978, 2023 06.
Artigo em Inglês | MEDLINE | ID: mdl-37210807

RESUMO

BACKGROUND: The presence of polyethylene terephthalate (PET) oligomers in food contact materials (FCMs) is well-documented. Consumers are exposed through their migration into foods and beverages; however, there is no specific guidance for their safety evaluation. OBJECTIVES: This systematic evidence map (SEM) aims to identify and organize existing knowledge and associated gaps in hazard and exposure information on 34 PET oligomers to support regulatory decision-making. METHODS: The methodology for this SEM was recently registered. A systematic search in bibliographic and gray literature sources was conducted and studies evaluated for inclusion according to the Populations, Exposures, Comparators, Outcomes, and Study type (PECOS) framework. Inclusion criteria were designed to record hazard and exposure information for all 34 PET oligomers and coded into the following evidence streams: human, animal, organism (non-animal), ex vivo, in vitro, in silico, migration, hydrolysis, and absorption, distribution, metabolism, excretion/toxicokinetics/pharmacokinetics (ADME/TK/PK) studies. Relevant information was extracted from eligible studies and synthesized according to the protocol. RESULTS: Literature searches yielded 7445 unique records, of which 96 were included. Data comprised migration (560 entries), ADME/TK/PK-related (253 entries), health/bioactivity (98 entries) and very few hydrolysis studies (7 entries). Cyclic oligomers were studied more frequently than linear PET oligomers. In vitro results indicated that hydrolysis of cyclic oligomers generated a mixture of linear oligomers, but not monomers, potentially allowing their absorption in the gastrointestinal tract. Cyclic dimers, linear trimers and the respective smaller oligomers exhibit physico-chemical properties making oral absorption more likely. Information on health/bioactivity effects of oligomers was almost non-existent, except for limited data on mutagenicity. CONCLUSIONS: This SEM revealed substantial deficiencies in the available evidence on ADME/TK/PK, hydrolysis, and health/bioactivity effects of PET oligomers, currently preventing appropriate risk assessment. It is essential to develop more systematic and tiered approaches to address the identified research needs and assess the risks of PET oligomers.


Assuntos
Contaminação de Alimentos , Polietilenotereftalatos , Humanos , Contaminação de Alimentos/análise , Embalagem de Alimentos , Inocuidade dos Alimentos , Polietilenotereftalatos/toxicidade , Medição de Risco
17.
Int J Biol Macromol ; 240: 124474, 2023 Jun 15.
Artigo em Inglês | MEDLINE | ID: mdl-37072063

RESUMO

The current study was conducted to develop biodegradable films with matrix composed from carboxymethyl cellulose (CMC), sodium alginate (SA) and different concentrations from Thymus vulgaris purified leaves extract (TVE). The color properties, physical properties, shape of surface, manners of crystallinity, mechanical properties and thermal properties of produced films were investigated. The continuous addition of TVE up to 1.6 % inside films matrix imparted the yellow color of extract that increased opacity to 2.98 and reduced moisture, swelling, solubility and water vapor permeability (WVP) of films up to 10.31 %, 30.17 %, 20.18 % and (1.12× 10-10 g.m-1 s-1 pa-1), respectively. Furthermore, the surface micrographs showed smoother surface after using small concentrations of TVE and turned to irregular with rough surface at higher concentrations. The FT-IR analysis indicated typically bands that demonstrated physical interaction between TVE extract and CMC/SA matrix. The fabricated films showed suitable thermal stability with decreasing trend by incorporation of TVE inside CMC/SA films. Furthermore, the developed CMC/SA/TVE2 showed significant effects on preserving the levels of moisture content, titrable acidity, force to puncture and sensory properties of cheddar cheese during cold storage days compared with commercial packaging materials.


Assuntos
Anti-Infecciosos , Thymus (Planta) , Alginatos , Antioxidantes/farmacologia , Carboximetilcelulose Sódica , Espectroscopia de Infravermelho com Transformada de Fourier , Embalagem de Alimentos , Anti-Infecciosos/farmacologia , Permeabilidade , Extratos Vegetais/farmacologia
18.
Food Chem ; 420: 136097, 2023 Sep 15.
Artigo em Inglês | MEDLINE | ID: mdl-37060672

RESUMO

The evaluation of the migration of ionic silver and nanoparticulated silver (AgNPs) from antimicrobial plastic packaging to food is crucial to ensure its safety. Migration assays were performed on reusable silver-containing polypropylene (PP) food containers and a silicone baby bottle, using food simulants, under conventional or microwave heating and repeated use. The PP containers released significant amounts of silver, increasing with temperature, contact time, acidity and lower crystallinity. Silver migration in the silicone bottle was much lower. Risk assessment of released silver was done considering European authorities safety recommendations, with some containers far exceeding these levels. No significant AgNPs release was detected in the simulants by single particle-ICPMS. Silver-containing microplastics and silicone microparticles were detected by SEM in the food simulants after the migration assays. Consumers may be continuously exposed to the harmful effects of ionic silver and microplastics, which can potentially lead to health issues.


Assuntos
Nanopartículas Metálicas , Plásticos , Embalagem de Alimentos , Microplásticos , Prata/análise , Calefação , Micro-Ondas , Nanopartículas Metálicas/análise , Antibacterianos , Polipropilenos , Medição de Risco , Contaminação de Alimentos/análise
19.
Int J Biol Macromol ; 235: 123880, 2023 Apr 30.
Artigo em Inglês | MEDLINE | ID: mdl-36870647

RESUMO

In this study, lignin was synthesized from the waste leaves of Ficus auriculata obtained after the extraction of gallic acid. The synthesized lignin was incorporated into PVA films, and the neat and blended films were characterized using different techniques. Lignin addition improved the UV-shielding, thermal, antioxidant, and mechanical properties of PVA films. The water solubility decreased from 31.86 % to 7.14 ± 1.94 %, while the water vapor permeability increased from 3.85 ± 0.21 × 10-7 g.m.h-1 Pa-1 to 7.84 ± 0.64 × 10-7 g.m.h-1 Pa-1 for pure PVA film and the film containing 5 % lignin, respectively. The prepared films showed a much better performance than commercial packaging films in inhibiting mold growth during the storage of preservative-free bread. The bread samples packed with commercial packaging showed signs of mold growth on the 3rd day, while the growth was inhibited entirely till the 15th day for PVA film containing 1 % lignin. The pure PVA film and the ones containing 3 % and 5 % of lignin inhibited growth till the 12th and 9th day, respectively. Findings from the current study show that safe, cheap, and eco-friendly biomaterials can hinder the growth of spoilage microorganisms and potentially be used in food packaging.


Assuntos
Ficus , Embalagem de Alimentos , Química Verde , Lignina , Folhas de Planta , Lignina/química , Lignina/metabolismo , Ficus/química , Folhas de Planta/química , Embalagem de Alimentos/economia , Embalagem de Alimentos/métodos
20.
PLoS One ; 18(2): e0278021, 2023.
Artigo em Inglês | MEDLINE | ID: mdl-36745600

RESUMO

Supervision over the suppliers of packaging as well as suppliers of raw materials for packaging production is important to ensure the quality and safety of meat products. The aim of this study was to verify the remote evaluation procedure of quality, processing and economic criteria in qualification of raw materials suppliers to the meat packaging foil producer during the Covid-19 pandemic. The evaluation was done remotely in terms of meeting some of the requirements of the quality management system (QMS) in conditions where regular audit could not be carried out. The survey was conducted in one of the biggest packaging foil producers in Greece via its supplier evaluation. The evaluation consisted of: 1/ economic criteria and 2/ quality and processing criteria. The highest and the lowest rated economic criteria were procedural compliance and price of raw materials. Among the quality and processing criteria, the highest score was given to warranties and claims policies and material quality, and the lowest one to lead time. The highest ratings obtained suppliers of raw materials directly involved in production, suppliers from Greece, the USA and Denmark, as well as suppliers to the R&D department. The results of the study showed that the quality of the raw materials directly used in the production of packaging foil was adequate. Therefore, their use ensure production of packaging foil and finally packaged meat products of adequate quality and safety. The presented procedure occurred to be useful for remote evaluation of quality, processing and economic criteria in qualification of suppliers during the Covid-19 pandemic. It may inspire other producers of food packaging materials to continuing supervision over their suppliers while regular methods of control are limited.


Assuntos
COVID-19 , Produtos da Carne , Humanos , Grécia , Pandemias , COVID-19/epidemiologia , Carne , Embalagem de Alimentos/métodos
SELEÇÃO DE REFERÊNCIAS
DETALHE DA PESQUISA