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1.
Radiat Prot Dosimetry ; 200(8): 715-720, 2024 Jun 03.
Artigo em Inglês | MEDLINE | ID: mdl-38689537

RESUMO

This study used gamma ray spectrometry to determine the radiological safety of construction soil sampled randomly from Mbeere North region, Kenya. The mean activity concentration of 232Th, 238U, and 40K was 149.7 ± 2.8 Bqkg-1, 88.3 ± 2.4 Bqkg-1, and 490 ± 35 Bqkg-1, respectively. These averages exceed the world average for all the radionuclides. The radionuclides were non-uniformly distributed, with higher concentrations along the slopes and on the feet of the hills. The mean absorbed dose rate, indoor and outdoor annual effective dose, radium equivalent, external hazard index, and internal hazard index were 157.9 ± 4.4 nGh-1, 0.58 ± 0.02 mSvy-1, 0.39 ± 0.01 mSvy-1, 340.7 ± 9.2 Bqkg-1, 0.92 ± 0.02 and 1.14 ± 0.03, respectively. Among the radiation safety indicators, only the average internal hazard index exceeded slightly the acceptable safe limit. Therefore, soils of Mbeere North region are radiologically safe for use in brick making and construction of human habitats.


Assuntos
Radioisótopos de Potássio , Monitoramento de Radiação , Poluentes Radioativos do Solo , Espectrometria gama , Tório , Quênia , Poluentes Radioativos do Solo/análise , Monitoramento de Radiação/métodos , Tório/análise , Radioisótopos de Potássio/análise , Humanos , Urânio/análise , Doses de Radiação , Raios gama
2.
Appl Radiat Isot ; 207: 111266, 2024 May.
Artigo em Inglês | MEDLINE | ID: mdl-38461629

RESUMO

Brazil is the fourth largest cement consumer in the world and the largest producer in Latin America, around 1.3% of global production. The main inputs in the manufacture of cement are limestone and clay. Few studies have been carried out in the country on the risk of these materials used in civil construction. Therefore, the objective of this present work is to evaluate the radiological danger that they can present to society. Gamma spectrometry analysis on 16 samples of different brands of cement used as construction material in Rio de Janeiro (Brazil) was performed in this study, using an HPGe detector and the Genie 2000 data acquisition software. Samples were set to count for an accumulation time of 14,400 s (4 h) and all measurements were corrected to eliminate background and backscattering. Activity concentrations are determined for 226Ra was from (41.2 ± 1.6 to 174.9 ± 3.9) Bq kg-1, 232Th was from (15.7 ± 0.5 to 43.1 ± 0.7) Bq kg-1 and 40K was from (82.6 ± 7.2 to 254 ± 17) Bq kg-1. To assess radiological health risks: mean values of Radium Activity Equivalent 150.0 ± 3.4 Bq kg-1, Annual Gonadal Dose Equivalent 468 ± 11 µSv year-1 and Lifetime Excess Cancer Risk (ELCR) 2.42 ± 0.06 were calculated. Total Absorbed Dose Rates ranged from 72.2 ± 1.7 to 225.1 ± 5.2 nGy h-1. The damage to collective health was also estimated from the annual effective dose rates with an estimated total cost of damage to health of US$ 130 million. Values are generally within global limits reported by UNSCEAR.


Assuntos
Monitoramento de Radiação , Radioatividade , Rádio (Elemento) , Poluentes Radioativos do Solo , Radioisótopos de Potássio/análise , Tório/análise , Monitoramento de Radiação/métodos , Brasil , Materiais de Construção/análise , Rádio (Elemento)/análise , Poluentes Radioativos do Solo/análise , Espectrometria gama
3.
Artigo em Inglês | MEDLINE | ID: mdl-38541314

RESUMO

This article reports the results of an investigation into the activity concentration of natural radionuclides in raw building materials for underground parking lots, together with the assessment of the radiation hazard for the public related to exposure to ionizing radiations. To this purpose, high-purity germanium (HPGe) γ-ray spectrometry was employed in order to quantify the average specific activity of 226Ra, 232Th, and 40K natural radioisotopes. With the aim to assess any possible radiological health risk for the population, the absorbed γ-dose rate (D), the annual effective dose equivalent outdoor (AEDEout) and indoor (AEDEin), the activity concentration index (I), and the alpha index (Iα) were also estimated, resulting in values that were lower than the maximum recommended ones for humans. Finally, the extent of the correlations existing between the observed radioactivity and radiological parameters and of these parameters with the analyzed samples was quantified through statistical analyses, including Pearson's correlation, a principal component analysis (PCA), and a hierarchical cluster analysis (HCA). As a result, three clusters of the investigated samples were recognized based on their chemical composition and mineralogical nature. Noteworthily, this paper covers a certain gap in science since its topic does not appear in literature in this form. Thus, the authors underline the importance of this work to global knowledge in the environmental research and public health fields.


Assuntos
Monitoramento de Radiação , Radioatividade , Rádio (Elemento) , Poluentes Radioativos do Solo , Humanos , Monitoramento de Radiação/métodos , Radioisótopos/análise , Saúde Radiológica , Espectrometria gama , Materiais de Construção/análise , Tório/análise , Radioisótopos de Potássio/análise , Rádio (Elemento)/análise , Poluentes Radioativos do Solo/análise
4.
Isotopes Environ Health Stud ; 60(2): 213-225, 2024 May.
Artigo em Inglês | MEDLINE | ID: mdl-38372986

RESUMO

Terrestrial gamma radiation is one of the major outdoor radiation exposures to the general public that varies substantially based on the type and geological properties of the soil. The objective of this study is to evaluate the naturally occurring radioactive materials (NORMs) distribution and assess the hazard parameters in the riverbank soil within various industrial zones in the densely populated Dhaka and Chattogram cities of Bangladesh. The mean activities of 226Ra (37 ± 3), 232Th (58 ± 4), and 40K (1129 ± 18) Bqkg-1 in the assessed soil samples were found to be slightly higher than the world average values 32, 35, and 420 Bqkg-1, respectively. The mean radium equivalent activity (207.49 Bqkg-1) and the external and internal hazard indices were within the recommended limits of 370 Bqkg-1 and <1, respectively. The mean absorbed dose rate (99.47 nGyhr-1), annual effective dose (0.12 mSva-1), ELCR (4.27 × 10-4), and gamma level index (1.58) exceeded the world average values 59 nGyhr-1, 0.07 mSva-1, 2.9 × 10-4, and 1 respectively. However, the studied areas are safe from a radiological viewpoint with no radiation health hazard to the people. The results of this study can be utilized to produce factual baseline data for future studies.


Assuntos
Monitoramento de Radiação , Radioatividade , Rádio (Elemento) , Poluentes Radioativos do Solo , Humanos , Poluentes Radioativos do Solo/análise , Monitoramento de Radiação/métodos , Tório/análise , Bangladesh , Rádio (Elemento)/análise , Solo , Radioisótopos de Potássio/análise , Espectrometria gama
5.
Radiat Prot Dosimetry ; 200(2): 201-205, 2024 Feb 16.
Artigo em Inglês | MEDLINE | ID: mdl-38044801

RESUMO

Natural radioactive materials in certain conditions can get to hazardous radiological level. The aim of the present work was to evaluate the natural activity concentration from sampled building materials collected from different locations in Babadogo Estate within Nairobi City County. The analysis done using gamma ray spectrometer, which was put into action for spectral data acquisition and then analysis. The activity concentration levels of 238U, 232Th and 40K for the selected samples of building materials was measured by the use of gamma ray spectrometry method. The analyzed data compared with the standard acceptable values. The activity concentration in 40K varied from 55 ± 3 to 2647 ± 132 Bq kg-1, giving an average (sum of all values divided by 33) value of 831 ± 42 Bq kg-1; 238U varied from 39 ± 2 to 3602 ± 180 Bq kg-1, giving average figures of 378 ± 19 Bq kg-1 and 232Th ranged from 5.000 ± 0.300 to 4213 ± 211 Bq kg-1, giving average figure of 290 ± 15 Bq kg-1. The calculated average figures for activity concentration surpassed the world average values of 420, 33 and 45 Bq kg-1 in 40K, 238U and 232Th, respectively.


Assuntos
Monitoramento de Radiação , Radioatividade , Rádio (Elemento) , Urânio , Tório/análise , Urânio/análise , Quênia , Materiais de Construção/análise , Espectrometria gama , Radioisótopos de Potássio/análise , Rádio (Elemento)/análise
6.
Environ Monit Assess ; 195(11): 1307, 2023 Oct 13.
Artigo em Inglês | MEDLINE | ID: mdl-37831213

RESUMO

Radioactive elements and their impact on the environment and the food chain, including humans, are a matter of major concern, for which appropriate investigations should be performed. The priority is to examine the concentration of radioactive substances in mineral and bottled spring water. This task aims to analyze the quality of 12 conditioned mineral waters by determining their main radionuclides concentrations, such as 238U, 232Th, and 40K. The identification and the quantification of these radionuclides are carried out by their progeny (except the 40K) by using a NaI(Tl) detector coupled with a multichannel analyzer (MCA) and connected to a computer. The activity measured in all samples varied from 0.95 to 3.38 mBq.L-1 with an average of 1.94 mBq.L-1; from 1.55 to 3.56 mBq.L-1 with an average of 2.46 mBq.L-1; and from 200.68 to 269.19 mBq.L-1 with an average of 236.6 mBq.L-1, for 238U, 232Th, and 40K, respectively. To compare the combined radiological effects of radionuclides present in water, a particular factor Ra(eq) is used. This study showed that the maximum value of Ra(eq) is 27.54 mBq.L-1, which is far below the activity limit of 370 mBq.year-1 set by the Organization of Economics and Development (OECD). Concerning the effective annual dose, the following maximums were measured: 1.61 µSv.year-1, 1.133 µSv.year-1, and 0.925 µSv.year-1 for infants, children, and adults, respectively. These values are even smaller than the dose recommended by the WHO which is 100 µSv.year-1. Regarding the excess lifetime cancer risk index, a maximum of 5.63 × 10-6 is found. This index value is still less than that proposed by James, namely 2.5 × 10-3. Thus, the quality of the studied samples respects the radiological international safety and health limits.


Assuntos
Água Potável , Monitoramento de Radiação , Radioatividade , Poluentes Radioativos da Água , Lactente , Criança , Adulto , Humanos , Água Potável/química , Poluentes Radioativos da Água/análise , Espectrometria gama , Monitoramento de Radiação/métodos , Radioisótopos/análise
7.
Mar Pollut Bull ; 194(Pt B): 115367, 2023 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-37567130

RESUMO

The objective of this study is to assess the natural resources and radiological risks of Wadi El Gemal Island by examining its topography, mineralogy, geochemistry, and radioactive distributions. This island, which is situated at the outlet of Wadi El Gemal in Egypt's southeastern Desert, has a unique shape resembling a dolphin based on Landsat imagery. It's a part of the Wadi El Gemal-Hamata Protectorate and is notable for its diverse environmental, geological, economic, and archeological features, including recent reefs, sandy deposits, Quaternary carbonate sediments, and mangroves. The main natural resources on the island are fauna, mangrove forests, and flora. Samples collected from the island were analyzed using a NaI detector to measure the concentrations of radionuclides such as 238U, 232Th, 226Ra, and 40K, which were found to be within acceptable levels according to UNSCAR guidelines. The radionuclide 238U, 232Th, 226Ra, and 40K activity concentrations of the collected samples were 32.55 ± 9, 12.63 ± 4, 12.49 ± 4, and 325 ± 34 Bq/kg, respectively. Regarding radiological hazard indices, the values of absorbed gamma dose rate (36.06 ± 5.42 nGy/h), radium equivalent activity (73.88 ± 14.4 Bq/kg), annual effective dose indoor (0.18 ± 0.03 mSv/y) and outdoor (0.04 ± 0.01 mSv/y), internal (0.29 ± 0.05) and external (0.2 ± 0.03) indices, and excess lifetime cancer index (0.15 ± 0.05 × 10-3).This is suggest that there is no significant risk associated with these sediments.


Assuntos
Monitoramento de Radiação , Radioatividade , Rádio (Elemento) , Poluentes Radioativos do Solo , Radioisótopos/análise , Rádio (Elemento)/análise , Recursos Naturais , Tório/análise , Poluentes Radioativos do Solo/análise , Radioisótopos de Potássio/análise , Espectrometria gama
8.
Appl Radiat Isot ; 199: 110918, 2023 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-37406489

RESUMO

In this study, the activity concentrations of 40K, 232Th, and 226Ra radionuclides were estimated in imported milk powder samples from 40 brands available in local markets in Erbil Governorate, Iraq. The measurements were performed using High Purity Germanium (HPGe) detector. The results indicated that the average activity concentrations of 40K, 232Th, and 226Ra were 241, 0.476, and 1.23 Bq kg-1, respectively, and comparisons were made based on the typical consumption characteristics of powdered milk by Kurdistan residents. In all investigated age groups (2-17 years), the average annual effective doses were below the ICRP-recommended limit of 1 mSv y-1 for public exposure. Radiological hazard parameters were determined based on the measured radioactivity concentrations. The relation between all the determined activities of natural radionuclides and radiological parameters was examined using multivariate statistical analysis techniques such as histograms, descriptive statistics, and Pearson correlation analyses. The cancer risk in all samples was lower than the allowable value of (2.5 × 10-3), while the ingestion dose in two samples was higher than the worldwide acceptable value of (0.29) mSv y-1.


Assuntos
Monitoramento de Radiação , Rádio (Elemento) , Poluentes Radioativos do Solo , Animais , Pós , Iraque , Leite/química , Radioisótopos/análise , Poluentes Radioativos do Solo/análise , Monitoramento de Radiação/métodos , Rádio (Elemento)/análise , Tório/análise , Radioisótopos de Potássio/análise , Espectrometria gama
9.
Environ Monit Assess ; 195(7): 851, 2023 Jun 16.
Artigo em Inglês | MEDLINE | ID: mdl-37326918

RESUMO

Measurements of radionuclides' activities in air, water, and soil give clues about the anthropogenic activities in the region, and imperative to assess the overall radiological risk for individuals. Such an investigation was carried out to characterize the soil activities in the region hosting a research center, and to calculate the associated elements of radiological risk in terms of radiation doses and hazard indices. The soil samples were collected within the radius of 10 km in local area, Nilore, and analysed for activity using a high-purity germanium (HPGe) gamma spectrometric system. In all samples, only the basic nuclides, contributing to terrestrial activity, i.e., 40 K, 232Th, 226Ra, and 137Cs, were observed within the detectable limits of activity. The distribution of the data set and the correlation between the measured activities were studied with the use of the principal component analysis (PCA). The measured average specific activities of 226Ra, 232Th, 40 K, and 137Cs were 40.65 ± 9.84 Bq/kg, 59.31 ± 16.53 Bq/kg, 528.24 ± 131.18 Bq/kg, and 5.16 ± 4.56 Bq/kg respectively. The corresponding dose rate in air was found to be 76.63 ± 18.39 nGy/h, which is slightly higher than the world median value of 51 nGy/h calculated from concentration of terrestrial radionuclides in soil but falls within the world average value range of outdoor external exposure of 18-93 nGy/h obtained through direct measurement, and therefore not harmful for the living species. The standard hazard indices for all soil samples such as radium equivalent activity ([Formula: see text]), external hazard index (Hex), and internal hazard index (Hin) were also found within safe limits for the soil to be used as construction of building material. This investigation led to conclusion that the soil activities are consistent with the usual background level of terrestrial activities, and their associated dose rates are well within the safe limits for public.


Assuntos
Monitoramento de Radiação , Rádio (Elemento) , Poluentes Radioativos do Solo , Humanos , Espectrometria gama , Monitoramento de Radiação/métodos , Paquistão , Poluentes Radioativos do Solo/análise , Radioisótopos de Césio/análise , Rádio (Elemento)/análise , Solo/química , Medição de Risco , Tório/análise , Radioisótopos de Potássio/análise
10.
Appl Radiat Isot ; 198: 110853, 2023 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-37216724

RESUMO

Gamma detector detection technology based on NaI(Tl) scintillation crystal has become a popular research topic and has been applied in the field of marine radioactive environment automatic monitoring because of its advantages of low power consumption, low cost and strong environmental adaptability. However, insufficient energy resolution of the NaI(Tl) detector and great Compton scattering in the low-energy region caused by the abundance of natural radionuclides in seawater hinder the automatic analysis of radionuclides in seawater. This study adopts the combination of theoretical derivation, simulation experiment, water tank test and seawater field test, establishing an effective and feasible spectrum reconstruction method. The measured spectrum in seawater is regarded as the output signal formed by the convolution of the incident spectrum and the detector response function. The acceleration factor p is introduced to construct the Boosted-WNNLS deconvolution algorithm, which is used to iteratively reconstruct the spectrum. The analysis results of the simulation test, water tank test and field test meet the radionuclide analysis speed and accuracy requirements for the in-situ automatic monitoring of seawater radioactivity. The spectrum reconstruction method in this study converts the physical problem of insufficient detection accuracy of spectrometer in the practical application into a mathematical problem of deconvolution solution, restores the original radiation information in seawater, and improves the resolution of the seawater gamma spectrum.


Assuntos
Monitoramento de Radiação , Radioatividade , Monitoramento de Radiação/métodos , Espectrometria gama/métodos , Método de Monte Carlo , Água do Mar/análise , Radioisótopos/análise , Água/análise , Raios gama
11.
Environ Pollut ; 323: 121288, 2023 Apr 15.
Artigo em Inglês | MEDLINE | ID: mdl-36791947

RESUMO

Radioactivity levels of naturally occurring radionuclides at the coast of Brunei Darussalam were evaluated along with their dose rates. Twenty-six berm and intertidal sediment samples were measured using gamma-ray spectrometry. The mean activity concentrations of 226Ra, 232Th and 40K in berm sediments were 10.07 ± 1.02 Bq/kg, below the minimum detectable activity, and 21.44 ± 1.23 Bq/kg, respectively, whereas for intertidal sediments they were 7.01 ± 0.87, 1.67 ± 0.15 and 4.99 ± 0.42 Bq/kg, respectively. With respect to the radiological health risk, the average hazard indices, absorbed gamma dose rate, effective dose equivalent, and excess lifetime cancer risk were found to be less than the global average. Calculation of the activity ratio showed that 40K is the main source of radiation in the coastal sediments. Furthermore, the difference in radioactivity levels between the berm sediments and intertidal sediments collected at the same location was investigated. Finally, a standard geological terminology of the littoral zone profile is proposed for describing coastal samples for universal communication among researchers.


Assuntos
Monitoramento de Radiação , Radioatividade , Poluentes Radioativos do Solo , Monitoramento de Radiação/métodos , Brunei , Radioisótopos/análise , Espectrometria gama , Poluentes Radioativos do Solo/análise
12.
J Environ Radioact ; 256: 107052, 2023 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-36308943

RESUMO

Environmental contamination by radioactive materials can be characterized by in situ gamma surface measurements. During such measurements, the field of view of a gamma detector can be tens of meters wide, resulting in a count rate that integrates the signal over a large measurement support volume/area. The contribution of a specific point to the signal depends on various parameters, such as the height of the detector above the ground surface, the gamma energy and the detector properties, etc. To improve the spatial resolution of the activity concentration, contributions of a radionuclide from nearby areas to the count rate of a single measurement should be disentangled. The experiments described in this paper, deployed 2D inversion of in situ gamma spectrometric measurements using a non-negative least squares-based Tikhonov regularization method. Data were acquired using a portable LaBr3 gamma detector. The detector response as a function of the distance of the radioactive source, required for the inversion process, was simulated using the Monte Carlo N-Particle (MCNP) transport code. The uncertainty on activity concentration was calculated using the Monte Carlo error propagation method. The 2D inversion methodology was first satisfactorily assessed for 133Ba and 137Cs source activity distributions using reference pads. Secondly, this method was applied on a 137Cs contaminated site, making use of above-ground in-situ gamma spectrometry measurements, conducted on a regular grid. The inversion process results were compared with the results from in-situ borehole measurements and laboratory analyses of soil samples. The calculated 137Cs activity concentration levels were compared against the activity concentration value for exemption or clearance of materials which can be applied by default to any amount and any type of solid material. Using the 2D inversion and the Monte Carlo error propagation method, a high spatial resolution classification of the site, in terms of exceeding the exemption limit, could be made. The 137Cs activity concentrations obtained using the inversion process agreed well with the results from the in-situ borehole measurements and those from the soil samples, showing that the 2D inversion is a convenient approach to deconvolute the contribution of radioactive sources from nearby areas within a detector's field of view, and increases the resolution of spatial contamination mapping.


Assuntos
Monitoramento de Radiação , Espectrometria gama , Espectrometria gama/métodos , Monitoramento de Radiação/métodos , Radioisótopos de Césio/análise , Método de Monte Carlo , Solo
13.
Appl Radiat Isot ; 191: 110528, 2023 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-36379133

RESUMO

Research on unmanned online monitoring equipment for marine radioactivity surrounding nuclear power plants is of great significance. In this work, a small radioactivity monitoring system based on buoy was designed and manufactured for the emergency situation of nuclear accidents. The core of the radioactivity monitoring system is the underwater gamma spectrometer. The spectrometer can respond to gamma rays from 60 keV to 3 MeV, and can identify the nuclides whose characteristic rays belong to this energy range. The detection efficiency curve was calculated through Monte Carlo simulation and verified in a standard liquid source. A data acquisition processor was also designed to coordinate the detectors in the system and wirelessly transmit online monitoring data. Three experiments were carried out in the seawater around the Tianwan Nuclear Power Plant in Lianyungang, China using this online marine radioactivity monitoring system based on buoys. The stability and radioactivity monitoring capabilities of the system have been verified.


Assuntos
Monitoramento de Radiação , Radioatividade , Espectrometria gama/métodos , Raios gama , Monitoramento de Radiação/métodos , Método de Monte Carlo
14.
Environ Monit Assess ; 195(1): 140, 2022 Nov 22.
Artigo em Inglês | MEDLINE | ID: mdl-36417000

RESUMO

Radiometric monitoring of construction materials is required for estimating the interior and exterior exposure to ionizing radiation emitted by terrestrial radioactive elements in building materials. Using gamma-ray spectroscopy, the activity concentrations of 226Ra, 232Th, and 40 K in fifty-two samples from eighteen different building materials commonly used in Erbil city, Kurdistan region, Iraq, were evaluated to assess possible radioactive dangers to human health. The activity concentrations of 226Ra, 232Th and 40 K ranged from 1 ± 0.1 (gypsum board) to 130 ± 11 (granite), 1.3 ± 0.2 (gypsum) to 66 ± 8 (ceramic sample), and 18.74 ± 4 (gypsum) to 1061.708 ± 40 (granite) with an average of 28 ± 5, 20.7 ± 4, and 340.8 ± 18 (average ± standard deviation), respectively. Radiological indicators (activity concentration index, alpha and gamma index, hazard indices, interior absorbed gamma dose rate and the corresponding yearly effective dosage rate, and excess lifetime cancer risk) were computed to assess the health risks associated with these building materials. Consideration was given to the indoor annual effective dosage for common construction materials, the radon surface expiration rate, and the indoor radon concentration. The mean values of activity concentration were then inputted into the RESRAD-BUILD computer software to calculate a resident's long-term radiation exposure. The dosages were measured over a range of 0 to 70 years. From 0 to 30 years, there was a significant change in dosages; however, from 30 to 70 years, the dosages were reasonably consistent. This research demonstrates that granite samples are not safe for dwellings with poor ventilation (especially those without windows). In general, other investigated construction materials in the buildings are deemed safe for the population, since the computed values for these parameters fall within the well-being restrictions or criterion values.


Assuntos
Monitoramento de Radiação , Radioatividade , Rádio (Elemento) , Radônio , Humanos , Radioisótopos de Potássio/análise , Tório/análise , Espectrometria gama , Rádio (Elemento)/análise , Sulfato de Cálcio/análise , Iraque , Monitoramento de Radiação/métodos , Materiais de Construção , Medição de Risco
15.
Artigo em Inglês | MEDLINE | ID: mdl-36078754

RESUMO

In this article, an investigation of the natural radioactivity content of pyroclastic products from Mt. Etna, eastern Sicily, Southern Italy, was carried out. In particular, the assessment of the average activity concentration of the investigated radionuclides, related to the mineralogical phase composition of the analyzed samples, and the radiological health risk for the population, was performed. High Purity Germanium (HPGe) gamma-ray spectrometry was employed in order to quantify the average specific activity of 226Ra, 232Th, and 40K natural radioisotopes. The absorbed gamma dose rate (D), the radium equivalent activity (Raeq), the hazard indices (Hin and Hex), the annual effective dose equivalent outdoor (AEDEout), and the excess lifetime cancer risk (ELCR) were also estimated in order to assess any possible radiological hazard for the population. In our case, they were found to be lower than the maximum recommended values for the population members, thus reasonably excluding radiological hazard effects. Moreover, the identification of the source of the aforementioned naturally occurring radionuclides was attempted by X-ray Diffraction (XRD) and Micro-Raman Scattering (MRS), thereby recognizing the main radioisotope-bearing minerals present in the investigated pyroclastic products. Finally, Pearson correlation, Principal Component Analysis (PCA), and Hierarchical Cluster Analysis (HCA) were performed by processing observed radioactivity and radiological parameters in order to determine their correlation with the sampling locations.


Assuntos
Monitoramento de Radiação , Radioatividade , Rádio (Elemento) , Poluentes Radioativos do Solo , Radioisótopos de Potássio/análise , Monitoramento de Radiação/métodos , Radioisótopos/análise , Rádio (Elemento)/análise , Sicília , Poluentes Radioativos do Solo/análise , Espectrometria gama , Tório/análise
16.
Artigo em Inglês | MEDLINE | ID: mdl-36141963

RESUMO

It has been analyzed in this article the radioactivity concentrations of 226Ra, 232Th, 40K and radiological hazard parameters in different types of cements commonly used in Poland and available on the Polish market. The radiological hazard parameters are, in particular, absorbed gamma dose rate, annual effective dose, radium equivalent activity, the external hazard index, and the gamma and alpha indices. The radionuclide activities of the most important radionuclides 226Ra, 232Th, 40K have been determined by gamma-ray spectrometry with the use of two kinds of spectrometers of different operational parameters. One performed also measurements on 30-day and 45-day aged samples as to verify if there is a statistically significant difference in radioactivity concentration for shorter and longer aging time. The radioactivity concentrations in the cement samples ranged from 21.7-75.7 Bq·kg-1 for 226Ra, 12.3-47.3 Bq·kg-1 for 232Th to 123-430 Bq·kg-1 for 40K. The radiological parameters in cement samples were calculated as follows: mean radium equivalent activity Raeq = 127 Bq·kg-1, mean absorbed gamma dose rate D = 115 nGy·h-1, mean annual effective dose E = 570 µSv·y-1, external hazard index Hex = 0.32, internal hazard index Hin = 0.51, mean activity concentration index Iγ = 0.47 and mean alpha index Iα = 0.28. The results were compared with the reported data from other countries and the international standard values given by European Commission (EC) and United Nations Scientific Committee on the Effects of Atomic Radiation (UNSCEAR 2000). Finally, thorough statistical analysis has been performed.


Assuntos
Monitoramento de Radiação , Radioatividade , Rádio (Elemento) , Poluentes Radioativos do Solo , Materiais de Construção/análise , Polônia , Radioisótopos de Potássio/análise , Monitoramento de Radiação/métodos , Radioisótopos/análise , Rádio (Elemento)/análise , Poluentes Radioativos do Solo/análise , Espectrometria gama , Tório/análise
17.
Radiat Prot Dosimetry ; 198(9-11): 796-801, 2022 Aug 22.
Artigo em Inglês | MEDLINE | ID: mdl-36005977

RESUMO

The gamma spectrometry is one of the fundamental methods used in nuclear technology with well-established procedures of data acquisition and evaluation. Yet with expanding possibilities of detection and data processing, the question of accurate calibration very often rises, since the traditional approach to calibration might not always be the most efficient. In our work, we focus on field spectrometry and present a way of utilizing an already established and well working calibration facility and expanding its scope for new types of radiation detectors.


Assuntos
Espectrometria gama , Calibragem , Método de Monte Carlo
18.
Radiat Prot Dosimetry ; 198(17): 1353-1360, 2022 Oct 01.
Artigo em Inglês | MEDLINE | ID: mdl-36004403

RESUMO

The activity concentrations of 238U, 232Th and 40K in the soil of areas surrounding the Kayelekera uranium mine were assessed. This study aims to provide a comprehensive profile of soil radioactivity distribution in the area surrounding the uranium mine to determine radiological hazards associated with mining and processing activities. Soil samples were analysed using gamma-ray spectrometry with a high-purity germanium detector. Mean specific activities of 238U, 232Th and 40K were 58.3 ± 3.7, 40.3 ± 0.3 and 590.9 ± 63.9 Bq kg-1, respectively. Results from this study have indicated changes in radioactivity levels of naturally occurring radioactive materials in the area surrounding the understudied mine, with certain areas close to the mine site showing elevated levels of 238U, highlighting the need for systematic and periodic monitoring.


Assuntos
Germânio , Monitoramento de Radiação , Radioatividade , Poluentes Radioativos do Solo , Urânio , Germânio/análise , Malaui , Radioisótopos de Potássio/análise , Monitoramento de Radiação/métodos , Solo , Poluentes Radioativos do Solo/análise , Espectrometria gama , Tório/análise , Urânio/análise
19.
Appl Radiat Isot ; 188: 110384, 2022 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-35863146

RESUMO

In low activity gamma spectrometric measurements of large, dense samples, the bulk sample material shields the HPGe crystal from external background sources. If not accounted for in studies that utilise background-subtraction methods, this effect may result in systematic errors in the sample activity and detection limit estimation. We introduce a Monte Carlo based method to minimise the impact of this effect on sample gamma spectra. It is validated using simulated detector backgrounds and applied to a measurement of low-activity [Formula: see text] . One main prerequisite for the correct application of this method is to know in advance the nuclides which contribute to the detector background spectrum and their spatial distribution. With a thorough understanding of the detector backgrounds, the method improves the accuracy of sensitive low-background measurements of low-activity samples. Even without knowing the background sources and their distribution, conservative results may still be presented that account for the potential systematic errors introduced by this background shielding effect.


Assuntos
Espectrometria gama , Raios gama , Método de Monte Carlo , Espectrometria gama/métodos
20.
Environ Monit Assess ; 194(8): 522, 2022 Jun 23.
Artigo em Inglês | MEDLINE | ID: mdl-35737131

RESUMO

The activity concentrations of natural and artificial radionuclides (40K, 232Th, 226Ra, 238U, 137Cs) and concentrations of six heavy metals of interest (Cd, Cr, Cu, Ni, Pb and Zn) were investigated in 18 soil samples through soil depths (0-10, 10-20, 20-30, 30-40.40-50, 50-60 cm) at the three selected sites in the Hadzici. Since at this area ammunition with depleted uranium had been used during the NATO strikes in 1995, this study was conducted with the aim to assess the radiological and environmental health hazards. Radioactivity was determined by gamma spectrometry using HPGe and LEGE detectors and content of heavy metals by using a flame atomic absorption spectrometry. The correlation with distribution of the radionuclides and their activity concentrations through depths was found only at the site 1 for 40K, 232Th and 226Ra, where minimum/maximum activity concentrations for 40K were 814.42 Bq/kg/1039.48 Bq/kg, for 232Th 53.98 Bq/kg/74.12 Bq/kg and for 226Ra 50.32 Bq/kg/65.73 Bq/kg. Vertical distribution of 137Cs along 3 site profiles was used for distinction of cultivated and uncultivated soil. Using the activity ratio of 238U/226Ra and 235U/238U, the presence of depleted uranium (DU) was established at the site 3. Obtained Igeo values for determined heavy metals showed that all of three sites were unpolluted to moderately polluted. Pb content in all three sites showed correlation with concentration decreasing with increasing soil depth.


Assuntos
Metais Pesados , Poluentes do Solo , Urânio , Monitoramento Ambiental , Chumbo/análise , Metais Pesados/análise , Solo/química , Poluentes do Solo/análise , Espectrometria gama/métodos , Urânio/análise
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